☆ 4.7 Review

A Comprehensive Review of MoSx for Improved Photo(electro)catalytic Performance

SOLAR RRL (2023)

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Article Chemistry, Physical

Rational design and fabrication of MoSx nanoclusters decorated Mn0.3Cd0.7S nanorods with promoted interfacial charge transfer toward robust photocatalytic H2 generation

Bo Wang et al.

Summary: In this work, a novel MoSx/Mn0.3Cd0.7S composite catalyst with 1D nanostructure was successfully designed and fabricated. The intimate interface between MoSx nanoclusters and Mn0.3Cd0.7S nanorods achieved through in situ photoreduction route contributes to high-efficiency interfacial charge separation. The resulting catalyst exhibits dramatically enhanced visible-light-driven photocatalytic H2 production activity due to more efficient spatial charge separation and enriched active sites.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

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Article Materials Science, Multidisciplinary

MnWO4 nanorods embedded into amorphous MoSx microsheets in 2D/1D MoSx/MnWO4 S-scheme heterojunction for visible-light photocatalytic water oxidation

Hongru Zhou et al.

Summary: A novel MoSx/MnWO4 hybrid photocatalyst was designed and synthesized for efficient visible light-driven water splitting to generate oxygen. The strong chemical interlayer between amorphous MoSx microsheets and MnWO4 nanorods improved charge transportation efficiency by reducing charge transfer barrier, leading to enhanced photocatalytic activity. The S-scheme heterojunction structure promoted solar light utilization and separation efficiency of photo-generated charge carriers, resulting in improved water oxidation performance.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2023)

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Article Green & Sustainable Science & Technology

Bifunctional Nanostructured Palladium/MoSx Electrocatalyst for Cathode Hydrogen Evolution Reaction PEM Water Electrolysis and Oxygen Reduction Reaction

Antonia Kagkoura et al.

Summary: MoSx@Pd hybrids were successfully synthesized as an excellent bifunctional electrocatalyst for both hydrogen evolution reaction and oxygen reduction reaction. It operates at the same potential as Pt/C for hydrogen evolution and achieves a low overpotential due to improved reaction kinetics and charge transfer processes. It also exhibits excellent performance and stability in a water electrolyzer, outperforming commercial Pt/C with enhanced ORR activity and stability.

ADVANCED SUSTAINABLE SYSTEMS (2023)

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Article Chemistry, Physical

One-step electrodeposition of amorphous MoSx- CdS on Ti mesh as a monolithic heterostructured photocatalyst for enhanced photocatalytic H2 evolution

Jingtao Zhang et al.

Summary: Exploiting large-size monolithic semiconductor photocatalyst sheet/layer with superior photocatalytic hydrogen production performances is challenging but important. This study constructed an amorphous MoSx -CdS monolithic heterostructured photocatalyst sheet through a one-step potentiostatic electrodeposition process. The photocatalyst demonstrated an optimized H-2 generation rate of 4476 mu mol h(-1) g(-1) and excellent operability during photocatalytic H-2 generation and recycling processes, making it promising for practical applications in photocatalysis, photoelectrocatalysis and beyond.

SURFACES AND INTERFACES (2023)

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Article Chemistry, Physical

Surface modification of CuInS2 photocathodes with ruthenium co-catalysts for efficient solar water splitting

Sang Youn Chae et al.

Summary: In this study, the photoelectrochemical activity of CuInS2 photocathodes was investigated after sequential surface modification with a-MoSx, Pt, or Ru. The results showed that a Ru-modified CuInS2/a-MoSx photocathode exhibited higher photoelectrochemical activities compared to a Pt-modified one. The high activity of the Ru modification was found to be due to the more suitable energy level of Ru on the photocathode, which improved the electron transfer and carrier lifetime during photoelectrochemical reaction.

APPLIED SURFACE SCIENCE (2023)

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Article Chemistry, Physical

Photodeposition of molybdenum sulfide on MTiO3 (M: Ba, Sr) perovskites for photocatalytic hydrogen evolution

Talha Kuru et al.

Summary: Photocatalytic hydrogen evolution using semiconductor materials to convert solar energy into chemical energy has been effectively studied. Perovskite-based materials have been widely used as semiconductor catalysts for this purpose. In this study, molybdenum sulfide photodeposited onto MTiO3 (M: Ba, Sr) perovskites (MTiO3/MoSx) was investigated for photocatalytic hydrogen evolution under solar light irradiation in the presence of triethanolamine and eosin Y. The results showed that BaTiO3/MoSx and SrTiO3/MoSx exhibited significant improvement in hydrogen production efficiency and stability compared to pristine MTiO3. The photocatalytic hydrogen activity followed the order of SrTiO3/MoSx > BaTiO3/MoSx > MoSx > SrTiO3 > BaTiO3. Additionally, SrTiO3/MoSx demonstrated higher hydrogen activity than SrTiO3/Pt due to the presence of active sites created by MoSx on the catalyst surface.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2023)

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Article Chemistry, Physical

Oxygen-contained amorphous MoSx cocatalyst by one-step photodeposition to enhance H-adsorption affinity for efficient photocatalytic H2 generation

Pinsi Deng et al.

Summary: In this paper, a strategy for enhancing hydrogen adsorption of saturated S by manipulating electron density through O atoms is proposed to boost the photocatalytic performance of CdS. Oxygen-contained amorphous MoSx (a-MoOSx) nanoparticles were tightly loaded on the CdS surface, showing superior H-2-production activity. Characterizations and density functional theory (DFT) calculations revealed the mechanism of improved H-2-evolution activity.

NANO RESEARCH (2023)

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Article Chemistry, Multidisciplinary

N, S Co-Coordinated Mo Defect Sites in Metal Coordination Polymers for Boosting Perdurable and High-Efficiency Alkaline Hydrogen Evolution

Mengying Liu et al.

Summary: In this study, a novel molybdenum-based coordination metal polymer (CMP) was synthesized to overcome the poor electrical conductivity and limited active sites issue in conventional MoSx materials. The CMP, which included N, S co-coordinated Mo defect site [MoV(=O)SxNy] moieties as active sites, showed high-efficiency alkaline hydrogen evolution reaction (HER) with good stability. This work inspires new ideas for designing N, S co-coordinated molybdenum-based CMP electrocatalysts for efficient hydrogen production in commercial alkaline water splitting.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

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Article Chemistry, Physical

Amorphization-crystallization synergism on MoSx homojunction for boosting photocatalytic H2 production of TiO2 in alkaline medium

Linfeng Li et al.

Summary: An amorphous-crystalline MoSx homojunction is synthesized and anchored on TiO2 surface to greatly enhance its photo-catalytic hydrogen production efficiency in alkaline medium.

