期刊
CHEMICAL SOCIETY REVIEWS
卷 44, 期 1, 页码 291-314出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00239c
关键词
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资金
- National Natural Science Foundation of China [21302171, 21376058]
- Science and Technology Plan of Zhejiang Province [2014C31153]
- Zhejiang Provincial Natural Science Foundation of China [LZ13B020001]
- Key-Sci-Tech Innovation Team of Zhejiang Province [2010R50017]
- National University of Singapore
- Ministry of Education
- Agency for Science, Technology and Research (A*Star) of Singapore [R-143-000-426-305, R143-000-426-331]
- National Research Foundation and the Economic Development Board [COY-15-EWI-RCFSA/N197-1]
- Materials Research Engineering [IMRE/12-1P0907]
The development of mild and general methods for C-S bond formation has received significant attention because the C-S bond is indispensable in many important biological and pharmaceutical compounds. Early examples for the synthesis of C-S bonds are generally limited to the condensation reaction between a metal thiolate and an organic halide. Recent chemical approaches for C-S bond formation, based upon direct C-H bond functionalization and decarboxylative reactions, not only provide new insights into the mechanistic understanding of C-S coupling reactions but also allow the synthesis of sulfur-containing compounds from more effective synthetic routes with high atom economy. This review intends to explore recent advances in C-S bond formation via C-H functionalization and decarboxylation, and the growing opportunities they present to the construction of complex chemical scaffolds for applications encompassing natural product synthesis, synthetic methodology development, and functional materials as well as nanotechnology.
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