4.7 Review

Charge-Transfer-Regulated Selective Solar Fuel Production in Aqueous Medium by a Tetrathiafulvalene-Based Redox-Active Metal-Organic Framework

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Visible-Light-Driven Photocatalytic CO2 Reduction to CO/CH4 Using a Metal-Organic Soft Coordination Polymer Gel

Parul Verma et al.

Summary: The self-assembly of a low-molecular weight gelator (LMWG) based on a porphyrin core connected to four terpyridine units (TPY-POR) has been demonstrated, which forms a coordination polymer gel (CPG) with Ru-II ions. The Ru-TPY-POR CPG exhibits efficient CO2 photoreduction, with a high selectivity for CO and CH4 using different sacrificial electron donors.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Chemistry, Multidisciplinary

Conductive metal and covalent organic frameworks for electrocatalysis: design principles, recent progress and perspective

Jinyan Wang et al.

Summary: Metal and covalent organic frameworks (MOFs/COFs) are promising catalyst candidates due to their porous nature, chemically defined active sites, and structural diversity. However, they often lack sufficient electrical conductivity to be effective electrocatalysts. This review highlights the design principles of conductive MOFs/COFs and their recent applications in electrocatalytic reactions, such as CO2RR, water splitting, and ORR. Future challenges and prospects for using conductive MOFs/COFs as electrocatalysts are also discussed.

NANOSCALE (2022)

Article Electrochemistry

A high-performance pseudocapacitive negatrode for lithium-ion capacitor based on a tetrathiafulvalene-cobalt metal-organic framework

Yi-Gang Weng et al.

Summary: Pseudocapacitive negatrodes based on TTF-Co-MOFs show enhanced discharge specific capacity and rate capability, offering competitive performance in terms of specific energy and specific power. The capacitive contribution ratios of TTF-Co-MOFs negatrodes can be finely tuned by adjusting the porosity of MOFs and fabrication composites.

ELECTROCHIMICA ACTA (2022)

Article Chemistry, Multidisciplinary

Engineering Single-Atom Active Sites on Covalent Organic Frameworks for Boosting CO2 Photoreduction

Lei Ran et al.

Summary: This study presents a novel method to enhance the catalytic performance of CO2 reduction by anchoring different metal single-atom sites on a triazine-based covalent organic framework. The synthesized catalyst shows superior CO generation rate and selectivity, achieving efficient CO2 conversion under visible light irradiation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Materials Science, Multidisciplinary

An Electrically Conductive Tetrathiafulvalene-Based Hydrogen-Bonded Organic Framework

Kent O. Kirlikovali et al.

Summary: Recent advancements in conductive metal-organic frameworks and covalent organic frameworks have led to increased interest in leveraging electronic materials due to their tunability, porosity, and crystallinity. Hydrogen-bonded organic frameworks are an emerging class of porous materials with weaker, reversible interactions, presenting challenges in isolation and activation. A novel approach using a tetrathiafulvalene (TTF) core has been developed to create a permanently porous HOF with electrical conductivity, showing promising results in structural characterization studies.

ACS MATERIALS LETTERS (2022)

Article Chemistry, Multidisciplinary

Conductive CuCo-Based Bimetal Organic Framework for Efficient Hydrogen Evolution

Bo Geng et al.

Summary: Incorporation of Co into Cu-CAT nanorod arrays improves the efficiency of hydrogen evolution reaction with lower overpotentials, optimized adsorption energy for hydrogen and water, and acceleration of reaction steps, opening a new pathway for the rational design of highly efficient MOF-based electrocatalysts.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

2D Copper Tetrahydroxyquinone Conductive Metal-Organic Framework for Selective CO2 Electrocatalysis at Low Overpotentials

Leily Majidi et al.

Summary: A 2D copper-based conductive MOF, Cu-THQ, exhibits excellent catalytic activity for aqueous CO2 reduction reaction (CO2RR) with low overpotentials. The material shows high CO production rate and current density at low overpotentials, making it a promising candidate for practical applications in CO2RR.

ADVANCED MATERIALS (2021)

Article Multidisciplinary Sciences

Charge-transfer regulated visible light driven photocatalytic H2 production and CO2 reduction in tetrathiafulvalene based coordination polymer gel

Parul Verma et al.