APPLIED SURFACE SCIENCE (2023)

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Article Chemistry, Physical

Activating Octahedral Center in Co-Doped NiFe2O4 via Bridging Amorphous MoSx for Electrocatalytic Water Oxidation: A Case for eg Orbital Regulation in Spinel Oxide

Lu Yao et al.

Summary: The filling states of Ni-Oh and Fe-Oh in the NiFe2O4-based spinel are controllably regulated by introducing catalytically inactive MoSx, resulting in a salutary transition from high to medium e(g) occupancy state. The Mo-S hanging on the apical of octahedral sites plays a key role in the migration of electrons in the e(g) orbit of M-Oh, as confirmed by X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. The modified surface with abundant unsaturated S atoms in amorphous MoSx shows superior water oxidation performance.

SMALL METHODS (2023)

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Article Engineering, Environmental

Linker regulation of iron-based MOFs for highly effective Fenton-like degradation of refractory organic contaminants

Junying Chen et al.

Summary: Iron-based MOFs with tunable structure and large surface area have been used in heterogeneous Fenton-like reactions for the degradation of new pollutants. This study investigates how the linker substituents of MIL-101 with MTN-typed topology influence the catalytic efficiency. The results show that the substituents affect crystal morphology and the MIL-101-NH2 exhibits significantly faster antibiotics removal compared to MIL-101-H due to the change in active surface.

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Nanoscience & Nanotechnology

Engineering of Molybdenum Sulfide Nanobunches on MWCNTs: Modulation of Active Sites and Electronic Conductivity via Controllable Solvothermal Deposition

Aya Ali et al.

Summary: Amorphous, mixed-valency molybdenum sulfide (MoSx) catalysts were successfully grown on carbon nanotube substrates using a one-pot solvothermal synthesis. Optimizing the catalyst loading and oxidation state of molybdenum led to enhanced catalytic performance in hydrogen evolution reaction, achieving one of the lowest reported overpotentials. Defect engineering in the catalyst was achieved through simple control of reductive synthesis conditions, without the need for sophisticated techniques.

ACS APPLIED NANO MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Linkage Microenvironment of Azoles-Related Covalent Organic Frameworks Precisely Regulates Photocatalytic Generation of Hydrogen Peroxide

Yi Mou et al.

Summary: Artificial H2O2 photosynthesis by covalent organic frameworks (COFs) photocatalysts is a promising method for wastewater treatment. This study successfully synthesized three types of azoles-linked COFs and found that the thiazole-linked structure in TZ-COF is more favorable for H2O2 production. The active sites in COFs were found to be located at the benzene ring fragment between the pyrene unit and azole linkage.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Review Engineering, Environmental

Preparation of photocatalysts decorated by carbon quantum dots (CQDs) and their applications: A review

Feixia Zhao et al.

Summary: In this paper, the precursor materials, physical and chemical properties, as well as the preparation methods of CQDs decorated photocatalysts are discussed. The effects of reaction conditions, precursor and reaction medium on the structural characteristics of CQDs decorated photocatalysts are summarized. The applications and recent progress of CQDs decorated photocatalysts, including organic pollutants degradation, hydrogen production, and carbon dioxide conversion, are reviewed. The challenges and suggestions for future research of CQDs decorated photocatalysts are also proposed.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

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Article Chemistry, Physical

Low-temperature synthesis of molybdenum sulfides, tungsten sulfides, and composites thereof as efficient electrocatalysts for hydrogen evolution reaction

Ha Huu Do et al.

Summary: In this work, a one-step approach for synthesizing molybdenum sulfides and tungsten sulfides was reported. The MoSx-100 degrees C exhibited the highest catalytic activity, while WS2 could produce hydrogen at 400 degrees C. A graphene oxide/MoSx-100 degrees C sample showed good stability and high performance in hydrogen production.

APPLIED SURFACE SCIENCE (2022)

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Article Chemistry, Physical

In-Situ Photodeposition of Highly Dispersed MoSx as a Co-catalyst on TiO2 Nanoparticles for Efficient and Stable Photocatalytic H2 Evolution

Xinxin Jiang et al.

Summary: This study synthesized a photocatalytic material of amorphous molybdenum sulfide electronic promoter modified TiO2 (TiO2/a-MoSx) to improve the photocatalytic hydrogen production performance, showing significantly enhanced efficiency with TiO2/a-MoSx-8p catalyst achieving the highest activity with a hydrogen evolution efficiency of 35.2 mmol g(-1) within two hours. The a-MoSx cocatalyst can increase catalyst specific surface area, provide active sites, capture photogenerated electrons of TiO2, and improve separation efficiency of photogenerated charges, enhancing catalytic activity.

CATALYSIS LETTERS (2022)

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Article Chemistry, Physical

Unique ternary Ni-MOF-74/Ni2P/MoSx composite for efficient photocatalytic hydrogen production: Role of Ni2P for accelerating separation of photogenerated carriers

Teng Li et al.

Summary: The introduction of highly dispersed Ni2P derived from MOFs is an effective way to reduce the recombination rate of photogenerated electron-holes and enhance photocatalytic hydrogen production activity. Adjusting the ratio between Ni-MOF-74/Ni2P and MoSx can lead to the best hydrogen production activity of the composite catalyst 10%-NPMS.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Materials Science, Multidisciplinary

Preparation of MoS2 spheres from Mo plate and elemental sulfur and the effect of sphericalization on electrochemical hydrogen evolution catalysis

Da-Som Shin et al.

Summary: Changes in morphological structure do not affect the intrinsic activity of molybdenum sulfide catalysts.

MATERIALS CHEMISTRY AND PHYSICS (2022)

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Article Nanoscience & Nanotechnology

Black Si Photocathode with a Conformal and Amorphous MoSx Catalytic Layer Grown Using Atomic Layer Deposition for Photoelectrochemical Hydrogen Evolution

Dae Woong Kim et al.

Summary: By conformally depositing an amorphous molybdenum sulfide (a-MoSx) thin film on a nano-structured surface of black Si using atomic layer deposition (ALD), we demonstrated enhanced photoelectrochemical (PEC) performance with high electrocatalytic activity and excellent stability.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Chemistry, Physical

Co-doped amorphous MoSx supported on CuO/CM (Cu mesh) with enhanced photocatalytic activity for ammonia synthesis

Weiwen Wang et al.

Summary: In this study, a thin-film heterojunction photocatalyst was successfully synthesized on a CuO/CM substrate using a simple electrochemical deposition method, showing good catalytic performance and stable structure for photocatalytic nitrogen fixation. By constructing a gas-liquid-solid three-phase photocatalytic reactor, the efficiency of photocatalytic nitrogen fixation was effectively enhanced.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2022)

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Article Chemistry, Physical

Amorphous MoSx electro-synthesized in alkaline electrolyte for superior hydrogen evolution

Chunxia Niu et al.

