期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 43, 页码 15256-15262出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500523
关键词
adsorption; cluster compounds; gold; gas-phase reactions; kinetics
资金
- Research Foundation-Flanders (FWO)
- KU Leuven Research Council (BOF) [GOA14/007]
- Vietnamese Government (MOET program) [322]
The adsorption of propene on neutral gold clusters is investigated in a collision cell under a few collision conditions. The adsorption reaction is studied by pressure-dependent kinetic measurements and delayed unimolecular dissociation of the excited Au(n)propene complexes. The cluster size (n=9-25) and temperature (T=90-300K) dependence of the propene adsorption is analyzed. Strong size dependences of the absorption reaction are observed; a larger propene adsorption probability was found for gold clusters composed of an even number of atoms. Propene binding energies are estimated by comparison of the temperature-dependent unimolecular dissociation rates with rates obtained by using statistical RRKM modeling. The Au-n-propene binding energies decrease non-monotonously with cluster size and are in the range of 1.2-0.85eV for n=9-25. Finally, the bonding of C3H6 on Au-n is qualitatively described and similarities with the absorption of CO molecules on gold clusters are discussed.
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