Summary: This study developed a metal-organic hybrid material that efficiently converts solar energy to hydrogen and reduces CO2 to CO and CH4 through photocatalysis. The material exhibits high catalytic activity regulated by charge-transfer interactions.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Tricycloquinazoline-Based 2D Conductive Metal-Organic Frameworks as Promising Electrocatalysts for CO2 Reduction

Jingjuan Liu et al.

Summary: 2D conductive metal-organic frameworks (2D c-MOFs) based on nitrogen-rich tricycloquinazoline (TQ) ligands show promise as efficient electrocatalysts for the CO2 reduction reaction (CO2RR), with Cu-3(HHTQ)(2) exhibiting superior catalytic activity and selectivity for CH3OH production. The performance of the catalyst is strongly influenced by the choice of metal centers and nitrogen-rich ligands.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal-Organic Framework

Dardan Ukaj et al.

Summary: Electrically conductive metal-organic frameworks show potential for next-generation electronic devices. The incorporation of guest molecules in porous structures creates charge transport pathways. Vibrational spectroscopy is a powerful tool for understanding host-guest interactions and enhancing electrical conductivity in MOFs.

CHEMISTRY OF MATERIALS (2021)

Article Multidisciplinary Sciences

Modulating electron density of vacancy site by single Au atom for effective CO2 photoreduction

Yuehan Cao et al.

Summary: The surface electron density significantly affects the photocatalytic efficiency, which can be manipulated by regulating the direction of electron transfer through CdS vacancy types and controlling the size of Au nanostructures. This manipulation leads to effective CO2 photoreduction by increasing the availability of electrons for the reduction process.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Conductive Two-Dimensional Phthalocyanine-based Metal-Organic Framework Nanosheets for Efficient Electroreduction of CO2

Jun-Dong Yi et al.

Summary: Metal-organic frameworks (MOFs) are promising alternatives for CO2RR due to their periodic arrangement of isolated metal active sites, but traditional MOFs have poor conductivity. Researchers have prepared conductive 2D phthalocyanine-based MOF nanosheets, which exhibit a high efficiency and selectivity for CO production.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Selective photocatalytic reduction CO2 to CH4 on ultrathin TiO2 nanosheet via coordination activation

Zhi-Wen Wang et al.

Summary: Ultra-thin TiO2 nanosheet (NST) with abundant Ti3+ sites has been developed as a photocatalyst for high yield and selectivity in the conversion of CO2 to CH4. The NST selectively activates CO2 on its surface, forming bridging Ti dot CO2-Ti coordination species to lower the activation energy barrier and determine the selectivity for CH4 production via Ti-C coordination bond.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Review Green & Sustainable Science & Technology

Metal-Organic Frameworks for Photo/Electrocatalysis

Junkuo Gao et al.

Summary: Metal-organic frameworks (MOFs) composed of metal clusters/ions and organic ligands are ideal materials for photo/electrocatalysis due to their large surface areas, high porosity, and tunable optical and electronic structures. Recent advances in MOF-based photo/electrocatalysts, including pristine MOFs, MOF composites, and MOF derivatives, as well as novel strategies to improve performance have been summarized. The current challenges and future development of MOFs for photo/electrocatalysis are also discussed and outlined.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Article Chemistry, Multidisciplinary

Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO2 reduction in water

Sanchita Karmakar et al.

Summary: The study reports the successful design and synthesis of Zr-MBA-Ru/Re-MOF for photocatalytic CO2 reduction, demonstrating high catalytic activity and selectivity in aqueous medium. Covalent immobilization of the photosensitizer and catalyst enhances the lifetime of photoexcited electrons and shortens charge carrier transport distance, leading to efficient CO2 reduction. In situ DRIFT characterization of reaction intermediates and DFT calculations support the established catalytic cycle involving the reaction mechanism.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Inorganic & Nuclear

Recent progress in pristine MOF-based catalysts for electrochemical hydrogen evolution, oxygen evolution and oxygen reduction

Lili Fan et al.

Summary: Metal-organic frameworks (MOFs) are seen as promising electrocatalysts for hydrogen evolution, oxygen evolution, and oxygen reduction reactions, but there are still challenges in terms of activity, conductivity, and identifying real active sites. Advanced strategies such as microstructure engineering and conductivity improvement are being explored to address these issues.

