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Applications of zinc indium sulfur-based photoelectrodes

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Metal-Free Phosphorus-Doped ZnIn2S4 Nanosheets for Enhanced Photocatalytic CO2 Reduction

Jiani Qin et al.

Summary: ZnIn2S4 (ZIS) with phosphorus doping (P-ZIS) nanosheets were successfully synthesized and demonstrated to enhance the photocatalytic performance of ZIS, with the optimal ZIS to NaH2PO4 ratio being 1:15. Optimized P-ZIS showed a significant increase in visible-light photocatalytic CO production rate, providing important guidance for the design and synthesis of efficient photocatalysts through nonmetal heteroatom doping.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Biophysics

Design of ultrathin nanosheet subunits ZnIn2S4 hollow nanocages with enhanced photoelectric conversion for ultrasensitive photoelectrochemical sensing

Jingjun Peng et al.

Summary: In this study, a high-efficiency photoactive material, hollow ZnIn2S4 nanocages, was synthesized through a metal-organic framework (MOF) derived method. When combined with TiO2 modified electrode, the ZIS-HNCs exhibited intense transient photocurrent and were utilized to establish a signal-off photoelectrochemical (PEC) aptasensor for sensitive detection of lincomycin. This study provides a promising strategy for designing nanomaterials with superior photoelectric activity for PEC sensing applications.

BIOSENSORS & BIOELECTRONICS (2021)

Article Environmental Sciences

An on-off-super on photoelectrochemical sensor based on quenching by Cu-induced surface exciton trapping and signal amplification of copper sulfide/porous carbon nitride heterojunction

Dong Liang et al.

Summary: The use of porous carbon nitride as a photoelectric transducer in a unique on-off-super on strategy allowed for the successful detection of hydrogen sulfide in water, demonstrating excellent stability, selectivity, sensitivity, and low fabrication cost.

CHEMOSPHERE (2021)

Review Materials Science, Multidisciplinary

Novel Z-Scheme ZnIn2S4-based photocatalysts for solar-driven environmental and energy applications: Progress and perspectives

Yogesh Kumar et al.

Summary: Z-scheme heterostructures of ZnIn2S4 based photocatalysts have gained significant interest due to their strong redox ability, improved charge transport, and enhanced charge separation. This review highlights the promising properties of ZnIn2S4 as a photocatalyst and its combination with oxidation photocatalyst to form Z-scheme, leading to remarkable improvement in photocatalytic performance.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Analytical

CdSe quantum dots-decorated ZnIn2S4 nanosheets for signal-on photoelectrochemical aptasensing of ATP by integrating exciton energy transfer with exciton-plasmon coupling

Xinjia He et al.

Summary: CdSe quantum dots-decorated ZnIn2S4 nanosheets exhibit high photoelectrochemical activity for sensitive ATP detection by integrating exciton energy transfer and exciton-plasmon coupling.

SENSORS AND ACTUATORS B-CHEMICAL (2021)

Article Engineering, Chemical

Rational design of direct Z-scheme heterostructure NiCoP/ZIS for highly efficient photocatalytic hydrogen evolution under visible light irradiation

Huihui Song et al.

Summary: Construction of Z-scheme heterojunctions is an efficient strategy to improve charge-separation efficiency for solar energy conversion. In this study, a novel direct Z-scheme catalyst of NiCoP/ZIS was designed and prepared, showing enhanced photocatalytic hydrogen production performance. This work provides a promising approach for rational design of efficient visible-light-driven photocatalysts.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Review Chemistry, Multidisciplinary

Engineering Nanostructure-Interface of Photoanode Materials Toward Photoelectrochemical Water Oxidation

Rui Tang et al.

Summary: Nanostructure-interface engineering has been proven effective in constructing highly efficient PEC water oxidation photoanodes, but the relationship between the nanostructure and interface of photoanode materials and their PEC performance remains unclear. This review briefly presents the PEC water oxidation reaction mechanism and evaluation criteria, and summarizes the theoretical basis and research status of nanostructure-interface engineering for constructing high-performance PEC water oxidation photoanodes. Current challenges and future opportunities in nanostructure-interface engineering for PEC reactions are also discussed.

