期刊
CHEMISTRY OF MATERIALS
卷 27, 期 10, 页码 3756-3762出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b01003
关键词
-
资金
- Chevron Energy and Technology Company
- NDSEG
RTH-type zeolites are promising catalytic materials for applications that include the important methanol-to-olefins (MTO) and NOX reduction reactions. Here, RTH-type zeolites are prepared using a wide-range of imidazolium-based, cationic organic structure directing agents (OSDAs), that greatly expand the methodologies and compositions that can be used to synthesize these materials. The abilities of the OSDAs to produce RTH-type zeolites agree well with results from molecular modeling studies of predicted stabilization energies of the OSDAs in the RTH framework. The RTH-type zeolites are stable to steaming up to 900 degrees C and are shown to be active MTO catalysts.
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