☆ 4.6 Article

Nickel-catalyzed hydrobivinylation of enones with 1,3-dienes

CELL REPORTS PHYSICAL SCIENCE (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Multidisciplinary

Enantioselective Ni/N-Heterocyclic Carbene-Catalyzed Redox-Economical Coupling of Aldehydes, Alkynes, and Enones for Rapid Construction of Acyclic All-Carbon Quaternary Stereocenters

Wu-Bin Zhang et al.

Summary: An innovative method for constructing acyclic quaternary carbon stereocenters from aldehydes, alkynes, and enones through N-heterocyclic carbene (NHC)-Ni catalysis has been successfully developed, with high selectivity and atom economy. This strategy is expected to inspire new and efficient approaches for generating other acyclic quaternary stereocenters.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Regio- and Enantioselective Hydroarylation of 1,3-Dienes with Indoles

Lei Cheng et al.

Summary: In this study, a nickel-catalyzed hydroarylation reaction of aliphatic and aromatic dienes with indoles has been reported, resulting in the synthesis of chiral indole derivatives. The reaction is performed under mild conditions and tolerates various functional groups.

CCS CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Applied

Nickel-Catalyzed Hydroborylative Polycyclization of Allenynes: an Atom-Economical and Diastereoselective Synthesis of Bicyclic 5-5 Fused Rings

Ines Manjon-Mata et al.

Summary: A diastereoselective synthesis of borylated bicyclic 5-5 fused ring systems has been achieved through a domino Ni-catalyzed hydroborylative polycyclization of allenynes, providing two new C-C bonds and one C-B bond. The reaction is atom-economical, rapid, and tolerant to functional groups. The process involves oxidative cyclometallation, sigma-metathesis, and 1,2-insertion into the Ni-H bond, followed by reductive elimination.

ADVANCED SYNTHESIS & CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereoselective Synthesis of Trisubstituted Alkenes by Nickel-Catalyzed Benzylation and Alkene Isomerization

Yunlong Zhao et al.

Summary: In this study, a N-heterocyclic carbene-Ni-I catalytic species was used to achieve highly substituted alkenes from abundant monosubstituted substrates with excellent regio- and stereoselectivities. Trimethylsilyl triflate and trimethylamine additives were added to mediate the reaction, resulting in the generation of trisubstituted boron- and arene-containing trans alkenes. This method represents a significant addition to the toolbox of reactions for the concise synthesis of unsaturated biologically active compounds.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ruthenium-Catalyzed Geminal Hydroborative Cyclization of Enynes

Yun-Xuan Tan et al.

Summary: The first geminal hydroborative cyclization of enynes is disclosed in this study. Unlike known hydroborative cyclizations, this reaction adds hydrogen and boron to the same position, leading to a new reaction mode. By using a specific catalyst, a variety of gem-hydroborated bicyclic products with a cyclopropane unit can be rapidly formed from simple enyne substrates. Control experiments and calculations provide important insights into the reaction mechanism. Notably, two competing pathways may operate, depending on the substrate.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective C2-H Alkylation of Pyridines with 1,3-Dienes via Ni-Al Bimetallic Catalysis

Jiang-Fei Li et al.

Summary: A chiral phosphine oxide-ligated Ni-Al bimetallic catalyst was successfully utilized for an enantioselective C2-H alkylation of pyridines, showing compatibility with a wide range of pyridine substrates and providing high yields and enantioselectivities.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-catalysed construction of butafulvenes

Xin Huang et al.

Summary: This article reports an efficient palladium-catalyzed coupling protocol for the rapid assembly of symmetric butafulvene derivatives. Two complementary mechanisms involving palladium catalysis were confirmed through mechanistic studies, enabling the synthesis of non-symmetric butafulvenes. The advantages of this strategy include mild reaction conditions, simple catalytic systems, and easy scalability. The synthetic potential of the products as platform molecules for cyclobutene derivatives was also demonstrated.