Summary: Amorphous MoSx electrocatalysts have gained significant attention due to their structural flexibility and rich defects, providing abundant active sites for hydrogen evolution. In this study, amorphous MoSx films were electrochemically deposited on carbon cloth via constant potentials method in a deposition solution containing different amounts of (NH4)2MoS4 and NaOH. The resulting samples exhibited amorphous structure as confirmed by X-ray diffraction patterns, while X-ray photoelectron and Raman spectrum revealed the presence of defective MoV=O sites coordinated with bridged sulfur. The optimized MoSx electrode showed remarkable overpotentials for hydrogen evolution reaction (HER) in both acidic and alkaline electrolytes, surpassing the performance of most amorphous MoSx-based electrodes. The proposed catalytic pathway suggests the active role of MoV=O sites. This synthesis approach in alkaline electrolyte holds potential for the preparation of high-performance electrocatalysts for HER.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Chemistry, Multidisciplinary

Integrating Amorphous Molybdenum Sulfide Nanosheets with a Co9S8@Ni3S2 Array as an Efficient Electrocatalyst for Overall WaterSplitting

Xueting Feng et al.

Summary: A hierarchical heterostructure consisting of MoSx@Co9S8@Ni3S2/NF was constructed on a 3D Ni foam, which exhibited excellent catalytic activity for both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER) in 1 M KOH. The superior catalytic activity of MoSx@Co9S8@Ni3S2/NF for overall water splitting was demonstrated, surpassing the performance of commercial Pt/C/NF||IrO2/NF and showing better stability.

LANGMUIR (2022)

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Article Materials Science, Multidisciplinary

Structure-performance correlation guided applications of covalent organic frameworks

Hou Wang et al.

Summary: This review provides an insightful understanding of COFs from a structural perspective and correlates them with their performance in practical applications. It addresses the synthesis challenges of COFs and discusses their structural and physicochemical properties in relation to different functions. Furthermore, it presents discussions on the correlation between structural characteristics of COFs and their performance in various fields, as well as future directions for function-oriented design and scalable production of COFs.

MATERIALS TODAY (2022)

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Article Chemistry, Physical

Mo3+ hydride as the common origin of H2 evolution and selective NADH regeneration in molybdenum sulfide electrocatalysts

Jeremy A. Bau et al.

Summary: Hydride transfers play a crucial role in economically and environmentally important reactions, and catalysts containing molybdenum have shown great potential for improving the sustainability of chemical reactions through electrochemical generation of hydrides. In this study, trapped Mo3+ hydride was found in amorphous molybdenum sulfide during the hydrogen evolution reaction, and its catalytic role in the selective hydrogenation of NADH was demonstrated. These results suggest that molybdenum sulfides could serve as economic electrocatalysts for NADH regeneration.

NATURE CATALYSIS (2022)

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Article Chemistry, Physical

Mo-N Bonds Effect Between MoSx Coupling With CoN For Efficient Photocatalytic Hydrogen Production

Hai Liu et al.

Summary: The facet-engineered surface and interface design in the preparation of efficient photocatalysts has attracted much attention. In this study, 3D MoSx was prepared using Polyvinylpyrrolidone (PVP) as a morphological modifier. CoN was added as an electron acceptor to greatly improve the hydrogen evolution performance of MoSx. The results showed that MoSx@CoN exhibited high hydrogen production activity and stability, providing new insights for the preparation of highly efficient photocatalytic hydrogen evolution materials.

CHEMCATCHEM (2022)

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Article Engineering, Chemical

Size Control of MoSx Catalysts by Diffusion Limitation for Electrocatalytic Hydrodesulfurization

Yue Zhang et al.

Summary: Electrochemical hydrodesulfurization technology is a promising method for removing sulfur compounds from fossil fuels. By increasing the active sites of catalysts, the desulfurization efficiency can be improved.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2022)

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Article Chemistry, Multidisciplinary

Pulsed Laser Phosphorus Doping and Nanocomposite Catalysts Deposition in Forming a-MoSx/NP-Mo//n+p-Si Photocathodes for Efficient Solar Hydrogen Production

Vyacheslav Fominski et al.

Summary: Pulsed laser deposition of nanostructured molybdenum sulfide films improves their electrocatalytic properties in hydrogen evolution reaction (HER). The formation of Mo nanoparticles during laser ablation synergistically enhances the catalytic performance of amorphous a-MoSx (2 <= x <= 3) matrix. This study investigates the potential of using a-MoSx/NP-Mo films (4 and 20 nm thickness) with a p-Si cathode for photo-stimulated hydrogen production. The results show that a-MoSx/NP-Mo//n(+)p-Si photocathode achieves photo-HER according to a Z-scheme, with a stable interfacial SiOy(P) nanolayer and high long-term durability.

NANOMATERIALS (2022)

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Article Chemistry, Physical

Unravelling the phase transition of 2H-MoS2 to 1T-MoS2 induced by the chemical interaction of Pd with molybdenum disulfide-graphene hybrids

Dimitris Tsikritzis et al.

Summary: Hybrids of transition metal dichalcogenides (TMDs) nanoparticles on carbon-based materials have attracted attention due to their remarkable properties, and this study investigates the chemical interaction and morphology of Pd on MoS2 and MoS2-rGO substrates, as well as MoSx and MoSx-rGO hybrids. Characterization with synchrotron radiation and X-ray photoelectron spectroscopies reveals important insights into the interaction of Pd with these materials.

APPLIED SURFACE SCIENCE (2022)

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Article Chemistry, Physical

Efficient photocatalytic hydrogen evolution on amorphous MoSx-modified CdS/KTaO3 heterojunctions under visible light irradiation

Tiantian Cao et al.

Summary: In this study, MoSx/CdS/KTaO3 ternary heterojunction photocatalysts were successfully prepared, and their photocatalytic hydrogen production activity was improved. The optimized photocatalyst exhibited a high rate of hydrogen evolution under visible light and showed good stability. This research provides beneficial insights for efficiently utilizing sunlight to decompose water for hydrogen production.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

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Article Chemistry, Physical

Multifunctional 3D MoSx/Zn3In2S6 nanoflower for selective photothermal-catalytic biomass oxidative and non-selective organic pollutants degradation

Liquan Jing et al.

Summary: This study reports on a 3D MoSx/Zn3In2S6 nanoflower that exhibits efficient photocatalytic selective oxidation of benzyl alcohol to benzaldehyde with simultaneous hydrogen production. The MoSx component acts as both a photothermal material and an electron transport bridge, facilitating charge transfer and hydrogen generation. Additionally, the MoSx/Zn3In2S6 catalyst demonstrates strong selectivity in oxidizing lignin model compounds and degrading organic pollutants.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Nanoscience & Nanotechnology

Efficient Point-of-Care Detection of Uric Acid in the Human Blood Sample with an Enhanced Electrocatalytic Response Using Nanocomposites of Cobalt and Mixed-Valent Molybdenum Sulfide

Debolina Roy et al.