ADVANCED MATERIALS (2021)

Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks and their derivatives-modified photoelectrodes for photoelectrochemical applications

Meiying Jia et al.

Summary: MOFs-based photoelectrodes can address issues in photocatalysis, regulate PEC activity at the molecular level, increase the contact area between electrolyte and electrode, and facilitate the diffusion of reaction substrate within the electrode.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Surface Sulfate Ion on CdS Catalyst Enhances Syngas Generation from Biopolyols

Zhe Zhang et al.

Summary: The study reports a novel method to increase the efficiency of photocatalytic biomass conversion by creating surface sulfate ions on the CdS catalyst to enhance electron and proton transfer. This method enables CdS catalyst to efficiently produce syngas from various sugars and reduce CO2 emissions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Energy & Fuels

A Review and Recent Developments in Full-Spectrum Photocatalysis using ZnIn2S4-Based Photocatalysts

Yanyan Song et al.

Summary: Photocatalytic technology is considered an efficient method for addressing global energy shortage and environmental pollution, with metal sulfide-based semiconductors like ZnIn2S4 (ZIS) attracting attention for their stability and simple synthesis methods. Recent research has focused on developing a variety of ZIS composite nanostructures and exploring the applications of ZIS-based photocatalysts under full-spectrum light irradiation.

ENERGY TECHNOLOGY (2021)

Article Engineering, Chemical

Corrosion and protection of galvanized steel in vegetation-growing concrete (II): Coating protection

Shiyuan Xiong et al.

Summary: The graphene-modified epoxy coating developed in this study showed excellent corrosion resistance for galvanized steel in vegetation-growing concrete under marine environment, exhibiting superior barrier properties.

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING (2021)

Article Chemistry, Multidisciplinary

The CdIn2S4/WO3 Nanosheet Composite Has a Significantly Enhanced Photo-electrochemical Cathodic Protection Performance and Excellent Electron Storage Capability

Yuying Yang et al.

Summary: Photo-electrochemical cathodic protection (CP) technology utilizes solar energy to protect metals from corrosion without consuming anode materials. A CdIn2S4/WO3 nanocomposite photoelectrode was prepared in this study, showing significantly enhanced CP performance due to the band matching and electron storage capability. This research contributes to the practical application of photo-electrochemical CP by demonstrating the continuous corrosion protection provided by the nanocomposite material.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Review Energy & Fuels

Review on Solar Hydrogen: Its Prospects and Limitations

Suman Dutta

Summary: This review explores various routes for hydrogen generation using solar energy as the primary resource, highlighting the popularity of solar photovoltaic cells combined with water electrolyzers and the potential of biomass conversion for hydrogen production. Economic analysis confirms the viability of hydrogen-fueled cars in terms of both cost-effectiveness and environmental benefits.

ENERGY & FUELS (2021)

Article Chemistry, Physical

Boosted photoinduced cathodic protection performance of ZnIn2S4/TiO2 nanoflowerbush with efficient photoelectric conversion in NaCl solution

Xuhong Jiang et al.

Summary: A green and environmentally friendly three-dimensional ZnIn2S4/TiO2 nanoflowerbush photoelectrode was constructed, showing excellent photoinduced cathodic protection performance for metallic materials and great potential for applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Construction homojunction and co-catalyst in ZnIn2S4 photoelectrode by Co ion doping for efficient photoelectrochemical water splitting

Hongxia Qian et al.

Summary: In this study, Co2+ was incorporated into ZnIn2S4 to form a homojunction, promoting carrier separation and transfer efficiency, resulting in significantly higher photocurrent density and charge efficiencies than pure ZnIn2S4.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Construction of p-n junctions in single-unit-cell ZnIn2S4 nanosheet arrays toward promoted photoelectrochemical performance

Yu Wu et al.

Summary: The p-n junctions based on ZIS nanosheet arrays show unique carrier separation/transport characteristics, with the n-ZIS-P photoelectrode delivering the highest photogenerated current density and nearly perfect Faradaic efficiency among all reported ZIS-based photoanodes.