NATURE CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Physical

Nickel-catalysed asymmetric heteroarylative cyclotelomerization of isoprene

Gong Zhang et al.

Summary: The atom-economic reaction of heteroarylative telomerization of isoprene with heterocycles provides an efficient enantioselective transformation method for creating an unnatural monoterpene framework, which may exhibit different biological activities.

NATURE CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Organic

Nickel-Catalyzed Carboalkenylation of 1,3-Dienes with Aldehydes and Alkenylzirconium Reagents: Access to Skipped Dienes

Cheng-Gang Wang et al.

Summary: A regio- and stereoselective nickel-catalyzed three-component coupling reaction has been developed, allowing for the convenient synthesis of skipped diene compounds with various functional groups and heterocyclic groups. The products are easily converted into structurally diverse polyenes, demonstrating the utility of this reaction for one-pot operation and scale-up preparation.

ORGANIC LETTERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Enantioselective α-Alkenylation of N-Sulfonyl Amines: Modular Access to Chiral α-Branched Amines

Lun Li et al.

Summary: The study introduces a nickel-catalyzed, atom-economical method for synthesizing chiral alpha-branched amines and their derivatives, demonstrating generality and high atom economy.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Multidisciplinary Sciences

Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group

Yi-Zhou Zhan et al.

Summary: The development of straightforward synthesis of regio- and stereo-defined alkenes with multiple aliphatic substituents under mild conditions is a challenging task. Here, the authors present a nickel-catalyzed intermolecular cross-dialkylation of alkynes to achieve syn-selective synthesis of alkenes with multiple aliphatic substituents.

NATURE COMMUNICATIONS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ni-catalyzed enantioselective [2+2+2] cycloaddition of malononitriles with alkynes

Jinhui Cai et al.

Summary: This study presents an efficient strategy for assembling enantioenriched pyridine derivatives by forming three bonds and one quaternary stereocenter simultaneously in a single reaction step. The reaction utilizes bio-renewable 2-MeTHF as the solvent, features mild reaction conditions, and shows good functional group compatibilities and enantioselectivities.

CHEM (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Palladium Complex as an Asymmetric π-Lewis Base Catalyst for Activating 1,3-Dienes

Ben-Xian Xiao et al.

Summary: Palladium(0) complexes can coordinate with 1,3-dienes in an eta(2) fashion, raising the energy of their HOMO to enable a hydrodienylation reaction. Additionally, a vinylogous addition/allylic alkylation difunctionalization process can also take place.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions

Laura M. Wickham et al.

Summary: Alkene dicarbofunctionalization is a powerful organic synthesis method that utilizes transition metals and carbon sources to synthesize complex molecules. The strategy of cyclometalation and metallacycle contraction is employed to address the issue of beta-H elimination in alkene dicarbofunctionalization reactions.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

添加到收藏夹

Article Chemistry, Organic

Access to Z-Selective 1,3-Enynes via Ni-Catalyzed Intermolecular Cross-Alkylalkynylation of Terminal Alkynes

Nan Xiao et al.

Summary: This method provides a facile and efficient way to synthesize stereodefined 1,3-conjugated enynes, with good tolerance towards a wide range of functional groups and operable at room temperature. It offers an attractive alternative for preparing carbonyl-tethered trisubstituted conjugated 1,3-enynes from readily available starting materials.

ORGANIC LETTERS (2021)

添加到收藏夹

Article Multidisciplinary Sciences

Ni-catalyzed hydroaminoalkylation of alkynes with amines

Wei-Wei Yao et al.

Summary: Allylic amines are versatile building blocks in organic synthesis and exist in bioactive compounds, but their efficient synthesis via hydroaminoalkylation of alkynes with amines has been a challenge. The authors report a late transition metal-catalyzed hydroaminoalkylation of alkynes with N-sulfonyl amines, providing a series of allylic amines in up to 94% yield.

