期刊
CHEMICAL REVIEWS
卷 115, 期 22, 页码 12286-12319出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.5b00320
关键词
-
资金
- Russian government [14.B25.31.0005]
- Russian Foundation for Basic Research [13-07-00001]
- Russian Ministry of Science and Education
This review focuses on topological features of three-periodic (framework) p, d, and f metal cyano complexes or cyanometallates, i.e. coordination compounds, where CN- ligands play the main structure-forming role. In addition, molecular, one-periodic (chain), and two-periodic (layer) cyanometallates are considered as possible building blocks of the three-periodic cyanometallates. All cyanometallates are treated as systems of nodes (mononuclear, polynuclear, or transitional metal cluster complexes) joined together via CN-containing spacers. The most typical nodes and spacers as well as methods of their connection are described and systematized. Particular attention is paid to the overall structural motifs in the three-periodic cyanometallates, especially to the relations between the local coordination (coordination figure) of structural units and the entire framework topology. The chemical factors are discussed that influence the cyanometallate topological properties due to modification of nodes, spacers, or coordination figures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据