期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 6, 页码 1211-1220出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400970
关键词
alcohols; aldehydes; benzylation; nickel-catalyzed reaction; reductive coupling
资金
- Research Council of Shiraz University
- Iran National Elite Foundation
The reductive benzylation of aromatic and aliphatic aldehydes with benzylic halides is reported using a nickel/zinc catalyst system. In addition to benzylic halides, the first report on the addition of benzylic triflates, acetates, tosylates and tritylates to aldehydes is also presented. By this new method a range of alcohols was synthesized efficiently from aldehydes and benzylic substrates at room temperature in moderate to high yields. The mild reaction conditions and good functional group tolerance make this nickel-catalyzed process synthetically useful for the synthesis of diverse benzylic alcohols.
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