Summary: This study efficiently detects uric acid in human blood using cobalt nanoparticle-immobilized mixed-valent molybdenum sulfide. It achieved high sensitivity by generating a three-electrode system and using a plasma separation membrane as the medium for analysis.

ACS APPLIED BIO MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Activation of MoS2 monolayer electrocatalysts via reduction and phase control in molten sodium for selective hydrogenation of nitrogen to ammonia

Hong Zhang et al.

Summary: This study demonstrates the activation of MoS2 catalyst in molten sodium for electrochemical nitrogen fixation at ambient conditions. The activated catalyst shows high electrocatalytic performance, converting N2 to NH3 with improved faradaic efficiency. The interfacial heterojunctions with sulfur vacancies synergistically enhance electron localization for nitrogen fixation and suppress proton recombination. This work provides new insights into manipulating catalyst properties by controlling chalcogenide vacancies and phase junctions.

CHEMICAL SCIENCE (2022)

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Article Materials Science, Multidisciplinary

Chemical vapor deposition of amorphous molybdenum sulphide on black phosphorus for photoelectrochemical water splitting

Yuanmei Xu et al.

Summary: The amorphous molybdenum sulphide layer composed of black phosphorus and molybdenum sulphide significantly enhances the performance of photoelectrochemical water splitting on the bismuth vanadate film; inserting a layer of black phosphorus between molybdenum sulphide and bismuth vanadate can improve the photoelectrochemical performance and stability of the electrodes; the molybdenum sulphide/black phosphorus/bismuth vanadate electrode exhibits excellent current density, twice as high as that of the pure bismuth vanadate electrode.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Article Chemistry, Multidisciplinary

[Mo3S13]2- as a Model System for Hydrogen Evolution Catalysis by MoSx: Probing Protonation Sites in the Gas Phase by Infrared Multiple Photon Dissociation Spectroscopy

Aristeidis Baloglou et al.

Summary: Materials based on molybdenum sulfide are efficient hydrogen evolution reaction (HER) catalysts, with [HMo3S13](-) serving as a molecular model system to study the binding site for H atoms. Through FT-ICR MS and IRMPD spectroscopy, one distinct S-H stretching vibration at 2450 cm(-1) was observed, providing evidence for a terminal disulfide unit as the H adsorption site based on thermochemical arguments and DFT calculations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Defect coupled MoSx sites over ZnIn2S4 nanosheets towards efficient H2 evolution

Zhaoyi Geng et al.

Summary: The co-deposition of amorphous MoSx onto ZnIn2S4 (ZIS) nanosheets leads to enhanced H2 generation from water reduction; Loading MoSx over O-doped ZIS (O-ZIS) results in larger enhancement compared to ZIS, indicating a synergistic effect.

CATALYSIS COMMUNICATIONS (2021)

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Article Engineering, Environmental

Molybdenum sulfide cocatalyst activation upon photodeposition of cobalt for improved photocatalytic hydrogen production activity of ZnCdS

Yonggang Lei et al.

Summary: In this study, a facile method was developed to synthesize Co-modified MoSx cocatalyst, which showed excellent performance for efficient hydrogen evolution reaction (HER). The ZnCdS/Co-MoSx photocatalyst exhibited superior HER rate and apparent quantum efficiency compared to ZnCdS/MoSx and pristine ZnCdS, as well as benchmarked Pt, Au and Ag co-catalysts. The recycling test demonstrated the satisfactory stability of ZnCdS/Co-MoSx catalyst with slightly reduced activity after 25 hours consecutive HER.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Metal-organic framework-derived MoSx composites as efficient electrocatalysts for hydrogen evolution reaction

Ha Huu Do et al.

Summary: Metal-organic frameworks (MOFs) are crystalline porous materials used for energy-related applications, serving as efficient catalysts for hydrogen evolution reactions (HERs). The modification of Co-based MOFs into MoSx can significantly enhance their catalytic activity, offering hope for replacing noble metals with high-performance catalysts in the future.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Chemistry, Analytical

Green preparation of amorphous molybdenum sulfide nanocomposite with biochar microsphere and its voltametric sensing platform for smart analysis of baicalin

Liangmei Rao et al.

Summary: The green and sustainable development provides a new idea for solving environmental pollution issues of rural biomass wastes. The amorphous molybdenum sulfide (a-MoSx) nanocomposite based on biochar microsphere (BM) as a voltametric sensing platform for smart analysis of baicalin in real samples was facilely prepared. The utilization of pomelo peel as the carbon source improves electronic conductivity and environmental stability of a-MoSx.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Physical

Ultra-small molybdenum sulfide nanodot-coupled graphitic carbon nitride nanosheets: Trifunctional ammonium tetrathiomolybdate-assisted synthesis and high photocatalytic hydrogen evolution

Xinhe Wu et al.

Summary: A facile one-step approach has been designed to produce ultra-small MoSx nanodot-coupled g-C3N4 nanosheets, resulting in a significantly increased photocatalytic hydrogen generation rate compared to traditional methods. This enhancement is mainly attributed to the synergistic effect between MoSx nanodots and cyano groups on the g-C3N4 nanosheet surface.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Nanoscience & Nanotechnology

Controllable Insertion Mechanism of Expanded Graphite Anodes Employing Conversion Reaction Pillars for Sodium-Ion Batteries

Suji Kim et al.

Summary: This study successfully controlled the structural and reaction characteristics of carbonaceous anode materials with MoSx conversion reaction pillars, overcoming irreversible capacity issues and significantly improving capacity and coulombic efficiencies. The strategy of inserting active sulfide pillars has the potential to advance alternative alkali-ion batteries.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Review Engineering, Environmental

Two-dimensional MXene-based and MXene-derived photocatalysts: Recent developments and perspectives

Qian Zhong et al.

Summary: This review summarizes recent studies on the preparation and environmental/energy applications of MXene-based and MXene-derived photocatalysts. It also discusses the roles of MXene as a co-catalyst or precursor in photocatalytic applications and presents the challenges and prospects for the future research of MXenes.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Amorphous-Ni(OH)2 on a Vertically Grown Lamellar Ag-Modified MoSx Thin-Film Electrode with Surface Defects for Hydrogen Production in Alkaline Solutions

Hairus Abdullah et al.

