4.3 Article

Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C-H Bond Cleavage

期刊

CHEMISTRY LETTERS
卷 44, 期 8, 页码 1104-1106

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CHEMICAL SOC JAPAN
DOI: 10.1246/cl.150444

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资金

  1. MEXT
  2. JSPS
  3. JST, Japan
  4. Deutsche Forschungsgemeinschaft [IGRK 1628]
  5. Grants-in-Aid for Scientific Research [25288048, 14J00760] Funding Source: KAKEN

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Rhodium-catalyzed direct coupling of benzothioamides with alkenes proceeds smoothly involving ortho-C-H bond cleavage. The thioamides also couple with alkynes under similar conditions accompanied by desulfurization and C-N bond cleavage to produce indenone derivatives.

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