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Review
Biochemistry & Molecular Biology
Idoia Urriza-Arsuaga et al.
Summary: In recent decades, there has been a growing demand for new molecular recognition elements to improve analytical methods and achieve the detection/quantification limits of target molecules. Molecularly imprinted polymers (MIPs) with molecular recognition abilities provided by template molecules during synthesis are excellent materials for sample preparation with high selectivity. They can replace antibodies or enzymes in various assays and have been successfully applied in chromatographic or solid-phase extraction methods as well as sensors and catalysis. This paper provides a comprehensive comparison of the new challenges in molecular imprinting as future materials in Spain.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Review
Biochemistry & Molecular Biology
Guangli Zhao et al.
Summary: The abuse and residues of antibiotics have a significant impact on the environment and organisms, making their determination crucial. Molecularly imprinted polymers (MIPs), prepared via molecular imprinting technology (MIT), have found wide applications in the analytical detection of antibiotics. This review discusses the recent advances in MIPs for antibiotic residue analysis.
Review
Biochemistry & Molecular Biology
Yan Zhang et al.
Summary: This review summarizes recent reports of stimuli-responsive nanomaterials based on molecularly imprinted polymers (MIPs) and discusses their applications in biomedicine. MIPs have shown widespread applications as new molecular recognition materials. Stimuli-responsive nanomaterials have endowed MIPs with affinity properties comparable to natural antibodies and the ability to respond to external stimuli. This review focuses on the synthesis of MIPs, classification of stimuli-responsive MIP nanomaterials, their mechanisms, and applications in biomedicine, particularly after 2015. It aims to contribute to the further exploration and practical applications of stimuli-responsive MIP nanomaterials, especially in biomedicine.
Review
Polymer Science
Semra Akgonullu et al.
Summary: The accurate detection of biological substances such as proteins has always been a hot topic in scientific research. Biomimetic sensors seek to imitate sensitive and selective mechanisms of biological systems and integrate these traits into applicable sensing platforms. Molecular imprinting technology has been extensively practiced in many domains, producing molecular recognition materials with specific capabilities. Molecularly imprinted polymers (MIPs), also known as plastic antibodies, are artificial receptors with high-affinity binding sites for a particular molecule or compound. MIPs for protein recognition are expected to have high affinity through interactions between polymer matrices and functional groups of the target protein. This critical review discusses recent advances in the synthesis, characterization, and application of MIP-based sensor platforms for protein detection.
Article
Chemistry, Multidisciplinary
Amine Khitous et al.
Summary: A new method has been developed to functionalize gold nanoparticles (AuNPs) using nanoscale layers of molecularly imprinted polymers (MIPs). By applying near-field radical photopolymerization, AuNPs@MIPs hybrid nanoparticles are fabricated, enabling sensitive and specific analysis through localized surface plasmon resonance and surface-enhanced Raman spectroscopy (SERS). The MIPs demonstrate high sensitivity and selectivity, as shown by the detection of methylene blue and comparison with non-imprinted control polymers and interference testing with Rhodamine 6G and Rhodamine 110. This fabrication method allows for the creation of robust and reusable sensor surfaces, with the added advantage of shorter analysis times.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Victoriya Popova et al.
Summary: Silica nanoparticles (SiNPs) have great potential in nanomedicine technology due to their stability, biocompatibility, and surface modification capability. This study proposes the synthesis of SiNPs and SiNPs nylon 6 (SiNPs-Nylon) coated nanocomposites. The results show that the DOX-loaded nanocomposites effectively inhibit the A549 and HEK 293FT cell lines, with high drug capacities and low IC50 values. Thus, silica nanocomposites have a promising role in cancer treatment.
Article
Chemistry, Multidisciplinary
Fan Yang et al.
Summary: Novel magnetic molecularly imprinted polymers (CBD-MMIPs) with specific recognizing capability for CBD were successfully synthesized. The CBD-MMIPs showed selective specificity and high adsorption capacity for CBD. The CBD-MMIPs could be used as an efficient adsorbent for the extraction of CBD from hemp leaf sample concentrates with high recovery efficiencies.