Summary: A low-temperature radio-frequency-sputtered Ag-modified MoSx lamellar thin-film electrode with electrochemical modification of amorphous Ni(OH)(2) exhibited promising hydrogen evolution reaction properties in alkaline solutions. The electrode had a highly active electrochemical surface area and showed good stability, making it a potential candidate for industrial applications.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Engineering, Environmental

Harmonizing the energy band between adsorbent and semiconductor enables efficient uranium extraction

Tao Chen et al.

Summary: By manipulating the concentration of sulfur vacancies, the energy band of defective molybdenum disulfide and reduced graphene oxide was harmonized to enhance the reduction of U(VI). The removal rate of U(VI) exhibited a volcanic relationship with the concentration of sulfur vacancies in the MoSx/RGO heterojunction, reaching a maximum removal rate of 91.6% with nearly 83.4% tetrahydrated uranium species (U(IV)).

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Catalysis of hydrogen evolution reaction by in situ electrodeposited amorphous molybdenum sulfide at soft interfaces

E. Aslan et al.

Summary: This study presents a novel method for template-free in situ electrodeposition of amorphous MoSx at freestanding soft interfaces, enabling biphasic catalysis of the hydrogen evolution reaction with decamethylferrocene (DMFc) acting as an organic sacrificial reducing agent.

MATERIALS TODAY ENERGY (2021)

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Article Chemistry, Physical

Fabrication of an Ag2S-MoSx/MoNiAg film electrode for efficient electrocatalytic hydrogen evolution in alkaline solution

N. S. Gultom et al.

Summary: The two-layer Ag2S-MoSx/MoNiAg film electrode significantly enhances the hydrogen evolution reaction (HER) under alkaline conditions, with lower overpotential and higher current density.

MATERIALS TODAY ENERGY (2021)

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Article Chemistry, Physical

Electrosynthesis of CdS/MoS2 Using Electrodeposited MoSx: A Combined Voltammetry-Electrochemical Quartz Crystal Nanogravimetry Study

Kongshik Rho et al.

Summary: A strategy for preparing CdS/MoS2 heterostructures was described in this study, where CdS/MoS2 particles were formed by derivatizing the excess sulfur intrinsic in the electrodeposited MoS3 surface with Cd through adjustment of medium pH and interfacial electrochemistry. The formation of heterojunction between MoS2 and CdS particles was confirmed, and the nonoptimized CdS/MoS2 heterostructures showed improved photoelectrochemical response for oxidation of sulfite species compared with CdS or MoS2.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Applied

Self-supporting NiFe LDH-MoSx integrated electrode for highly efficient water splitting at the industrial electrolysis conditions

Han Zhang et al.

Summary: The self-supporting NiFe LDH-MoSx integrated electrode shows excellent performance for water oxidation under normal alkaline and simulated industrial electrolysis conditions, indicating its potential for large-scale industrial water electrolysis applications.

CHINESE JOURNAL OF CATALYSIS (2021)

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Article Chemistry, Physical

Eosin Y-sensitized rose-like MoSx and CeVO4 construct a direct Z-scheme heterojunction for efficient photocatalytic hydrogen evolution

Zhiliang Jin et al.

Summary: The construction of heterojunctions between MoSx and CeVO4 effectively improves the photocatalytic performance in hydrogen production. The direct Z-scheme heterojunction inhibits the recombination of electron-hole pairs, promoting electron transfer and enhancing hydrogen generation. Photoluminescence spectra also showed the suppression of electron-hole pair recombination in the MoSx/CeVO4 composite.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

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Review Chemistry, Physical

Roles of sulfur-edge sites, metal-edge sites, terrace sites, and defects in metal sulfides for photocatalysis

Yue Liu et al.

Summary: Metal-sulfide photocatalysts possess excellent optoelectronic properties and appropriate band-gap energy. Understanding the relationship between photocatalytic performance and reactive sites in metal sulfide is crucial for enhancing activity and selectivity. Various correlations between the active sites of metal sulfides and photocatalytic applications have been established to explore opportunities and challenges for their development in photocatalysis.

CHEM CATALYSIS (2021)

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Article Chemistry, Physical

A tuned Lewis acidic catalyst guided by hard-soft acid-base theory to promote N2 electroreduction

Yongwen Ren et al.

Summary: The study presents a paradigm for designing an electrocatalyst with tuned Lewis acidity to efficiently activate and reduce N-2 to NH3 based on the hard-soft acid-base theory. Increasing the Lewis acidity of the molybdenum sulfide (MoSx) model catalyst supported on carbon nanotubes greatly improves its ability to activate the N-2 molecule, resulting in significantly enhanced NH3 yield rate and selectivity. Density functional theory calculations confirm that tuning the Lewis acidity of MoSx to match the basicity of N-2 can accelerate the N-2 activation process via the sigma -> d donation mechanism.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Synergistic enhancement of the oxygen evolution reaction by MoSx and sulphate on amorphous polymetallic oxide nanosheets

Yonghao Gan et al.

Summary: In order to alleviate the energy crisis and achieve the transformation of renewable energy sources, there is great interest in developing low-cost, highly efficient, and stable oxygen evolution reaction (OER) electrocatalysts for water splitting. A facile one-step solvothermal strategy was used to fabricate amorphous iron-cobalt-molybdenum oxide flakes containing MoSx and sulfate (FCMOS) which exhibited a low overpotential, lower Tafel slope, large electrochemical active surface area, and excellent durability. The excellent OER performance of FCMOS can be attributed to the acceleration of the *OH -> *O + *H reaction by MoSx, optimization of the deprotonation of *OOH by sulfate, and the synergistic polymetallic effect.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

An effective photocatalytic hydrogen evolution strategy based on tunable band gap (CuIn)xZn2(1-x)S2 combined with amorphous molybdenum sulfide

Yanren Cao et al.

Summary: Utilizing the (CuIn)(x)Zn2(1-x)S2 solid solution photocatalyst and co-catalyst a-MoSx can effectively enhance the performance of photocatalytic water splitting, achieving a hydrogen evolution rate of 2100 µmol g-1 h-1.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Materials Science, Multidisciplinary

Highly dispersed MoSx nanodot-modified TiO2 photocatalysts: vitamin C-mediated synthesis and improved H2 evolution activity

Jiangyuan He et al.

Summary: The study demonstrates that unsaturated S atoms on exposed edges of MoS2 are critical H-2-generation active sites, and fabricating MoSx cocatalyst with a small size can enhance its performance. By using a vitamin C-mediated method, highly dispersed MoSx nanodots with an ultrasmall size are loaded on TiO2 surface to achieve the highest H-2-evolution rate. The strategy of using a mediator for simultaneous realization of nanosized cocatalyst and improved cocatalyst-host interaction could provide alternative idea for enhancing photocatalytic H-2-generation activity.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Physical

Synthesis of Ni-MoSx/g-C3N4 for Photocatalytic Hydrogen Evolution under Visible Light

Bo Wang et al.

