The Synthesis, Crystal Structure, and Magnetic Properties of Mono-Scorpionate Eu(III) Complexes

Review Chemistry, Inorganic & Nuclear

The Tripodal Ligand's 4f Complexes: Use in Molecular Magnetism

Kira E. Vostrikova

Summary: The review summarizes the structural information and magnetic properties of lanthanide complexes with tripodal ligands, and highlights the potential of these ligands in the design of quantum molecular magnets involving lanthanide ions.

INORGANICS (2023)

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Article Chemistry, Inorganic & Nuclear

Magnetism Studies of Bis(acyl)phosphide-Supported Eu3+and Eu2+Complexes

Ju Chen et al.

Summary: A series of bis(acyl)phosphide-supported Eu complexes were synthesized, and the BAP ligands were found to be excellent ligands for the synthesis of both Eu3+ and Eu2+ molecular complexes. The complexes were characterized using a combination of spectroscopic techniques and X-ray diffraction, and their magnetic properties were investigated.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

Elucidation of LMCT Excited States for Lanthanoid Complexes: A Theoretical and Solid-State Experimental Framework

Elodie Rousset et al.

Summary: The photophysical and magnetic properties of lanthanoid ions in both ground and excited states have important applications. Ligand-to-metal charge-transfer (LMCT) states have a substantial impact on these properties, both negatively and positively. However, detecting LMCT states in f-block chemistry, especially in the solid state, remains a challenge. In this study, the LMCT character of the absorption bands in europium compounds was investigated using magnetometry, absorption and emission spectroscopies, and solid-state electrochemistry. The findings suggest a framework for understanding LMCT excited states in lanthanoid compounds in the solid state.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Heteroleptic lanthanide(III) complexes: synthetic utility and versatility of the unsubstituted bis-scorpionate ligand framework

Tajrian Chowdhury et al.

Summary: The unsubstituted bis-hydrotris(I-pyrazolyl)borate) (Tp) ligand framework has been used to synthesise a range of heteroleptic Ln(III) coordination complexes. The complexes were characterised and their solid-state molecular structure was determined by single-crystal X-ray diffraction.

AUSTRALIAN JOURNAL OF CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

Shining New Light on Multifunctional Lanthanide Single-Molecule Magnets

Riccardo Marin et al.

Summary: Single-molecule magnets play a crucial role in quantum information processing and spintronics. The harmonious combination of magnetism and luminescence within single molecules provides insights for emerging next-generation spintronics devices.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Inorganic & Nuclear

Europium(III), Terbium(III), and Gadolinium(III) Oxamato-Based Coordination Polymers: Visible Luminescence and Slow Magnetic Relaxation

Jhonny Willians de Oliveira Maciel et al.

Summary: The reaction of Eu-III, Tb-III, and Gd-III ions with Na(2)Hpcpa in aqueous solutions led to the formation of three new lanthanide(III) coordination polymers. These isostructural polymers exhibit different emission properties and magnetic behaviors, showcasing the versatile applications of these compounds.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Tripodal Oxazolidine-N-Oxyl Diradical Complexes of Dy3+ and Eu3+

Philippe Rey et al.

Summary: Two new diradical complexes of lanthanides and oxazolidine nitroxide were obtained under air conditions and characterized crystallographically and magnetically. Single crystal XRD analysis revealed their coordination sphere structure, while static magnetic measurements confirmed the presence of two paramagnetic ligands in the metal coordination sphere.

INORGANICS (2021)

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Article Chemistry, Inorganic & Nuclear

Tris-{Hydridotris(1-pyrazolyl)borato}lanthanide Complexes: Synthesis, Spectroscopy, Crystal Structure and Bonding Properties

Christos Apostolidis et al.

Summary: This study conducted a joint experimental-theoretical analysis on complexes of trivalent lanthanides with the hydridotris(1-pyrazolyl)borato ligand, revealing structural trends and bonding properties through X-ray diffraction experiments and density functional theory calculations. The analysis identified significant steric strain in the nine-coordinate structures and elucidated the major electrostatic character of the Ln ... Tp bonding with fine variations in charge transfer effects across the lanthanide row.

INORGANICS (2021)

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Article Chemistry, Inorganic & Nuclear

Lanthanide Complexes with a Tripodal Nitroxyl Radical Showing Strong Magnetic Coupling

Mauro Perfetti et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Mononuclear lanthanide(III)-oxamate complexes as new photoluminescent field-induced single-molecule magnets: solid-state photophysical and magnetic properties

Raphael C. A. Vaz et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Air stable and efficient rare earth Eu(ii) hydro-tris(pyrazolyl)borate complexes with tunable emission colors

Hao Qi et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Optics

Synthesis, spectroscopic properties and applications of divalent lanthanides apart from Eu2+

Markus Suta et al.

JOURNAL OF LUMINESCENCE (2019)

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Luminescent and magnetic bifunctional coordination complex based on a chiral tartaric acid derivative and europium

Mei-rong Han et al.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2019)

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Slow magnetic relaxation in a {EuCu5} metallacrown

Jin Wang et al.

DALTON TRANSACTIONS (2019)

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Slow magnetic relaxation in Cu(ii)-Eu(iii) and Cu(ii)-La(iii) complexes

Malay Dolai et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Nitronyl nitroxide bridged 3d-4f hetero-tri-spin chains: synthesis strategy, crystal structure and magnetic properties

Mei Zhu et al.

