期刊
SURFACES AND INTERFACES
卷 43, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.surfin.2023.103555
关键词
Electrochemical capacitor; Pseudocapacitance; Areal capacitance; Diffusion coefficient
In this study, flower-like nickel cobalt oxide (NiCo2O4) electrode material was prepared by a facile hydrothermal method and its properties were characterized. The obtained results showed that the electrode material exhibited high areal capacity and energy density, surpassing some carbon-based materials.
The surface chemistry and decent morphology of electrode materials are highly desirable for high-performance energy storage/conversion devices. Bimetallic oxides especially nickel cobalt oxide (NCO) have gained substantial attention in energy storage/conversion devices owing to their exclusive electronic properties. Herein, flower-like nickel cobalt oxide (NiCo2O4) was prepared by a facile hydrothermal method for different reaction times. The properties of obtained samples were characterized through X-ray diffraction (XRD), EDS, field-emision scanning electron microscopy (FE-SEM), and high-resolution transmission electron microscopy (HR-TEM). The cyclic voltammogram (CV), Galvanostatic changing discharging (GCD), and electrochemical impedance spectroscopy (EIS) were employed for the evaluation of the electrochemical performances of the resultant product. The flower-like NiCo2O4 electrode exhibits high areal capacity (392 mF cm-2 at 0.5 mA cm-2) and the electrode shows an energy density of about 9.1 mu Wh cm-2 at power density 102 mu W cm-2. The excellent electrochemical performance of the fabricated supercapacitor offers good areal capacitance and energy density that exceeds several carbon-based materials.
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