CHEMCATCHEM (2020)

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Article Chemistry, Multidisciplinary

Rapid Microwave-Assisted Synthesis of CdS/Graphene/MoSx Tunable Heterojunctions and Their Application in Photocatalysis

Iordanis Tzanidis et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Article Electrochemistry

Controllable in situ growth of amorphous MoSx nanosheets on CoAl layered double hydroxides for efficient oxygen evolution reaction

Xiaolong Deng et al.

ELECTROCHEMISTRY COMMUNICATIONS (2020)

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Article Engineering, Environmental

Amorphous molybdenum sulfide monolayer nanosheets for highly efficient electrocatalytic hydrogen evolution

Deliang Wang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Multidisciplinary

Comparative Study of the Structure, Composition, and Electrocatalytic Performance of Hydrogen Evolution in MoSx∼2+δ/Mo and MoSx∼3+δ Films Obtained by Pulsed Laser Deposition

V. Fominski et al.

NANOMATERIALS (2020)

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Article Chemistry, Physical

Sensitization of vertically grown ZnO 2D thin sheets by MoSx for efficient charge separation process towards photoelectrochemical water splitting reaction

Mamta Devi Sharma et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Physical

Solvothermal synthesis of oxygen-incorporated MoS2-x nanosheets with abundant undercoordinated Mo for efficient hydrogen evolution

Man Zhao et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Materials Science, Multidisciplinary

Highly efficient S2-adsorbed MoSx-modified TiO2 photocatalysts: A general grafting strategy and boosted interfacial charge transfer

Duoduo Gao et al.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2020)

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Article Chemistry, Multidisciplinary

Sandwich-Structured Fe-Ni2P/MoSx/NF Bifunctional Electrocatalyst for Overall Water Splitting

Xinglin Zhang et al.

ADVANCED MATERIALS INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Performance and Mechanism of Photoelectrocatalytic Activity of MoSx/WO3 Heterostructures Obtained by Reactive Pulsed Laser Deposition for Water Splitting

Vyacheslav Fominski et al.

NANOMATERIALS (2020)

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Article Nanoscience & Nanotechnology

MoSx on Nitrogen-Doped Graphene for High-Efficiency Hydrogen Evolution Reaction: Unraveling the Mechanisms of Unique Interfacial Bonding for Efficient Charge Transport and Stability

Mallikarjun Bhavanari et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Nanoscience & Nanotechnology

Ag-Decorated MoSx Laminar-Film Electrocatalyst Made with Simple and Scalable Magnetron Sputtering Technique for Hydrogen Evolution: A Defect Model to Explain the Enhanced Electron Transport

Dong-Hau Kuo et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Chemical

Sulfur-Rich Molybdenum Sulfide Grown on Porous N-Doped Graphene for Efficient Hydrogen Evolution

Peng Juan et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Chemistry, Physical

Structure of Nanocrystalline, Partially Disordered MoS2+δ Derived from HRTEM-An Abundant Material for Efficient HER Catalysis

Emanuel Ronge et al.

CATALYSTS (2020)

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Article Chemistry, Physical

Self-supported MoSx/V2O3 heterostructures as efficient hybrid catalysts for hydrogen evolution reaction

Mingwei Hu et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Engineering, Environmental

MoSx Coated Copper Nanowire on Copper Foam as A Highly Stable Photoelectrode for Enhanced Photoelectrocatalytic Hydrogen Evolution Reaction via. Plasmon-Induced Hot Carriers

Yuanyuan Tian et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Physics, Atomic, Molecular & Chemical

Formation of Effective Electrocatalysts of Hydrogen Evolution MoSx> 2by Pulsed Laser Ablation Assisted by the Deposition of Mo Nanoparticles

D. V. Fominski et al.

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B (2020)

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Article Chemistry, Multidisciplinary

Non-Equilibrium Synthesis of Highly Active Nanostructured, Oxygen-Incorporated Amorphous Molybdenum Sulfide HER Electrocatalyst

Giorgio Giuffredi et al.

SMALL (2020)

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Article Chemistry, Physical

One-Step Synthesis of Modified Ti3C2 MXene-Supported Amorphous Molybdenum Sulfide Electrocatalysts by a Facile Gamma Radiation Strategy for Efficient Hydrogen Evolution Reaction

Shuangxiao Li et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

All-Electrochemically Grown Sb2Se3/a-MoSx Photocathodes for Hydrogen Production: The Effect of the MoSx Layer on the Surface Recombination and Photocorrosion of Sb2Se3 Films

Magno B. Costa et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Inorganic & Nuclear

Photochemical deposition of amorphous MoSxon one-dimensional NaNbO3-CdS heterojunction photocatalysts for highly efficient visible-light-driven hydrogen evolution

Jiawei Zhu et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Multidisciplinary

Facile synthesis of amorphous MoSx-Fe anchored on Zr-MOFs towards efficient and stable electrocatalytic hydrogen evolution

Le Zhang et al.

CHEMICAL COMMUNICATIONS (2020)

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Review Environmental Sciences

Hydrothermal/solvothermal synthesis and treatment of TiO2 for photocatalytic degradation of air pollutants: Preparation, characterization, properties, and performance

Alireza Haghighat Mamaghani et al.

CHEMOSPHERE (2019)

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Article Chemistry, Physical

Light-induced confined growth of amorphous Co doped MoSx nanodots on TiO2 nanoparticles for efficient and stable in situ photocatalytic H2 evolution

Yuan Xue et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

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Article Chemistry, Physical

Structural Transformation Identification of Sputtered Amorphous MoSX as an Efficient Hydrogen-Evolving Catalyst during Electrochemical Activation

Fanxing Xi et al.

ACS CATALYSIS (2019)

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Article Biophysics

All-electrodeposited amorphous MoSx@ZnO core-shell nanorod arrays for self-powered visible-light-activated photoelectrochemical tobramycin aptasensing

Mengxiang Shang et al.

BIOSENSORS & BIOELECTRONICS (2019)

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Article Engineering, Environmental

Ni-Co-MoSx ball-in-ball hollow nanospheres as Pt-free bifunctional catalysts for high-performance solar cells and hydrogen evolution reactions

Xing Qian et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Physical

Ni3S2-MoSx nanorods grown on Ni foam as high-efficient electrocatalysts for overall water splitting

Dawei Zhang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

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Article Chemistry, Physical

Hybrid amorphous MoSx-graphene protected Cu2O photocathode for better performance in H2 evolution

Hoang V. Le et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

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Article Materials Science, Multidisciplinary

Sonochemical deposition of MoSx on ZnIn2S4 for photocatalytic hydrogen evolution

Xianhao Qian et al.