CRYSTENGCOMM (2018)

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Article Chemistry, Inorganic & Nuclear

Synthesis, structure and magnetic properties of tris(pyrazolyl) methane lanthanide complexes: effect of the anion on the slow relaxation of magnetization

Jerome Long et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Multidisciplinary

The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*2(RN=)2S], Ln= Sm, Eu, Yb; R= SiMe3

Svetlana V. Klementyeva et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

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Article Chemistry, Multidisciplinary

A family of lanthanide compounds based on nitronyl nitroxide radicals: synthesis, structure, magnetic and fluorescence properties

Xue-Hui Lv et al.

RSC ADVANCES (2017)

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Article Chemistry, Inorganic & Nuclear

Structure and Magnetic Investigation of a Series of Rare Earth Heterospin Monometallic Compounds of Nitronyl Nitroxide Radical

Yuxiao Wang et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2016)

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Synthesis, Crystal Structure, and Magnetic Property of New Trispin Ln(III)-Nitronyl Nitroxide Complexes

Zhe Fan et al.

HELVETICA CHIMICA ACTA (2016)

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Magneto-optical studies of valence instability in europium and terbium phosphors

Lucas C. V. Rodrigues et al.

JOURNAL OF LUMINESCENCE (2016)

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Review Chemistry, Inorganic & Nuclear

Interpretation of europium(III) spectra

Koen Binnemans

COORDINATION CHEMISTRY REVIEWS (2015)

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Slow magnetic relaxation and field-induced metamagnetism in nitronyl nitroxide-Dy(III) magnetic chains

Xiufeng Wang et al.

DALTON TRANSACTIONS (2015)

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Article Chemistry, Inorganic & Nuclear

Synthesis, crystal structure, luminescent and magnetic properties of europium(III) and terbium(III) complexes with a bidentate benzoate and a tripod N7 ligand containing three imidazole, [LnIII(H3L)benzoate](ClO4)2•H2O•2MeOH (LnIII = EuIII and TbIII)

Seira Shintoyo et al.

POLYHEDRON (2015)

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Article Chemistry, Multidisciplinary

Polymer encapsulated scorpionate Eu3+ complexes as novel hybrid materials for high performance luminescence applications

Kelly Machado et al.

RSC ADVANCES (2015)

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Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

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Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

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Structural and magnetic properties of some lanthanide (Ln = Eu(III), Gd(III) and Nd(III)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and Nd substitutions

A. Arauzo et al.

DALTON TRANSACTIONS (2014)

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Complexes of lanthanides with spin-labeled pyrazolylquinoline

E. V. Tretyakov et al.

RUSSIAN CHEMICAL BULLETIN (2014)

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Three new one-dimensional lanthanide complexes bridged by nitronyl nitroxide radicals: Crystal structures and magnetic characterization

Ruina Liu et al.

JOURNAL OF MOLECULAR STRUCTURE (2013)

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Syntheses, crystal structures, magnetic and luminescence properties of five novel lanthanide complexes of nitronyl nitroxide radical

Ya-Li Wang et al.

JOURNAL OF SOLID STATE CHEMISTRY (2013)

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Dinuclear lanthanide complexes bridged by nitronyl nitroxide radical ligands with 2-phenolate groups: structure and magnetic properties

Xuelan Mei et al.

NEW JOURNAL OF CHEMISTRY (2013)

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A Luminescent and Sublimable DyIII-Based Single-Molecule Magnet

Xiaohui Yi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

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Photoluminescent and Magnetic Properties of a Series of Lanthanide Coordination Polymers with 1H-Tetrazolate-5-formic Acid

Mei-Feng Wu et al.

CRYSTAL GROWTH & DESIGN (2011)

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Magnetic and Luminescent Properties of Sm, Eu, Tb, and Dy Coordination Polymers with 2-Hydroxynicotinic Acid

Na Xu et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2011)

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Article Chemistry, Inorganic & Nuclear

Four New Lanthanide-Nitronyl Nitroxide (LnIII=PrIII, SmIII, EuIII, TmIII) Complexes and a TbIII Complex Exhibiting Single-Molecule Magnet Behavior

Jin-Xia Xu et al.

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OLEX2: a complete structure solution, refinement and analysis program

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Synthesis and solid-state structures of pyrazolylmethane complexes of the rare earths

Andrea Sella et al.

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Crystal structures and magnetic and luminescent properties of a series of homodinuclear lanthanide complexes with 4-cyanobenzoic ligand

Yan Li et al.

INORGANIC CHEMISTRY (2006)

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Antiferromagnetic coupling between rare earth ions and semiquinones in a series of 1 : 1 complexes

A Caneschi et al.

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Tetrabutylammonium tetrakis(nitrato-κ2O,O′)-[1,3,5-tris(pyrazolyl)methane-κ3N]cerate(III)

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Systematic investigation of the nature of the coupling between a Ln(III) ion (Ln = Ce(III) to Dy(III)) and its aminoxyl radical ligands.: Structural and magnetic characteristics of a series of {Ln(organic radical)2} compounds and the related {Ln(Nitrone)2} derivatives

ML Kahn et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

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The Synthesis, Crystal Structure, and Magnetic Properties of Mono-Scorpionate Eu(III) Complexes

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