期刊
NEW JOURNAL OF CHEMISTRY
卷 40, 期 4, 页码 3308-3313出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj02681d
关键词
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资金
- China Scholarship Council (CSC) from the People's Republic of China (XL)
- Fondo Nacional de Desarrollo Cientifico y Tecnologico [FONDECYT (Chile) [1090310, 1130105]
- Vicerrectoria de Investigacion y Estudios Avanzados, Pontificia Universidad Catolica de Valparaiso, Chile
- CNRS
- Universite de Rennes 1
- CONICYT (Chile)
- BECAS-CHILE
- Joint Supervision Scholarship (PUCV/UR1)
A new ferrocenyl-containing unsymmetrical Cu-II-Schiff-base complex, 2, and its covalently poly(methyl) (methacrylate) (PMMA)-grafted counterpart 3 were synthesized and characterized using elemental analysis, electrospray ionisation (ESI) mass spectrometry for 2, and FT-IR spectroscopy. New complex 3 was employed as a precatalyst in the copper-catalyzed [3+2] cycloaddition of organic azides to alkynes (CuAAC, click reaction). The active Cu-I species generated from only 0.2 mol% of Cu-II precatalyst 2 and sodium ascorbate displayed high activity at room temperature in ethanol for 24 hours allowing the synthesis of a wide variety of 1,4-disubstituted 1,2,3-triazoles in high isolated yields. The PMMA-supported catalyst 3 is also efficient and has been reused at least three times in these click reactions without any loss of activity or copper leaching.
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