MATERIALS LETTERS (2019)

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Article Green & Sustainable Science & Technology

Accelerating photosensitized H2 evolution over in situ grown amorphous MoSx catalyst employing TiO2 as an efficient catalyst loading matrix and electron transfer relay

Xiangyu Liu et al.

RENEWABLE ENERGY (2019)

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Article Engineering, Environmental

Ethyl acetate-induced formation of amorphous MoSx nanoclusters for improved H2-evolution activity of TiO2 photocatalyst

Huogen Yu et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Multidisciplinary

Controllable Synthesis of Nanosized Amorphous MoSx Using Temporally Shaped Femtosecond Laser for Highly Efficient Electrochemical Hydrogen Production

Bo Li et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Chemistry, Physical

MoSx co-catalytic activation of H2O2 by heterogeneous hemin catalyst under visible light irradiation

Xiaojie Ji et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Synthesis of a MoSx-O-PtOx Electrocatalyst with High Hydrogen Evolution Activity Using a Sacrificial Counter-Electrode

Yingxin Zhan et al.

ADVANCED SCIENCE (2019)

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Review Chemistry, Multidisciplinary

Plasmon-Enhanced Photoelectrochemical Water Splitting for Efficient Renewable Energy Storage

Luca Mascaretti et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Physical

Designing Pd/O co-doped MoSx for boosting the hydrogen evolution reaction

Yingxin Zhan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

An amorphous MoSx modified g-C3N4 composite for efficient photocatalytic hydrogen evolution under visible light

Xia Li et al.

RSC ADVANCES (2019)

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Article Chemistry, Multidisciplinary

N-Doped amorphous MoSx for the hydrogen evolution reaction

Ruimin Ding et al.

NANOSCALE (2019)

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Article Chemistry, Multidisciplinary

In situ growth and activation of an amorphous MoSx catalyst on Co-containing metal-organic framework nanosheets for highly efficient dye-sensitized H2 evolution

Xiangyu Liu et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Efficient Hydrogen Evolution Reaction Catalysis in Alkaline Media by All-in-One MoS2 with Multifunctional Active Sites

Mohsin Ali Raza Anjum et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

Hydrogen evolution enhancement of ultra-low loading, size-selected molybdenum sulfide nanoclusters by sulfur enrichment

Daniel Escalera-Lopez et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Ultra-small freestanding amorphous molybdenum sulfide colloidal nanodots for highly efficient photocatalytic hydrogen evolution reaction

Kun Chang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Highly efficient dual cocatalyst-modified TiO2 photocatalyst: RGO as electron-transfer mediator and MoSx as H2-evolution active site

Ying Xu et al.

APPLIED SURFACE SCIENCE (2018)

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Article Chemistry, Multidisciplinary

CoAl-layered double hydroxide nanosheets as an active matrix to anchor an amorphous MoSx catalyst for efficient visible light hydrogen evolution

Shixiong Min et al.

CHEMICAL COMMUNICATIONS (2018)

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Article Engineering, Environmental

Co-Fe-MoSx hollow nanoboxes as high-performance counter electrode catalysts for Pt-free dye-sensitized solar cells

Chong Xu et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Chemistry, Inorganic & Nuclear

Light-assisted synthesis MoSx as a noble metal free cocatalyst formed heterojunction CdS/Co3O4 photocatalyst for visible light harvesting and spatial charge separation

Hao Yang et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Inorganic & Nuclear

One-dimensional hierarchical MoO2-MoSx hybrids as highly active and durable catalysts in the hydrogen evolution reaction

Yu Qiu et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Physical

Electrochemical growth of MoSx on Cu foam: A highly active and robust three-dimensional cathode for hydrogen evolution

Shixiong Min et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Chemistry, Physical

Photodeposition of amorphous MoSx cocatalyst on TiO2 nanosheets with {001} facets exposed for highly efficient photocatalytic hydrogen evolution

Fuying Du et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Chemistry, Physical

Amorphous MoSx-Coated TiO2 Nanotube Arrays for Enhanced Electrocatalytic Hydrogen Evolution Reaction

Zhongqing Liu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2018)

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Article Nanoscience & Nanotechnology

Heterogeneous Nanostructure Design Based on the Epitaxial Growth of Spongy MoSx on 2D Co(OH)(2) Nanoflakes for Triple-Enzyme Mimetic Activity: Experimental and Density Functional Theory Studies on the Dramatic Activation Mechanism

Yongqi Ding et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Physical

A facile cation-exchange approach to 2D PbS/amorphous MoSx heterojunction composites with enhanced photocatalytic activity

Ming Li et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2018)

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Article Chemistry, Physical

Quasi-homogenous dye-sensitized photocatalytic H-2 evolution catalyzed by in-situ grown cobalt-promoted MoSx catalyst coupled with graphene quantum dots

Yonggang Lei et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2018)

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Article Chemistry, Physical

Redox-Mediator-Assisted Electrocatalytic Hydrogen Evolution from Water by a Molybdenum Sulfide-Functionalized Metal-Organic Framework

Hyunho Noh et al.

ACS CATALYSIS (2018)

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Article Chemistry, Physical

Towards activation of amorphous MoSx via Cobalt doping for enhanced electrocatalytic hydrogen evolution reaction

Peng Yang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Chemistry, Physical

Defect-rich MoSx/carbon nanofiber arrays on carbon cloth for highly efficient electrocatalytic hydrogen evolution

Xiaosong Guo et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Nanoscience & Nanotechnology

Cobalt-Activated Amorphous MoSx Nanodots Grown In Situ on Natural Attapulgite Nanofibers for Efficient Visible-Light-Driven Dye-Sensitized H2 Evolution

Xiangyu Liu et al.

ACS APPLIED NANO MATERIALS (2018)

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Article Nanoscience & Nanotechnology

Cobalt Sulfide Nanotubes (Co9S8) Decorated with Amorphous MoSx as Highly Efficient Hydrogen Evolution Electrocatalyst

Liqian Wu et al.

ACS APPLIED NANO MATERIALS (2018)

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Article Chemistry, Physical

Ti@MoSx core-shell nanowire arrays as self-supported electrodes for hydrogen evolution reaction

Chao Liu et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

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Article Chemistry, Physical

Electrodeposited MoSx films assisted by liquid crystal template with ultrahigh electrocatalytic activity for hydrogen evolution reaction

Guan-Qun Han et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

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Article Chemistry, Inorganic & Nuclear

One-pot synthesis nickel sulfide/amorphous molybdenum sulfide nanosheets array on nickel foam as a robust oxygen evolution reaction electrocatalyst

Yuan-Zi Xu et al.

JOURNAL OF SOLID STATE CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Amorphous MoSx on CdS nanorods for highly efficient photocatalytic hydrogen evolution

Xiaofang Li et al.

