期刊
CHEMISTRY OF MATERIALS
卷 27, 期 15, 页码 5332-5339出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b01711
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资金
- Swedish Research Council (VR)
- Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Berzelii Center EXSELENT on Porous Materials
- Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Rontgen-Angstrom Cluster through VR
- Knut & Alice Wallenberg Foundation
- project grant 3DEM-NATUR
- VINNOVA through a VINNMER grant
- Wenner-Gren Foundations
A series of highly porous isoreticular lanthanide-based metal organic frameworks (LnMOFs) denoted as SUMOE-7I to SUMOE-7IV (SU = Stockholm University; Ln = La, Ce, Pr, Nd, Sm, Eu, and Gd) have been synthesized using tritopic carboxylates as the organic linkers. The SUMOF-7 materials display one-dimensional pseudohexagonal channels with the pore diameter gradually enlarged from 8.4 to 23.9 angstrom, as a result of increasing sizes of the organic linkers. The structures have been solved by single crystal X-ray diffraction or rotation electron diffraction (RED) combined with powder X-ray diffraction (PXRD). The SUMOF-7 materials exhibit robust architectures with permanent porosity. More importantly, they exhibit exceptionally high thermal and chemical stability. We show that, by inclusion of organic dye molecules, the luminescence properties of the MOFs can be elaborated and modulated, leading to promising applications in sensing and optics.
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