期刊
ACS APPLIED ENERGY MATERIALS
卷 6, 期 20, 页码 10585-10592出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.3c01737
关键词
Zn ion hybrid supercapacitor; water-in-DES; ZnCl2-based electrolyte; wide ESW; goodstability; N-rGO electrode
Zinc ion hybrid supercapacitors (ZIHSs) are reliable alternatives for future energy applications, but the poor cycle reversibility of Zn metal anodes in aqueous electrolytes limits their practical use. In this study, a deep eutectic solvent (DES) prepared by mixing ZnCl2 and urea with a small amount of water showed significantly suppressed side reactions and dendrite growth in ZIHS, resulting in improved electrochemical stability, cycling stability, and coulombic efficiency.
Zinc ion hybrid supercapacitors (ZIHSs) with low cost, high safety, and high capacity density are considered reliable alternatives for future energy applications. However, the poor cycle reversibility of Zn metal anodes in aqueous electrolytes hinders their further practical application, mainly due to dendrite growth and water-induced parasitic reactions. Herein, we have prepared a deep eutectic solvent (DES) by mixing ZnCl2 and urea and added a very small amount of water to optimize the utilization of this DES as an electrolyte for ZIHS. This DES has significantly suppressed the side reactions and dendrite growth in ZIHS, resulting in a wide electrochemical stability window of 2.3 V, a maximum energy density of 255.4 Wh kg(-1) at a capacity density of 127.7 mAh g(-1), and good cycling stability of ZIHS, maintaining 79.5% capacity density after 3000 cycles, and the Coulombic efficiency has been maintained at over 99%.
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