Improvement of the photocatalytic activity of ZnO thin films doped with manganese

In the herein report, we synthesized ZnO thin films doped with manganese (Mn). We studied the impact of Mn doping loads (1 %, 3 %, 5 % wt.) on physicochemical properties of the compounds. Furthermore, we presented the photocatalytic efficiency in removal of methylene blue dye. The structural assay indicated ZnO conserve the wurtzite crystalline structure after dopant insertion. Furthermore, the crystalline size of catalysts was reduced after dopant incorporation. The SEM analysis showed a change in surface morphology after modification of ZnO thin films. Further-more, Raman spectroscopy verified the Mn insertion inside the ZnO lattice. After the doping process, band gap was reduced by 16 %, in comparison to bare ZnO. After the photocatalytic test, the doped catalysts showed better performance than bare ZnO in removing MB. The best test showed a kinetics constant value of 2.9 x 10-3 min-1 after 120 min of visible irradiation. Finally, the Mn(5 %):ZnO thin film was suitable after five degradation cycles, and the degradation process efficiency was reduced by 32%.

Automated summary

In this study, we synthesized Mn-doped ZnO thin films and investigated the effects of doping loads on the physicochemical properties of the compounds. The results showed that doping altered the structure, crystalline size, and surface morphology of ZnO, while also reducing the band gap. Furthermore, the doped catalysts exhibited improved photocatalytic performance in dye removal compared to bare ZnO.