4.8 Review

Photo-responsive pseudorotaxanes and assemblies

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CHEMICAL SOCIETY REVIEWS
卷 44, 期 3, 页码 663-676

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00295d

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  1. DST (India)
  2. CSIR (India)
  3. CSIR

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Chemists have achieved a predictable control over various non-covalent interactions and have used these weak interactions in their favour for developing a plethora of intricate functional structures. In this tutorial review we have summarized reports on such supramolecular structures that describe the rational approach in designing host and/or guest components, tagged with an appropriate fluorophore, for achieving the modified optical responses on formation of an assembly. This has relevance for designing new photo-responsive smart or adaptive stimuli responsive functional materials, self- healable materials, with interesting photo-physical property. These are also important in the area of supramolecular chemistry and biophysical chemistry in predicting the relative conformation in solution.

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