Review
Chemistry, Inorganic & Nuclear
Victoriya Popova et al.
Summary: Magnetic nanocomposites (MNCs) combine the features of magnetic nanoparticles and a second material, providing distinct properties for various applications. This review focuses on nucleic acid-based bioapplications of MNCs with different surface coatings and forms. The review also presents the synthesis of MNCs using ready-made magnetic cores and discusses the restrictions and possibilities in the field. Additionally, the most recent advancements of MNCs and imprinted polymers in nucleic acid-based therapies, diagnostics, and biosensing are introduced.
Review
Biochemistry & Molecular Biology
Greta Pilvenyte et al.
Summary: Biomarkers are crucial in providing information about cancer and other diseases. Molecularly imprinted polymers (MIPs) have recently been used in analytical systems to detect cancer biomarkers, such as prostate cancer (PSA), breast cancer (CA15-3, HER-2), ovarian cancer (CA-125), hepatocellular carcinoma (AFP), and small molecule cancer biomarkers (5-HIAA and neopterin). The determination of low concentrations of these biomarkers in complex matrices is challenging, but MIP-based biosensors have been employed for assessment. This article provides an overview of the MIP-based sensor creation principles, analytical signal determination methods, and suitable materials for each biomarker through comparing and discussing the results of reviewed biosensors.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Review
Biochemistry & Molecular Biology
Maria Marinela Lazar et al.
Summary: The introduction of ion-imprinted polymers (IIPs) based on the molecular imprinting methodology has provided an innovative solution for the selective recognition of heavy metal ions (HMIs). Recent advances have demonstrated that IIPs exhibit higher selectivity coefficients, enabling various environmental applications such as extraction, monitoring, detection, and quantification of HMIs. This review critically analyzes relevant literature studies from the past decade, focusing on the selective removal of transition metal ions using IIPs. It discusses the chemical components, ion-imprinting technologies, characterization methods, synthesis parameters, adsorption performance, and solid phase extraction of heavy metal ions by different IIPs.
Review
Pharmacology & Pharmacy
Emilia Balcer et al.
Summary: Simultaneous diagnostics and targeted therapy are important trends in personalized medicine. Molecularly imprinted polymers (MIPs) have great potential as drug carriers due to their stability and integration capabilities. This review focuses on the application of MIPs in theranostics, including their construction strategies and future prospects.
Article
Pharmacology & Pharmacy
Victoriya Popova et al.
Summary: A magnetic nanocomposite (MNC) combines functions of two materials to create a new material with unique properties. The magnetic core of MNC allows for magnetic resonance imaging, targeted delivery, hyperthermia, and other applications. The synthesis of nanoscale Fe3O4@CaCO3 composites using different agents and characterization techniques was proposed. The resulting nanocomposite showed high stability, low cytotoxicity, and efficient drug release for cancer treatment.
Article
Chemistry, Inorganic & Nuclear
Ekaterina Kovrigina et al.
Summary: Nanoplatforms like magnetic nanocomposites (MNCs) and nanocapsules (NCs) show great potential for cancer treatment as they can deliver drugs more effectively and reduce side effects. In this study, nylon-6-coated MNCs and nylon-6 polymeric membrane NCs were developed. The MNCs and NCs demonstrated excellent drug-loading capacity and pH-sensitive drug release properties, inhibiting cancer cell lines. These nanoscale systems offer promising prospects for cancer treatment.
Article
Mariacristina Gagliardi
Advanced Industrial and Engineering Polymer Research
(2023)
Article
Environmental Sciences
Idrees Khan et al.
Summary: The paper discusses the significant health issue of unavailability of clean drinking water in modern society, as well as the toxicity and environmental pollution caused by industrial dyes. By studying photodegradation technology to remove MB, efficient and environmentally friendly water treatment systems can be achieved. The photodegradation mechanism and factors affecting MB are summarized.
Review
Chemistry, Inorganic & Nuclear
Alexey S. Chubarov
Summary: Magnetic nanoparticles have great potential in biochemistry and medical science. This review highlights a method for fabricating biocompatible iron oxide nanoparticles using human serum albumin. Human serum albumin, as a highly abundant plasma protein, plays an important role in the stability and biodistribution of drug-delivery systems.
