4.8 Article

A resilient MXene/CNT nano-accordion framework for anode-free sodium-metal batteries with exceptional cyclic stability

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

Real-Time Visualizing Nucleation and Growth of Electrodes for Post- Lithium-Ion Batteries

Ji Hyun Um et al.

Summary: This article reviews the nucleation and growth behaviors of metal (Li, Na, and Mg) anodes and chalcogen (S and Se) cathodes, and overviews the morphological evolutions on the electrode surface and interface by in situ/operando visualizations. Through experimental verification, the complex and dynamic nucleation and growth behaviors of metal and chalcogen electrodes are validated by in situ/operando visualization methods, aiming to contribute to supporting the fundamental knowledge for the development of high-energy-density metal and chalcogen electrodes.

ACCOUNTS OF CHEMICAL RESEARCH (2023)

Article Materials Science, Multidisciplinary

Anode-less all-solid-state batteries: recent advances and future outlook

Nohjoon Lee et al.

Summary: Anode-less all-solid-state batteries have gained attention for their potential to further reduce cell volume and cost. This perspective article summarizes recent research trends in anode-less all-solid-state batteries based on different types of solid electrolytes and encourages researchers to address remaining issues through the use of advanced materials and cell designs.

MATERIALS FUTURES (2023)

Article Nanoscience & Nanotechnology

Visualization of Sodium Metal Anodes via Operando X-Ray and Optical Microscopy: Controlling the Morphological Evolution of Sodium Metal Plating

Jeesoo Seok et al.

Summary: Due to the abundance and cost effectiveness of sodium, rechargeable sodium metal batteries have attracted widespread attention as a potential replacement for lithium-ion batteries. However, challenges such as the reactivity of sodium, unstable solid-electrolyte interphase (SEI), and sodium dendrite formation remain unresolved. This study investigates the mechanistic behavior of sodium metal plating using operando X-ray and optical imaging techniques. The addition of a fluorine-containing additive to the electrolyte results in more uniform sodium plating and enhanced cycling performance due to the formation of a stable SEI containing NaF.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Multidisciplinary Sciences

Elastomeric electrolytes for high-energy solid-state lithium batteries

Michael J. Lee et al.

Summary: Elastomeric solid-state electrolytes with mechanical robustness, high ionic conductivity, low interfacial resistance and high lithium-ion transference number enable stable operation of high-energy, solid-state lithium batteries.

NATURE (2022)

Article Chemistry, Multidisciplinary

Sodiophilic Mg2+-Decorated Ti3C2 MXene for Dendrite-Free Sodium Metal Batteries with Carbonate-Based Electrolytes

Huiyu Jiang et al.

Summary: Sodium metal is a promising metal anode due to its abundant resources, low cost, high capacity, and high working potential. However, the hazardous dendrite growth of sodium metal hinders its practical application. This study shows that using multifunctional Mg(II)@Ti3C2 MXene as a protective layer on the current collector can improve the wettability of the electrolyte and suppress sodium dendrites. Experimental results demonstrate the absence of sodium dendrites even under high capacity deposition.
Article Chemistry, Applied

High-performance solid-solution potassium-ion intercalation mechanism of multilayered turbostratic graphene nanosheets

Jiae Um et al.

Summary: This study reports a solid-solution potassium-ion intercalation mechanism with a low-voltage plateau capacity on multilayered turbostratic graphene nanosheets. By designing a disordered graphitic structure, the researchers achieved high reversible plateau capacity and sloping capacity, along with improved cycling performance.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Energy & Fuels

Interfacial engineering to achieve an energy density of over 200 Wh kg-1 in sodium batteries

Yuqi Li et al.

Summary: This study presents an initial anode-free sodium battery with an energy density exceeding 200 Wh kg(-1), showcasing the potential for sodium batteries to rival lithium-ion battery performance. Through innovative design and interface chemistry, the cycling lifetime of the sodium battery reaches an impressive 260 cycles without applying additional pressure, providing insights for further development of high-performance sodium batteries.

NATURE ENERGY (2022)

Article Chemistry, Multidisciplinary

Room-Temperature Anode-Less All-Solid-State Batteries via the Conversion Reaction of Metal Fluorides

Jieun Lee et al.

Summary: Anode-less electrodes in all-solid-state batteries have competitive energy densities and improved cycle life, but the composite matrices of these electrodes inhibit lithium-ion diffusion. This study utilizes the conversion reaction of metal fluorides, which induces alloying reactions with lithium ions and improves the uniformity and sustainability of lithium (de)plating.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

3D Sodiophilic Ti3C2 MXene@g-C3N4 Hetero-Interphase Raises the Stability of Sodium Metal Anodes

Changyuan Bao et al.

Summary: Sodium metal batteries, with the advantages of high theoretical capacity, low cost and wide availability, have great potential in electric vehicles and grid-scale energy storage. However, achieving stable cycling of sodium metal anodes remains a challenge due to low Coulombic efficiency caused by side reactions. A g-C3N4 layer was attached to the Ti3C2 MXene surface, forming a stable hetero-interphase and inhibiting side reactions. The 3D Ti3C2 MXene@g-C3N4 nanocomposite showed enhanced Coulombic efficiency, long-term stability, and outstanding rate capability for sodium metal anodes.

ACS NANO (2022)

Article Chemistry, Physical

Sodiophilic Current Collectors Based on MOF-Derived Nanocomposites for Anode-Less Na-Metal Batteries

Huihua Li et al.

Summary: Anode-less sodium metal batteries with Cu@C composite as a sodiophilic layer show improved cycling performance and Coulombic efficiency. Cu@C also inhibits side reactions, dendrite growth, and accumulation of dead sodium, resulting in outstanding rate capability and long-term cycling life.