JOURNAL OF SOLID STATE CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Molybdenum Sulfide for Hydrogen Evolution Reaction: The Importance of Solution Dynamic Wetting Behavior in The Drying Process

Yu-Wen Chen et al.

LANGMUIR (2017)

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Article Chemistry, Multidisciplinary

Co-catalytic Effects of CoS2 on the Activity of the MoS2 Catalyst for Electrochemical Hydrogen Evolution

Ranjith Bose et al.

LANGMUIR (2017)

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Article Chemistry, Multidisciplinary

Amorphous Molybdenum Sulfide/Carbon Nanotubes Hybrid Nanospheres Prepared by Ultrasonic Spray Pyrolysis for Electrocatalytic Hydrogen Evolution

Zhifeng Ye et al.

SMALL (2017)

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Article Materials Science, Multidisciplinary

Regulated growth of quasi-amorphous MoSx thin-film hydrogen evolution catalysts by pulsed laser deposition of Mo in reactive H2S gas

V. Yu. Fominski et al.

THIN SOLID FILMS (2017)

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Article Chemistry, Physical

Investigating Catalyst-Support Interactions To Improve the Hydrogen Evolution Reaction Activity of Thiomolybdate [Mo3S13]2- Nanoclusters

Thomas R. Hellstern et al.

ACS CATALYSIS (2017)

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Article Chemistry, Physical

Sulfur and Nitrogen Dual-Doped Molybdenum Phosphide Nanocrystallites as an Active and Stable Hydrogen Evolution Reaction Electrocatalyst in Acidic and Alkaline Media

Mohsin Ali Raza Anjum et al.

ACS CATALYSIS (2017)

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Article Multidisciplinary Sciences

Tuning the Composition and Structure of Amorphous Molybdenum Sulfide/Carbon Black Nanocomposites by Radiation Technique for Highly Efficient Hydrogen Evolution

Pengfei Cao et al.

SCIENTIFIC REPORTS (2017)

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Article Multidisciplinary Sciences

Bi-axial grown amorphous MoSx bridged with oxygen on r-GO as a superior stable and efficient nonprecious catalyst for hydrogen evolution

Cheol-Ho Lee et al.

SCIENTIFIC REPORTS (2017)

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Article Chemistry, Physical

In situ photodeposition of MoSx on CdS nanorods as a highly efficient cocatalyst for photocatalytic hydrogen production

Xianliang Fu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Chemistry, Physical

Amorphous MoSx developed on Co(OH)2 nanosheets generating efficient oxygen evolution catalysts

Fengzhan Sun et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Chemistry, Physical

Symmetrical synergy of hybrid Co9S8-MoSx electrocatalysts for hydrogen evolution reaction

Xiaofeng Zhou et al.

NANO ENERGY (2017)

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Review Chemistry, Physical

Evolution of layered double hydroxides (LDH) as high performance water oxidation electrocatalysts: A review with insights on structure, activity and mechanism

Sengeni Anantharaj et al.

MATERIALS TODAY ENERGY (2017)

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Article Chemistry, Physical

Boosting the catalytic performance of MoSx cocatalysts over CdS nanoparticles for photocatalytic H2 evolution by Co doping via a facile photochemical route

Yonggang Lei et al.

APPLIED SURFACE SCIENCE (2017)

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Article Nanoscience & Nanotechnology

Subnanometer Molybdenum Sulfide on Carbon Nanotubes as a Highly Active and Stable Electrocatalyst for Hydrogen Evolution Reaction

Ping Li et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Chemistry, Physical

Three dimensional CNTs aerogel/MoSx as an electrocatalyst for hydrogen evolution reaction

Sathish Reddy et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Article Chemistry, Physical

MoSx supported graphene oxides with different degree of oxidation as efficient electrocatalysts for hydrogen evolution

Wen-Hui Hu et al.

CARBON (2016)

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Article Chemistry, Multidisciplinary

Polyethylenimine promoted electrocatalytic reduction of CO2 to CO in aqueous medium by graphene-supported amorphous molybdenum sulphide

Fengwang Li et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

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Article Chemistry, Physical

Crystallization of Amorphous Molybdenum Sulfide Induced by Electron or Laser Beam and Its Effect on H2-Evolving Activities

Duc N. Nguyen et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

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Article Chemistry, Physical

Molybdenum Polysulfide Anchored on Porous Zr-Metal Organic Framework To Enhance the Performance of Hydrogen Evolution Reaction

Xiaoping Dai et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

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Article Chemistry, Physical

Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide

Phong D. Tran et al.

NATURE MATERIALS (2016)

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Article Chemistry, Physical

Catalytic Activities of Sulfur Atoms in Amorphous Molybdenum Sulfide for the Electrochemical Hydrogen Evolution Reaction

Louisa Rui Lin Ting et al.

ACS CATALYSIS (2016)

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Article Chemistry, Physical

Operando Raman Spectroscopy of Amorphous Molybdenum Sulfide (MoSx) during the Electrochemical Hydrogen Evolution Reaction: Identification of Sulfur Atoms as Catalytically Active Sites for H+ Reduction

Yilin Deng et al.

ACS CATALYSIS (2016)

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Article Chemistry, Multidisciplinary

A highly active molybdenum multisulfide electrocatalyst for the hydrogen evolution reaction

Li-Fang Zhang et al.

RSC ADVANCES (2016)

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Article Chemistry, Physical

Oxygen-mediated formation of MoSx-doped hollow carbon dots for visible light-driven photocatalysis

Jung Hyun Park et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Chemistry, Physical

Amorphous molybdenum sulfide quantum dots: an efficient hydrogen evolution electrocatalyst in neutral medium

Diptiman Dinda et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Chemistry, Multidisciplinary

A Flexible Platform Containing Graphene Mesoporous Structure and Carbon Nanotube for Hydrogen Evolution

Rujing Zhang et al.

ADVANCED SCIENCE (2016)

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Article Nanoscience & Nanotechnology

Electrocatalytic Hydrogen Evolution from Molybdenum Sulfide-Polymer Composite Films on Carbon Electrodes

Youssef Lattach et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Article Chemistry, Multidisciplinary

Polymer Electrolyte Membrane Electrolyzers Utilizing Non-precious Mo-based Hydrogen Evolution Catalysts

Jia Wei Desmond Ng et al.

CHEMSUSCHEM (2015)

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Graphene film-confined molybdenum sulfide nanoparticles: Facile one-step electrodeposition preparation and application as a highly active hydrogen evolution reaction electrocatalyst

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Recent Development of Molybdenum Sulfides as Advanced Electrocatalysts for Hydrogen Evolution Reaction

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Characterization and reactivity of the Mo4S6+ cluster deposited on Au(111)

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NO adsorption on MoSx clusters:: A density functional theory study

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Surface structure and stability of MoSx model clusters

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