期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 16-17, 页码 3727-3731出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500583
关键词
asymmetric synthesis; chiral alcohols; hydrosilylation; reduction; zinc
资金
- Polish National Science Center [NCN 2012/07/B/ST5/00909]
Zinc acetate complexes with a chiral diphenylethylenediamine (DPEDA)-derived ligand have been proved to be efficient catalysts for the enantioselective hydrosilylation of aryl ketones. Replacing pyrophoric dialkylzinc with the readily available zinc salt simplifies the procedures and provides excellent conversions (up to >99%) and enantioselectivities (ees up to 97%).
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