DALTON TRANSACTIONS (2021)

Article Chemistry, Physical

Stabilization of ultra-small gold nanoparticles in a photochromic organic cage: modulating photocatalytic CO2 reduction by tuning light irradiation

Ashish Singh et al.

Summary: This study successfully stabilized ultra-small metal nanoparticles using a photochromic organic cage, allowing for visible-light-driven photocatalytic CO2 reduction. By irradiating with light of the full range, a wide spectrum absorption was achieved, leading to enhanced performance in the photocatalytic CO2 reduction process.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Physical

Atomic-Level Reactive Sites for Semiconductor-Based Photocatalytic CO2 Reduction

Yanzhao Zhang et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Multidisciplinary

Electrically Conductive Metal-Organic Frameworks

Lilia S. Xie et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Multidisciplinary

Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal-Organic Framework

Yan Zhou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Inorganic & Nuclear

Recent advances in MOF-based photocatalysis: environmental remediation under visible light

Qi Wang et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

Review Chemistry, Multidisciplinary

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Chemistry, Multidisciplinary

Metal-Organic-Framework-Based Catalysts for Photoreduction of CO2

Rui Li et al.

ADVANCED MATERIALS (2018)

Review Chemistry, Multidisciplinary

Conductive two-dimensional metal-organic frameworks as multifunctional materials

Michael Ko et al.

CHEMICAL COMMUNICATIONS (2018)

Review Chemistry, Multidisciplinary

Two-dimensional metal-organic framework nanosheets: synthesis and applications

Meiting Zhao et al.

CHEMICAL SOCIETY REVIEWS (2018)

Article Chemistry, Multidisciplinary

Nature-based catalyst for visible-light-driven photocatalytic CO2 reduction

Zhifeng Jiang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

The role of reticular chemistry in the design of CO2 reduction catalysts

Christian S. Diercks et al.

NATURE MATERIALS (2018)

Review Chemistry, Inorganic & Nuclear

Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes

Yusuke Kuramochi et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Review Chemistry, Physical

Metal-organic frameworks (MOFs) for photocatalytic CO2 reduction

Yi Chen et al.

CATALYSIS SCIENCE & TECHNOLOGY (2017)

Review Chemistry, Multidisciplinary

CO2 Reduction: From the Electrochemical to Photochemical Approach

Jinghua Wu et al.

ADVANCED SCIENCE (2017)

Review Chemistry, Multidisciplinary

Electrocatalytic Metal-Organic Frameworks for Energy Applications

Courtney A. Downes et al.

CHEMSUSCHEM (2017)

Review Chemistry, Inorganic & Nuclear

Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives

Hai-Ying Wang et al.

COORDINATION CHEMISTRY REVIEWS (2017)

Review Chemistry, Multidisciplinary

Electrically Conductive Porous Metal-Organic Frameworks

Lei Sun et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Multidisciplinary Sciences

Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2

Elise M. Miner et al.

NATURE COMMUNICATIONS (2016)

Article Chemistry, Inorganic & Nuclear

Efficient Photocatalysts for CO2 Reduction

Go Sahara et al.

INORGANIC CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

Cation-Dependent Intrinsic Electrical Conductivity in lsostructural Tetrathiafulvalene-Based Microporous Metal-Organic Frameworks

Sarah S. Park et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Two-Dimensional Metal-Organic Surfaces for Efficient Hydrogen Evolution from Water

Andrew J. Clough et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Review Chemistry, Multidisciplinary

Metal-organic frameworks for artificial photosynthesis and photocatalysis

Teng Zhang et al.

CHEMICAL SOCIETY REVIEWS (2014)

Article Chemistry, Multidisciplinary

High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal-Organic Graphene Analogue

Dennis Sheberla et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Editorial Material Chemistry, Multidisciplinary

Introduction to Metal-Organic Frameworks

Hong-Cai Zhou et al.

CHEMICAL REVIEWS (2012)

Review Chemistry, Multidisciplinary

Electrical conductive coordination polymers

Gonzalo Givaja et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Chemistry, Multidisciplinary

High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal-Organic Framework

Tarun C. Narayan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Physical

Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

L. C. Grabow et al.

ACS CATALYSIS (2011)