期刊
NEW JOURNAL OF CHEMISTRY
卷 40, 期 7, 页码 5835-5845出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj03347k
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Two series of cofacial bis(dipyrrins) were prepared and their photophysical properties as well as their bimolecular fluorescence quenching with C-60 were investigated. DFT and TDDFT computations were also performed as a modeling tool to address the nature of the fluorescence state and the possible inter-chromophore interactions. Clearly, there is no evidence for such interactions and the bimolecular quenching of fluorescence, in comparison with mono-dipyrrins, indicates that C-60-bis(dipyrrin) contacts occur from the outside of the mouth of the cofacial structure.
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