期刊
NEW JOURNAL OF CHEMISTRY
卷 40, 期 1, 页码 687-693出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj02697k
关键词
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资金
- Fusion Research Program for Green Technologies through the National Research Foundation of Korea - Ministry of Science, ICT and Future Planning [2012M3C1A1054502]
- Basic Science Research Program through the National Research Foundation of Korea [2015R1D1A1A09057372]
- BK21 PLUS Program
Tungstosulfonic acid (TSA) has been found to be an efficient solid acid catalyst for the protection of aldehydic carbonyl groups by geminal diacetate (acylal) formation following the nucleophilic addition of acetic anhydride under neat conditions as well as in a solvent. The TSA catalyst is fully characterized by infrared spectroscopy, wide-angle X-ray scattering analysis, and scanning electron microscopy with energy dispersive X-ray spectroscopy. The deprotection of acylals to corresponding aldehydes has also been investigated under the similar conditions. The catalyst can be reused seven times without a significant loss of activity. In addition, no chromatographic separations are needed to obtain the desired products. This method is a green approach for the chemoselective protection of aldehydes in the presence of ketones.
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