期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 5, 页码 1065-1069出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400856
关键词
2-aminothiazoles; azides; green chemistry; homogeneous catalysis; iron
资金
- Science Technology Department of Zhejiang Province [2012C33065]
- Education Department of Zhejiang Province [Y201223193]
- National Science Foundation of China [81072516]
- Program for Zhejiang Leading Team of ST Innovation [2011R50014]
A simple protocol to prepare the privileged 2-aminothiazoles promoted by ferrous sulfate heptahydrate via C-N bond formation from vinyl azides and commercially available potassium thiocyanate has been developed. A wide range of vinyl azides are tolerated to afford the expected polysubstituted 2-aminothiazoles in reasonably good yields. The use of the non-toxic substrates and catalyst renders the reaction more environmentally friendly than traditional approaches.
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