☆ 4.6 Article

Ultrafast-sintered self-standing LLZO membranes for high energy density lithium-garnet solid-state batteries

CELL REPORTS PHYSICAL SCIENCE (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Multidisciplinary

Bilayer Dense-Porous Li7La3Zr2O12 Membranes for High-Performance Li-Garnet Solid-State Batteries

Huanyu Zhang et al.

Summary: Li dendrites form in Li7La3Zr2O12 (LLZO) solid electrolytes due to volume changes and voids at the Li metal/LLZO interface. Dense-porous LLZO membranes provide a solution by storing lithium in the pores, avoiding volume changes and void formation. The reported method of sequential tape-casting allows for the production of bilayer membranes with high performance.

ADVANCED SCIENCE (2023)

添加到收藏夹

Article Chemistry, Physical

Intermediate-Stage Sintered LLZO Scaffolds for Li-Garnet Solid-State Batteries

Faruk Okur et al.

Summary: The formation of cavities at the LLZO/Li interface hinders the further development of Li-garnet solid-state batteries. To address this issue, a method of fabricating porous LLZO membranes is proposed, which not only reduces cavity formation but also increases energy densities. The fabricated porous LLZO membranes exhibit long cycling stability.

ADVANCED ENERGY MATERIALS (2023)

添加到收藏夹

Article Multidisciplinary Sciences

On the feasibility of all-solid-state batteries with LLZO as a single electrolyte

Kostiantyn Kravchyk et al.

Summary: Replacing liquid-state electrolytes with solid-state counterparts in Li-ion batteries is a major research objective. Among the different solid-state electrolytes, garnet-type Li-ion electrolytes based on LLZO are considered promising candidates, but they still face challenges due to high density and lower ion conductivity compared to liquid electrolytes.

SCIENTIFIC REPORTS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ultrafast Sintering for Ceramic-Based All-Solid-State Lithium-Metal Batteries

Shaojie Chen et al.

Summary: In this study, an ultrafast sintering method using microwave-induced carbothermal shock is reported, which can fabricate various ceramic electrolytes in seconds. Furthermore, it is possible to integrate the electrode and electrolyte in one step by simultaneous co-sintering. Based on this technique, a high areal capacity all-solid-state lithium-metal battery with promising electrochemical performance at room temperature is successfully achieved. This method can also be extended to other solid devices based on ceramic multilayer structures.

ADVANCED MATERIALS (2022)

添加到收藏夹

Article Materials Science, Ceramics

Influence of sintering atmosphere on the phase, microstructure, and lithium-ion conductivity of the Al-doped Li7La3Zr2O12 solid electrolyte

Xinyu Ping et al.

Summary: Al-LLZO-O-2 sample with the highest relative density and largest grain size demonstrates higher lithium-ion conductivity.

CERAMICS INTERNATIONAL (2022)

添加到收藏夹

Article Instruments & Instrumentation

A new high temperature, high heating rate, low axial gradient capillary heater

Kenneth P. Marshall et al.

JOURNAL OF SYNCHROTRON RADIATION (2022)

添加到收藏夹

Article Chemistry, Physical

Achieving Desired Lithium Concentration in Garnet Solid Electrolytes; Processing Impacts on Physical and Electrochemical Properties

Matthew A. Limpert et al.

Summary: Lithium-ion-conducting garnets are promising solid-state electrolytes for lithium batteries. This study investigates the impact of lithium content on the physical and electrochemical properties of Li6.75 +/- XLa2.75Ca0.25Zr1.75Nb0.5O12 (LLCZN) garnets. The results show that variations in lithium content affect sintering and conductivity, with secondary phases hindering sintering and reducing total conductivity. Sintering in Al2O3 crucibles leads to higher total conductivity compared to MgO crucibles.

CHEMISTRY OF MATERIALS (2022)

添加到收藏夹

Article Materials Science, Ceramics

Phase transformation and grain-boundary segregation in Al-Doped Li7La3Zr2O12 ceramics

Libin Zhuang et al.

Summary: Cubic phase garnet-type Li7La3Zr2O12 (LLZO) is a safe solid electrolyte for Li-ion batteries, while Al-doped LLZO (Al-LLZO) has been widely studied for its low cost, but the ionic conductivity is affected by Al3+-Li+ substitution and Li(x)AlOy segregation.

CERAMICS INTERNATIONAL (2021)

添加到收藏夹

Article Chemistry, Physical

Break-Even Analysis of All-Solid-State Batteries with Li-Garnet Solid Electrolytes

Kostiantyn V. Kravchyk et al.