Review
Chemistry, Multidisciplinary
Komal Poonia et al.
Summary: This review discusses the importance of Magnetic Molecularly Imprinted Polymers (M-MIPs) in the degradation of low-concentration pollutants during water purification. The synergistic effect of adsorption and photocatalysis allows M-MIPs to effectively remove refractory pollutants and selectively bind target molecules.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Chemistry, Analytical
Susana Meseguer-Lloret et al.
Summary: In this study, a selective magnetic molecularly imprinted polymer (MMIP) was successfully synthesized and applied as sorbent in magnetic molecularly imprinted solid-phase extraction (MMISPE) for the selective extraction of a mixture of five herbicides. The optimized MMISPE method combined with HPLC-DAD showed low detection and quantification limits, as well as good accuracy and precision. The MMIP sorbent demonstrated remarkable reusability without loss in extraction capacity.
Review
Polymer Science
Marisa Dwi Ariani et al.
Summary: The development of separation techniques using magnetic molecularly imprinted polymers (MMIPs) shows great promise in sample pretreatment due to their high specificity and selectivity. When used as SPE sorbents, MMIPs can efficiently separate analytes from samples, enhancing the separation efficiency.
Article
Chemistry, Physical
Daliborka Popadic et al.
Summary: In this study, unmodified natural silicates were tested as adsorbents for organic pollutants in water. Bentonite showed the highest adsorption capacity, removing up to 237 mg/g of pollutants. The treated adsorbent was also found to be effective as an electrode material for oxygen reduction, achieving a significant removal rate of Methylene Blue through electrochemical treatment.
Article
Chemistry, Inorganic & Nuclear
Anastasia Bulgakova et al.
Summary: Magnetic Fe3O4 nanoparticles have been widely studied for their potential applications in nucleic acid separation, detection, and delivery. In this study, magnetic nylon 6 nanocomposites were synthesized, and a novel method of UV-induced immobilization of oligonucleotides on these nanocomposites for nucleic acid magnetic separation was proposed. The results showed that the synthesized nanocomposites exhibited high oligonucleotide binding capacity and loading efficiency, making them attractive candidates for nucleic acid-specific magnetic isolation.
Review
Polymer Science
Niky Murdaya et al.
Summary: The multi-template molecularly imprinting polymer (MT-MIP) strategy enables the synthesis of MIP with multiple recognition sites for simultaneous recognition and extraction of multiple analytes. It offers advantages such as lower solvent consumption, cost-effectiveness, and shorter analysis time. This review summarizes the synthesis, factors affecting quality, and applications of MT-MIP, highlighting its potential in chemical isolation and analysis. MT-MIP shows good sensitivity, selectivity, and reusability, making it a promising approach for MIP development and application.
Review
Chemistry, Inorganic & Nuclear
Ashi Mittal et al.
Summary: The use of magnetic nanoparticles in biomedical applications has expanded greatly in the past two decades. These nanoparticles have high potential in drug delivery, magnetic hyperthermia, magnetic resonance imaging, and other fields, but issues such as biocompatibility and drug release need to be addressed for efficient incorporation into physiological systems.
Article
Chemistry, Inorganic & Nuclear
Ekaterina Bobrikova et al.
Summary: The study investigated the formation of a stable complex of iron oxide nanoparticles with oligonucleotides through different factors selection to enhance binding efficiency, and identified the complexes using standard characterization techniques. The experimental results showed that the complexes formed by Fe3O4 MNPs with oligonucleotides exhibited high stability and biocompatibility.
Review
Polymer Science
Mohamadreza Shakiba et al.
Summary: Nylon is a versatile engineering plastic widely used in biomedical applications due to its desirable properties. Despite its usefulness, there is still a need for further research on the interactions between nylon and human body tissues. Researchers are also exploring antimicrobial strategies to improve the potential of nylon materials for long-term contact with tissues.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2021)
Article
Oncology
Ana Luisa G. Silva et al.
