期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 1, 页码 56-61出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500785
关键词
aerobic oxidation; copper; sulfinates; sulfinyl radicals; thiosulfonates
资金
- Korea CCS R&D Center (KCRC) grant from Korea Government (Ministry of Education, Science and Technology) [2015M1A8A1048886]
- C1 gas refinery program through National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2015M3D3A1065436]
- Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant - Korea government Ministry of Trade, Industry Energy [20154010200820]
- National Research Foundation of Korea [2015M1A8A1048886] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Copper-catalyzed aerobic coupling of thiols and alcohols affords sulfinates and thiosulfonates. These products are assumed to form via sulfinyl radicals which are not commonly found in oxidative coupling reactions of thiols. A reaction mechanism involving sulfinyl radicals is proposed, and mass and electron paramagnetic resonance (EPR) experimental results are provided.
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