NATURE COMMUNICATIONS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel- and Bronsted Acid-Catalyzed Redox-Neutral Coupling of 1,3-Dienes and Aldehydes for Synthesis of Dienols

Xing-Wang Han et al.

Summary: A redox-neutral coupling of simple 1,3-dienes and aldehydes via nickel and Bronsted acid dual catalysis provides a highly atom-economical and by-product-free route to various dienols, with up to 94% yield and up to 50:1 EE/EZ ratio. The use of 2-isopropoxyphenol as a Bronsted acid co-catalyst was critical to the reactivity and selectivity.

CCS CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Switch in Selectivity for Formal Hydroalkylation of 1,3-Dienes and Enynes with Simple Hydrazones

Leiyang Lv et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ni(COD)(DQ): An Air-Stable 18-Electron Nickel(0)-Olefin Precatalyst

Van T. Tran et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Reductive Coupling of Aldehydes with Alkynes Mediated by Alcohol

Yan-Long Zheng et al.

CHINESE JOURNAL OF CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Physical

Copper-Catalyzed Functionalization of 1,3-Dienes: Hydrofunctionalization, Borofunctionalization, and Difunctionalization

Gregory J. P. Perry et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Physical

Mechanism of Cobalt-Catalyzed Heterodimerization of Acrylates and 1,3-Dienes. A Potential Role of Cationic Cobalt(I) Intermediates

Montgomery Gray et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Expedient Synthesis of KetonesviaN-HeterocyclicCarbene/Nickel-Catalyzed Redox-EconomicalCoupling of Alcohols and Alkynes†

Yu-Qing Li et al.

CHINESE JOURNAL OF CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-catalyzed allyl-allyl coupling reactions between 1,3-dienes and allylboronates

Ding-Wei Ji et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Asymmetric synthesis of allylic compounds via hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes

Guanlin Li et al.

CHEMICAL SOCIETY REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic Prenylation and Reverse Prenylation of Indoles with Isoprene: Regioselectivity Manipulation through Choice of Metal Hydride

Yan-Cheng Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ruthenium-Catalyzed Redox Isomerizations inside Living Cells

Cristian Vidal et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Organic

Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates

Natalia Cabrera-Lobera et al.

ORGANIC LETTERS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ni-Catalyzed Cyclization of Enynes and Alkynylboronates: Atom-Economical Synthesis of Boryl-1,4-dienes

Natalia Cabrera-Lobera et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles

Chengxi Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Organic

Copper-Catalyzed Modular Amino Oxygenation of Alkenes: Access to Diverse 1,2-Amino Oxygen-Containing Skeletons

Brett N. Hemric et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

NHC ligand-enabled Ni-catalyzed reductive coupling of alkynes and imines using isopropanol as a reductant

Wei-Wei Yao et al.

GREEN CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-catalyzed hydroalkylation and hydroalkenylation of 1,3-dienes with hydrazones

Lei Cheng et al.

CHEMICAL SCIENCE (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

Michael Holmes et al.

CHEMICAL REVIEWS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Selective[1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts

Valerie A. Schmidt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regioselective Simmons-Smith-type cyclopropanations of polyalkenes enabled by transition metal catalysis

Jacob Werth et al.

CHEMICAL SCIENCE (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-catalyzed enantioselective carboannulation of 1,3-dienes with aryl iodides enables access to chiral indanes

Xiang Wu et al.

CHEMICAL COMMUNICATIONS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel(0)-Catalyzed Hydroalkylation of 1,3-Dienes with Simple Ketones

Lei Cheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective Coupling of Dienes and Phosphine Oxides

Shao-Zhen Nie et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis of and Catalytic Linear Cross-Dimerizations by an Electron-Deficient Cyclic Diene Complex of Ruthenium(0)

Masafumi Hirano et al.

ORGANOMETALLICS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene

Takuya Kawashima et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Physical

Selectivities in Nickel-Catalyzed Hydrocarboxylation of Enynes with Carbon Dioxide

Tao Cao et al.

