期刊
CHEMICAL SOCIETY REVIEWS
卷 44, 期 5, 页码 1070-1082出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00347k
关键词
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资金
- 973 Program [2011CB808600, 2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
- Program of Introducing Talents of Discipline to Universities of China (111 Program)
Direct olefinic C-H functionalization represents the ideal way of introducing an alkenyl group into organic molecules. A well-known process is the Heck reaction, which involves alkene insertion and beta-hydride elimination in the presence of a transition metal. However, the traditional Heck reaction mainly deals with the alkenylation of aryl or vinyl electrophiles. Recent developments have revealed that alkenylation can also be achieved through radical addition to alkenes and following single-electrontransfer (SET) oxidation/elimination. The radical alkenylation pathway allows alkenylation with a variety of carbon-centered radicals and even heteroatom-centered radicals. This tutorial review gives an overview of recent advances in this emerging field.
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