期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 18, 页码 3917-3926出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500627
关键词
dihydroquinolines; Horner-Wadsworth-Emmons (HWE) reaction; N-arylation; quinolones
资金
- KRICT [SI-1504]
A series of 1,2- and 1,4-dihydroquinolines has been successfully prepared. The Pd-catalyzed intramolecular N-arylation of Z-enamines, formally prepared by the Horner-Wadsworth-Emmons olefination, proceeded efficiently to furnish the cyclized products. Depending on the cyclization conditions, substituted 1,4-dihydroquinolines and further isomerized 1,2-dihydroquinolines were independently obtained in high yields with an excellent control of isomerization of the double bond.
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