Summary: The study proposes the use of a nanocomplex consisting of methylene blue and citrate-coated maghemite nanoparticles (MAGCIT-MB) for the treatment of breast and ovarian cancer. Results from in vitro studies show significant reduction in cell viability of cancer cell lines treated with MAGCIT-MB, without affecting non-tumor cells. This suggests the potential of MAGCIT-MB as a targeted therapy for breast and ovarian cancer.
CANCER NANOTECHNOLOGY
(2021)
Review
Chemistry, Multidisciplinary
Junyu Li et al.
Summary: Magnetic molecularly imprinted polymers (MMIPs) have combined molecular imprinting technology (MIT) and magnetic separation technology, making them a novel material for specific recognition and effective separation of target molecules such as antibiotics. Their integration with conventional analytical methods offers a rapid approach for the separation and determination of antibiotic residues, providing a sensitive and selective method for measuring antibiotics in complex matrices.
FRONTIERS IN CHEMISTRY
(2021)
Article
Polymer Science
Hongfu Meng et al.
Summary: The Fe3O4 magnetic methylene blue molecularly imprinted polymer synthesized via bulk polymerization method showed high adsorption capacity and selectivity for methylene blue. Its adsorption performance was well represented by the Langmuir equation and pseudo-first-order kinetic model, indicating mainly monolayer and chemical adsorption process.
POLYMER SCIENCE SERIES B
(2021)
Article
Biochemical Research Methods
Xiao-Chen Huang et al.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2020)
Review
Chemistry, Inorganic & Nuclear
Tatyana I. Shabatina et al.
Review
Biochemistry & Molecular Biology
Beatriz Fresco-Cala et al.
Review
Pharmacology & Pharmacy
Nasim Sanadgol et al.
Review
Chemistry, Inorganic & Nuclear
Vlad Socoliuc et al.
Review
Chemistry, Inorganic & Nuclear
Maria Hepel
Article
Materials Science, Multidisciplinary
V. L. Kirillov et al.
MATERIALS CHEMISTRY AND PHYSICS
(2019)
Review
Chemistry, Analytical
Mehmet Dinc et al.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2019)
Article
Chemistry, Analytical
Saman Fatima et al.
JOURNAL OF SEPARATION SCIENCE
(2019)
Article
Nanoscience & Nanotechnology
Garima Goyal et al.
ACS APPLIED NANO MATERIALS
(2019)
Article
Chemistry, Analytical
Shou-Lian Wei et al.
JOURNAL OF SEPARATION SCIENCE
(2018)
Article
Chemistry, Analytical
Qingzhou Dai et al.
Article
Chemistry, Analytical
Saeedeh Ansari et al.
Article
Chemistry, Multidisciplinary
Przemyslaw Kowalik et al.
Article
Chemistry, Multidisciplinary
E. M. Reyes-Gallardo et al.
Article
Multidisciplinary Sciences
Jing Li et al.
ROYAL SOCIETY OPEN SCIENCE
(2017)
Article
Biochemical Research Methods
Shoulian Wei et al.
JOURNAL OF CHROMATOGRAPHY A
(2016)
Article
Thermodynamics
Marcela Stoia et al.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2016)
Review
Chemistry, Analytical
Muchuan Niu et al.
Review
Chemistry, Multidisciplinary
Elena V. Dmitrienko et al.
RUSSIAN CHEMICAL REVIEWS
(2016)
Article
Materials Science, Multidisciplinary
Jaime Ibarra et al.
MATERIALS RESEARCH EXPRESS
(2015)
Article
Multidisciplinary Sciences
Xiaoli Zhao et al.
SCIENTIFIC REPORTS
(2015)
Article
Materials Science, Multidisciplinary
Victor L. Kirillov et al.
MATERIALS CHEMISTRY AND PHYSICS
(2014)
Article
Chemistry, Multidisciplinary
Ruixia Gao et al.
Article
Biochemistry & Molecular Biology
E. V. Dmitrienko et al.
JOURNAL OF MOLECULAR RECOGNITION
(2013)
Article
Chemistry, Multidisciplinary
N. Vasanthan
JOURNAL OF CHEMICAL EDUCATION
(2012)
Article
Nanoscience & Nanotechnology
Hassan Mahfuz et al.