JOURNAL OF CATALYSIS (2021)

Review Materials Science, Multidisciplinary

A review: Synthesis, modification and photocatalytic applications of ZnIn2S4

Jie Wang et al.

Summary: ZnIn2S4, as a promising photocatalytic material, with its wide light absorption range and tunable bandgap, has been widely applied in various fields in recent years. This review introduces the crystal structures, preparation methods, and applications of ZnIn2S4 in photocatalytic systems.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Analytical

Enhanced two-electrode photoelectrochemical biosensing platform amplified by bilirubin oxidase labelling

Yibin Lu et al.

Summary: A novel and robust two-electrode photoelectrochemical biosensing platform amplified by bilirubin oxidase labeling was reported, showing high sensitivity and good selectivity. By separating biorecognition with the photoanode, the platform presents a promising path for applying in complex biological samples.

SENSORS AND ACTUATORS B-CHEMICAL (2021)

Article Chemistry, Physical

Incorporation of Sulfate Anions and Sulfur Vacancies in ZnIn2S4 Photoanode for Enhanced Photoelectrochemical Water Splitting

Weiwei Xu et al.

Summary: This study developed a new method to enhance the photoelectrochemical performance of ZnIn2S4 photoanodes by introducing sulfate anions and controlled sulfur vacancies, improving the oxygen evolution reaction kinetics and carrier separation efficiency.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Physical

ZnIn2S4-Based Photocatalysts for Energy and Environmental Applications

Ruijie Yang et al.

Summary: Zinc indium sulfide (ZnIn2S4) as a visible-light-responsive photocatalyst has attracted interdisciplinary interest due to its nontoxicity, suitable band gap, and high stability. This review provides an overview of recent advances in ZnIn2S4-based photocatalysts, including crystal structures, modulation strategies, potential applications, and personal perspectives on the material's promises and prospects.

SMALL METHODS (2021)

Article Chemistry, Physical

Insight into the Active Site in Electrochemical CO2 Reduction of Self-Supported Cobalt Phthalocyanine Anchored on ZnIn2S4 Nanoarrays

Hong-Lin Zhu et al.

Summary: The study successfully demonstrated the electrocatalytic reduction of CO2 into value-added fuels by anchoring self-supported cobalt phthalocyanine on chrysanthemum-like ZnIn2S4 nanoarray electrode. Experimental and computational analyses revealed that the active site for CO2 reduction was attributed to Co sites, while for hydrogen evolution reaction, it was mainly ascribed to the S site on the surface of ZIS.

ACS APPLIED ENERGY MATERIALS (2021)

Review Chemistry, Physical

Recent advances and the design criteria of metal sulfide photocathodes and photoanodes for photoelectrocatalysis

Cui Ying Toe et al.

Summary: Metal sulfides are promising materials for photoelectrochemical applications due to their favorable light absorption ability and tunable structural and optical properties. They can be used as photocathodes and/or photoanodes in PEC systems, with the potential to improve charge transfer and consumption capabilities by constructing composite photoelectrodes. This review assesses recent publications on metal sulfide photoelectrodes for PEC applications, highlighting the importance of key design strategies and differences in fabricating metal sulfide photocathodes and photoanodes.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

A promising ternary sulfide bidirectional p-n heterojunction for unassisted tandem photoelectrochemical cells

Hongxia Qian et al.

Summary: This study investigated the photoelectrochemical performance of ternary sulfide photoelectrodes with the same nanostructure and applied bidirectional p-n heterojunctions. The use of ZnIn2S4/CuInS2 and CuInS2/ZnIn2S4 as photoanode and photocathode in the unassisted tandem PEC cell device achieved a relatively high photocurrent density of 0.06 mA cm(-2), providing new ideas for the design and manufacture of high-efficiency unassisted tandem PEC cell devices.

CHEMICAL COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

A highly efficient photoelectrochemical sensor for detection of chlorpyrifos based on 2D/2D β-Bi2O3/g-C3N4 heterojunctions

Haixia Wang et al.