ACS CATALYSIS (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Chalcone: A Privileged Structure in Medicinal Chemistry

Chunlin Zhuang et al.

CHEMICAL REVIEWS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regiocontrol in Catalytic Reductive Couplings through Alterations of Silane Rate Dependence

Evan P. Jackson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of Highly Functionalized Tri- and Tetrasubstituted Alkenes via Pd-Catalyzed 1,2-Hydrovinylation of Terminal 1,3-Dienes

Vaneet Saini et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Exploring Bis(cyclometalated) Ruthenium(II) Complexes as Active Catalyst Precursors: Room-Temperature Alkene-Alkyne Coupling for 1,3-Diene Synthesis

Jing Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Review Chemistry, Multidisciplinary

Ni-Catalyzed C-C Bond Formation with α,β-Unsaturated Carbonyl Compounds and Alkynes

Takuya Kurahashi

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2014)

添加到收藏夹

Review Chemistry, Multidisciplinary

[4+2] and [4+3] catalytic cycloadditions of allenes

Fernando Lopez et al.

CHEMICAL SOCIETY REVIEWS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols

Kenichiro Nakai et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regioselective Hydroacylation of 1,3-Dienes by Cobalt Catalysis

Qing-An Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-catalyzed regio- and diastereoselective intermolecular three-component coupling of oxabicyclic alkenes with alkynes and organoboronic acids

Subramaniyan Mannathan et al.

CHEMICAL COMMUNICATIONS (2013)

添加到收藏夹

Article Biochemistry & Molecular Biology

Exploring Pharmacological Significance of Chalcone Scaffold: A Review

N. K. Sahu et al.

CURRENT MEDICINAL CHEMISTRY (2012)

添加到收藏夹

Review Chemistry, Organic

Hydrovinylation Reactions - Atom-Economic Transformations with Steadily Increasing Synthetic Potential

Gerhard Hilt

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Suzuki-Miyaura Reaction of Aryl Fluorides

Mamoru Tobisu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regioselective Nickel-Catalyzed Reductive Couplings of Enones and Allenes

Wei Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes

Rakesh K. Sharma et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regio- and Stereoselective Ni-Catalyzed 1,4-Hydroboration of 1,3-Dienes: Access to Stereodefined (Z)-Allylboron Reagents and Derived Allylic Alcohols

Robert J. Ely et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Article Chemistry, Organic

Nickel-Catalyzed [2+2+2] Cycloaddition of Two Enones and an Alkyne

Sensuke Ogoshi et al.

ORGANIC LETTERS (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Borylative Coupling of Alkynes, Enones, and Bis(pinacolato)diboron as a Route to Substituted Alkenyl Boronates

Subramaniyan Mannathan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Evolution of Efficient Strategies for Enone-Alkyne and Enal-Alkyne Reductive Couplings

Wei Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed [4+2] Cycloaddition of Enones with Alkynes

Ichiro Koyama et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Direct Conjugate Addition of Simple Alkenes to Enones

Sensuke Ogoshi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Chemistry, Organic

Iron-Catalyzed 1,4-Addition of α-Olefins to Dienes

Benoit Moreau et al.

ORGANIC LETTERS (2009)

添加到收藏夹

Review Chemistry, Multidisciplinary

Cobalt- and Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling of Alkynes, Allenes, and Alkenes with Alkenes

Masilamani Jeganmohan et al.

CHEMISTRY-A EUROPEAN JOURNAL (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regio- and stereoselective nickel-catalyzed homoallylation of aldehydes with 1,3-dienes

Masanari Kimura et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

添加到收藏夹

Article Chemistry, Organic

Nickel-catalyzed intermolecular coupling of 1,3-dienes and aldehydes via transmetalation of nickelacycles with diisobutylaluminum acetylacetonate

Y Sato et al.

JOURNAL OF ORGANIC CHEMISTRY (2002)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.