ACS ENERGY LETTERS (2021)

添加到收藏夹

Review Chemistry, Physical

Garnet-Based Solid-State Li Batteries: From Materials Design to Battery Architecture

Sara Abouali et al.

Summary: This review focuses on the garnet family as a solid electrolyte candidate, discussing its structure, optimization for ionic conductivity, and synthesis methods for different garnet solid electrolytes, as well as providing a detailed comparison of garnet-based all-solid-state lithium batteries. It aims to pave the way for practical garnet-based all-solid-state lithium batteries by providing insights into the latest achievements in the field.

ACS ENERGY LETTERS (2021)

添加到收藏夹

Editorial Material Chemistry, Physical

Challenges for and Pathways toward Li-MetalBased All-Solid-State Batteries

Paul Albertus et al.

ACS ENERGY LETTERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

High-Temperature Ultrafast Sintering: Exploiting a New Kinetic Region to Fabricate Porous Solid-State Electrolyte Scaffolds

Ruiliu Wang et al.

Summary: The method described in the text offers a simple and efficient way to fabricate 3D porous scaffolds with ceramic solid-state electrolytes, allowing for rapid sintering of the desired crystalline phase and control over densification. This approach is suitable for various applications in all-solid-state batteries.

ADVANCED MATERIALS (2021)

添加到收藏夹

Article Materials Science, Ceramics

Phase evolution during reactive flash sintering of Li6.25Al0.25La3Zr2O12 starting from a chemically prepared powder

Viviana Avila et al.

Summary: Reactive flash sintering (RFS) was used to fabricate Al-LLZO ceramics from a chemically prepared multiphase precursor powder, resulting in single-phase dense samples with high bulk conductivity. In-situ X-ray diffraction revealed that RFS promoted the growth of intermediate phases, suggesting its potential for stabilizing thermodynamically unfavored phases.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2021)

添加到收藏夹

Article Materials Science, Ceramics

Li7La3Zr2O12 solid electrolyte sintered by the ultrafast high-temperature method

Martin Ihrig et al.

Summary: All-solid-state Li batteries with garnet LLZO as solid electrolyte show stability against Li metal, but challenges exist in integrating it due to high temperature and long dwell time for sintering. Advanced sintering techniques like Ultrafast High-temperature Sintering can significantly increase sintering rates, but demixing at grain boundaries may occur during sintering in vacuum and Ar atmosphere.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Amorphous-Carbon-Coated 3D Solid Electrolyte for an Electro-Chemomechanically Stable Lithium Metal Anode in Solid-State Batteries

Hua Xie et al.

Summary: The study introduces a novel approach to maintain a stable Li metal | electrolyte interface by depositing amorphous carbon nanocoating on a garnet-type solid-state electrolyte, demonstrating outstanding electro-chemomechanical stability and promoting homogeneity in lithium metal stripping and plating processes. This work suggests that amorphous carbon coatings may be a promising strategy for achieving stable Li metal | electrolyte interfaces and reliable Li metal batteries.

NANO LETTERS (2021)

添加到收藏夹

Article Chemistry, Physical

Building a Better Li-Garnet Solid Electrolyte/Metallic Li Interface with Antimony

Romain Dubey et al.

Summary: The study finds that using Sb as an interface layer helps to improve the wettability of Li on LLZO, reducing the interfacial resistance. Experimental results show that both Li/Sb-coated LLZO/Li cells and LLZO/V2O5 full cells exhibit good electrochemical performance without external pressure.

ADVANCED ENERGY MATERIALS (2021)

添加到收藏夹

Article Chemistry, Physical

Lithium garnet-cathode interfacial chemistry: inclusive insights and outlook toward practical solid-state lithium metal batteries

M. S. Indu et al.

Summary: Solid-state lithium batteries have attracted significant interest as a potential alternative to lithium-ion batteries, but practical realization is hindered by challenges at the electrode-garnet interface. Further research is needed to address issues at the cathode-garnet interface.

MATERIALS TODAY ENERGY (2021)

添加到收藏夹

Review Chemistry, Physical

Solid-State Li-Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces

Kun Joong Kim et al.

Summary: The introduction of new, safe, and reliable solid-electrolyte chemistries and technologies can potentially overcome the challenges facing their liquid counterparts while widening the breadth of possible applications. Through analyzing the transition from liquid-based Li-ion batteries (LIBs) to all-solid-state Li-metal batteries (ASSLBs), a roadmap for the development of a successful oxide and sulfide-based ASSLB is introduced, focusing on interfacial challenges and considering parameters such as energy density, power density, longterm stability, processing, and safety.