Summary: The 2D/2D Z-scheme beta-Bi2O3/g-C3N4 heterojunctions can selectively and sensitively detect chlorpyrifos, showing higher photocurrent response. The Bi-chlorpyrifos complex formed after exposure to chlorpyrifos blocks the transformation of photogenerated charges, leading to a significant decrease in photocurrent signal intensity.

ENVIRONMENTAL SCIENCE-NANO (2021)

Article Chemistry, Analytical

Graphitic carbon nitride homojunction films for photocathodic protection of 316 stainless steel and Q235 carbon steel

Xiong Zhang et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

Review Chemistry, Analytical

Recent advances in photoelectrochemical biosensors for analysis of mycotoxins in food

Qian Zhou et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2020)

Review Chemistry, Multidisciplinary

Role of Vacancies in Photocatalysis: A Review of Recent Progress

Minhua Ai et al.

CHEMISTRY-AN ASIAN JOURNAL (2020)

Article Chemistry, Analytical

Novel molecularly imprinted photoelectrochemical sensor for rutin based on Bi2S3/ZnIn2S4 heterojunction

Jiajia Xi et al.

SENSORS AND ACTUATORS B-CHEMICAL (2020)

Article Chemistry, Multidisciplinary

Enhancing photoelectrochemical performance of ZnIn2S4 by phosphorus doping for sensitive detection of miRNA-155

Hongyan Liu et al.

CHEMICAL COMMUNICATIONS (2020)

Review Chemistry, Physical

g-C3N4-based photoelectrodes for photoelectrochemical water splitting: a review

Xingyue Zou et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Multidisciplinary

Crystal Facet Engineering of Photoelectrodes for Photoelectrochemical Water Splitting

Songcan Wang et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Analytical

The photoelectrocatalytic performance of ZnIn2S4 nanosheets and microspheres grown on flexible graphite felt

Bo Gao et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

3D Hierarchical ZnIn2S4 Nanosheets with Rich Zn Vacancies Boosting Photocatalytic CO2 Reduction

Yiqiang He et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Chemistry, Analytical

Robust photoelectrochemical cytosensor in biological media using antifouling property of zwitterionic peptide

Gao-Chao Fan et al.

SENSORS AND ACTUATORS B-CHEMICAL (2019)

Review Chemistry, Multidisciplinary

Toward practical solar hydrogen production - an artificial photosynthetic leaf-to-farm challenge

Jin Hyun Kim et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Materials Science, Multidisciplinary

Titanium dioxide nanostructures for photoelectrochemical applications

Shaohua Shen et al.

PROGRESS IN MATERIALS SCIENCE (2018)

Article Chemistry, Multidisciplinary

Defect-Mediated Electron-Hole Separation in One-Unit-Cell ZnIn2S4 Layers for Boosted Solar-Driven CO2 Reduction

Xingchen Jiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Layered crystalline ZnIn2S4 nanosheets: CVD synthesis and photo-electrochemical properties

Wenjin Yang et al.

NANOSCALE (2016)

Article Nanoscience & Nanotechnology

Photoelectrochemical Biosensor Using Enzyme-Catalyzed in Situ Propagation of CdS Quantum Dots on Graphene Oxide

Xianxiang Zeng et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

Article Nanoscience & Nanotechnology

2D ZnIn2S4 Nanosheet/lD TiO2 Nanorod Heterostructure Arrays for Improved Photoelectrochemical Water Splitting

Qiong Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

Review Chemistry, Multidisciplinary

Roles of Cocatalysts in Photocatalysis and Photoelectrocatalysis

Jinhui Yang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Article Chemistry, Multidisciplinary

Energy transfer between CdS quantum dots and Au nanoparticles in photoelectrochemical detection

Wei-Wei Zhao et al.

CHEMICAL COMMUNICATIONS (2011)

Article Chemistry, Inorganic & Nuclear

Insights into photoluminescence property and photocatalytic activity of cubic and rhombohedral ZnIn2S4

Shaohua Shen et al.

JOURNAL OF SOLID STATE CHEMISTRY (2011)

Article Energy & Fuels

Photoelectrochemical performance of Cu-doped ZnIn2S4 electrodes created using chemical bath deposition

Kong-Wei Cheng et al.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2011)