期刊
CHEMISTRY OF MATERIALS
卷 27, 期 9, 页码 3505-3515出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b00944
关键词
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资金
- National Key Basic Research Program of China [2013CB933901, 2014CB744502, 2014CB932004]
- National Natural Science Foundation of China [21222106, 81370042, 81430041, J1310024]
- Natural Science Foundation of Fujian [2013J06005]
- Ying Tung Education Foundation [142012]
Controlled synthesis of monodisperse iron oxide (IO) nanostructures with diverse morphology remains a major challenge. In this work, IO nanostructures with various shapes and surface structures were synthesized by thermal decomposition of iron oleate (FeOL) in the presence of sodium oleate (NaOL). In a mild condition using 1-octadecene (ODE) as solvent, NaOL may preferentially bind to Fe3O4{111} facets and lead to the formation of Fe3O4{111} facet exposed 10 plates, truncated octahedrons, and tetrahedrons. While in a high-boiling temperature tri-n-octylamine (TOA) solvent, we obtained Fe3O4{100} facet exposed 110 cubes, concaves, multibranches, and assembled structures by varying the molar ratios of NaOL/FeOL. Moreover, we demonstrated that IO nanoparticles (NPs) with metal-exposed surface structures have enhanced T-1 relaxation time shortening effects to protons, and IO NPs with anisotropic shapes are superior in protons T-2 relaxation shortening due to the larger effective radii compared to that of spherical IO NPs. This study can provide rational design considerations for the syntheses and applications of IO nanostructures for a broad community of material research fields.
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