期刊
NEW JOURNAL OF CHEMISTRY
卷 40, 期 4, 页码 3119-3123出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj02734a
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资金
- UGC, New Delhi
Oxime-palladacycle catalyzed Suzuki-Miyaura cross-coupling reaction of acid chlorides and arylboronic acids to yield aryl ketones was developed. The remarkable benefit of this method is the use of water immiscible (practically) 2-MeTHF as solvent, which provides easy isolation of the crude reaction mixture just by separation of 2-MeTHF-water layers, and then evaporation of 2-MeTHF. Moreover, the use of relatively equal proportion of substrates and less generation of side products make the method highly atom economic.
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