ADVANCED ENERGY MATERIALS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Tape-Casting Li0.34La0.56TiO3 Ceramic Electrolyte Films Permit High Energy Density of Lithium-Metal Batteries

Zhouyang Jiang et al.

ADVANCED MATERIALS (2020)

添加到收藏夹

Article Nanoscience & Nanotechnology

Scalable Freeze-Tape-Casting Fabrication and Pore Structure Analysis of 3D LLZO Solid-State Electrolytes

Hao Shen et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries

Chengwei Wang et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Materials Science, Multidisciplinary

Spark plasma sintering plus heat-treatment of Ta-doped Li7La3Zr2O12 solid electrolyte and its ionic conductivity

Jiali Xue et al.

MATERIALS RESEARCH EXPRESS (2020)

添加到收藏夹

Article Multidisciplinary Sciences

A general method to synthesize and sinter bulk ceramics in seconds

Chengwei Wang et al.

SCIENCE (2020)

添加到收藏夹

Article Energy & Fuels

Benchmarking the performance of all-solid-state lithium batteries

Simon Randau et al.

NATURE ENERGY (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries

Thorben Krauskopf et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Computation-Guided Synthesis of New Garnet-Type Solid-State Electrolytes via an Ultrafast Sintering Technique

Ruiliu Wang et al.

ADVANCED MATERIALS (2020)

添加到收藏夹

Review Nanoscience & Nanotechnology

Li/Garnet Interface Optimization: An Overview

Huanan Duan et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

添加到收藏夹

Article Chemistry, Physical

All-Solid-State Batteries Using Rationally Designed Garnet Electrolyte Frameworks

Eongyu Yi et al.

ACS APPLIED ENERGY MATERIALS (2020)

添加到收藏夹

Article Materials Science, Multidisciplinary

High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture

Gregory T. Hitz et al.

MATERIALS TODAY (2019)

添加到收藏夹

Article Multidisciplinary Sciences

High thermal conductivity of high-quality monolayer boron nitride and its thermal expansion

Qiran Cai et al.

SCIENCE ADVANCES (2019)

添加到收藏夹

Article Nanoscience & Nanotechnology

Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries-An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li6.25Al0.25La3Zr3O12

Thorben Krauskopf et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

添加到收藏夹

Article Materials Science, Multidisciplinary

Microwave assisted reactive sintering for Al doped Li7La3Zr2O12 lithium ion solid state electrolyte

Dalu Gao et al.

MATERIALS RESEARCH EXPRESS (2019)

添加到收藏夹

Article Chemistry, Physical

Building better all-solid-state batteries with Li-garnet solid electrolytes and metalloid anodes

Semih Afyon et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹

Article Chemistry, Physical

Oriented porous LLZO 3D structures obtained by freeze casting for battery applications

Hao Shen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹

Article Physics, Multidisciplinary

Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration

Chao Yuan et al.

COMMUNICATIONS PHYSICS (2019)

添加到收藏夹

Article Chemistry, Physical

Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte

Nathan J. Taylor et al.

JOURNAL OF POWER SOURCES (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Three-Dimensional, Solid-State Mixed Electron-Ion Conductive Framework for Lithium Metal Anode

Shaomao Xu et al.

NANO LETTERS (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Continuous plating/stripping behavior of solid-state lithium metal anode in a 3D ion-conductive framework

Chunpeng Yang et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

The effect of sintering process on lithium ionic conductivity of Li6.4Al0.2La3Zr2O12 garnet produced by solid-state synthesis

Wenjuan Xue et al.

RSC ADVANCES (2018)

添加到收藏夹

Article Chemistry, Physical

All-in-one lithium-sulfur battery enabled by a porous-dense-porous garnet architecture

Shaomao Xu et al.

ENERGY STORAGE MATERIALS (2018)

添加到收藏夹

Article Chemistry, Physical

3D lithium metal anodes hosted in asymmetric garnet frameworks toward high energy density batteries

Boyang Liu et al.

ENERGY STORAGE MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal-sulfur batteries

Kun (Kelvin) Fu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2017)

添加到收藏夹

Article Materials Science, Ceramics

Reaction mechanisms of lithium garnet pellets in ambient air: The effect of humidity and CO2

Wenhao Xia et al.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Frequency analysis for modulation-enhanced powder diffraction

Dmitry Chernyshov et al.

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2016)

添加到收藏夹

Article Chemistry, Physical

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O12

Ezhiyl Rangasamy et al.

SOLID STATE IONICS (2012)

添加到收藏夹

Article Chemistry, Physical

Al-doped Li7La3Zr2O12 synthesized by a polymerized complex method

Ying Jin et al.

JOURNAL OF POWER SOURCES (2011)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.