期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 5, 页码 955-960出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400957
关键词
Baeyer-Villiger oxidation; hydrogen peroxide; organoselenium catalysis; alpha,beta-unsaturated ketones; vinyl esters
资金
- NNSFC [21202141, 20902070, 51273172]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- ZJNSF for Distinguished Young Scholars [LR14B020002]
By carefully screening the organoselenium pre-catalysts and optimizing the reaction conditions, simple dibenzyl diselenide was found to be the best pre-catalyst for Baeyer-Villiger oxidation of (E)-alpha,beta-unsaturated ketones with the green oxidant hydrogen peroxide at room temperature. The organoselenium catalyst used in this reaction could be recycled and reused several times. This new method was suitable not only for methyl unsaturated ketones, but also for alkyl and aryl unsaturated ketones. Therefore, it provided a direct, mild, practical, highly functional group-tolerant process for the chemoselective preparation of the versatile (E)vinyl esters from the readily available (E)-alpha,beta-unsaturated ketones. A possible mechanism was also proposed to rationalize the activity of the organoselenium catalyst in the presence of hydrogen peroxide in this Baeyer-Villiger oxidation reaction.
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