4.4 Article

Bifunctional Salen-Cu(II) Complex as Efficient Catalyst for N-Arylation of Imidazoles and Suzuki-Miyaura Coupling Reactions

期刊

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
卷 31, 期 4, 页码 549-552

出版社

HIGHER EDUCATION PRESS
DOI: 10.1007/s40242-015-4437-3

关键词

Salen-Cu(II) complex; Homogenous catalysis; Cross-coupling; N-Arylation

资金

  1. National Natural Science Foundation of China [20672054]
  2. Scientific Research Fund of Yunnan Provincial Department of Education, China [22012Z020]

向作者/读者索取更多资源

Bifunctional Salen-Cu(II) complex catalyzed cross-coupling reactions of aryl halids with imidazoles or phenylboronic acid reagents have been developed as practical methods for C-N and C-C bond formation. The procedure tolerates aryl halides with various functional groups(such as methoxy, acetyl, nitrile, fluoro and nitro groups) and gives the corresponding coupling products in moderate to high yields. The catalyst remained active after five successive catalytic runs without loss in performance.

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