ADVANCED ENERGY MATERIALS (2022)

Article Engineering, Environmental

Scalable fabrication of MXene-based flexible micro-supercapacitor with outstanding volumetric capacitance

Eunji Kim et al.

Summary: This work presents a facile and reliable process for manufacturing on-chip and flexible microsupercapacitor devices. The microfabrication process based on photolithography and solution process enables the fabrication of MXene electrodes on flexible substrates. The resulting microsupercapacitors exhibit excellent capacitance and energy density, as well as customizable features.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

An anodeless, mechanically flexible and energy/power dense sodium battery prototype

Miao Bai et al.

Summary: The research proposes an anode-less design for sodium metal batteries, utilizing carbon nanotubes as a sodium deposition substrate and various zinc-containing multialloys. The results show successful preferential sodium nucleation within the composite scaffold and oriented deposit propagation along the nanotubes, leading to improved energy density and cycling performance of the batteries.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Anode-less seawater batteries with a Na-ion conducting solid-polymer electrolyte for power to metal and metal to power energy storage

Yongil Kim et al.

Summary: Seawater batteries store energy by using pure sodium metal as the negative electrode, without the need for a specific host material. The sodium metal is harvested from seawater and converted into energy through charge and discharge processes. The compact and metal-less design of the battery achieves high energy efficiency.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Engineering, Environmental

FeS2@N-C nanorattles encapsulated in N/S dual-doped graphene/carbon nanotube network composites for high performance and high rate capability anodes of sodium-ion batteries

Syam Kandula et al.

Summary: Developing effective anode materials for sodium-ion batteries remains challenging. In this study, a method to synthesize N-doped carbon-coated FeS2 nanorattles was successfully developed, enabling the formation of nanorattle structures and N/S dual-element doping into the G/SWCNT network. The resulting sample exhibited remarkable electrochemical performance as an anode for SIBs.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Physical

Anode-Free Full Cells: A Pathway to High-Energy Density Lithium-Metal Batteries

Sanjay Nanda et al.

Summary: The anode-free full cell configuration is ideal for high energy density and lithium storage, but poor efficiencies of lithium plating and stripping lead to short cycle life. Recent studies have shown that advanced electrolytes and other methods can stabilize lithium deposition and improve cycle life.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

MXenes for Rechargeable Batteries Beyond the Lithium-Ion

Fangwang Ming et al.

Summary: MXenes have shown great potential as electrode materials in next-generation batteries, with their unique properties and versatile applications. Researchers have proposed various comprehensive utilization methods and also provided a perspective on future research directions for MXenes and MXene-based materials.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

A Carbon Foam with Sodiophilic Surface for Highly Reversible, Ultra-Long Cycle Sodium Metal Anode

Xue-Yang Cui et al.

Summary: An oxygen-doped carbon foam (OCF) derived from starch is reported as a promising material for sodium-ion batteries, with the ability to reduce nucleation resistance of sodium metal, provide abundant nucleation sites, and form a more stable SEI layer, leading to stable cycling and high coulombic efficiency. The OCF electrode can maintain stable 2000 cycles at a current density of 10 mA cm(-2) with a coulombic efficiency of 99.83%, and the Na@OCF||Na3V2(PO4)(3) full cell also shows high capacity retention over 150 cycles. These results provide a simple and effective method for achieving the safety and commercialization of sodium metal anodes.

ADVANCED SCIENCE (2021)

Article Chemistry, Multidisciplinary

Stable Dendrite-Free Sodium-Sulfur Batteries Enabled by a Localized High-Concentration Electrolyte

Jiarui He et al.

Summary: Ambient-temperature sodium-sulfur batteries offer a sustainable and low-cost alternative to lithium-ion batteries with their high specific energy, but face challenges like Na polysulfide shuttling, Na loss, and dendrite formation. By tweaking the solvation structure of the electrolyte, a solid electrolyte interphase rich in inorganic components can be achieved, leading to improved battery performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Energy & Fuels

Engineering rGO/MXene Hybrid Film as an Anode Host for Stable Sodium-Metal Batteries

Shiyang Wang et al.

Summary: A hybrid rGO/MXene film was fabricated to serve as a sodiophilic anode host for stabilizing sodium-metal anode, showing excellent electrochemical performance. By regulating sodium deposition behavior and suppressing dendrite growth, the electrode achieved high Coulombic efficiency and long-term cycling stability, as well as a low N/P ratio parallel to Na full cell with Na3V2(PO4)(3).

ENERGY & FUELS (2021)

Article Engineering, Multidisciplinary

Gram-scale synthesis of rGO wrapped porous α-Fe2O3 as an advanced anode material for Na-ion batteries with superior cyclic stability

Syam Kandula et al.

Summary: The gram-scale synthesis of alpha-Fe2O3@rGO core@shell nanocubes using a direct solution route demonstrates excellent efficiency in reducing costs. The materials exhibit promising electrochemical performance for practical energy storage devices, showcasing high specific capacities and good rate capabilities. This approach enables the synthesis of various electroactive materials in gram-scale with improved cost-effectiveness.

COMPOSITES PART B-ENGINEERING (2021)

Review Chemistry, Multidisciplinary

Recent advanced skeletons in sodium metal anodes

Chenxiao Chu et al.

Summary: Sodium metal anodes have high theoretical capacity and low redox potential, but face challenges such as dendrite growth. Using skeleton materials is an effective strategy to reduce local current density, inhibit dendrite growth, and alleviate volume expansion in sodium metal anodes.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Advanced in situ technology for Li/Na metal anodes: an in-depth mechanistic understanding

Jun Pu et al.

Summary: Metallic Li/Na anodes are promising alternatives for high energy batteries due to their high theoretical capacity and low electrochemical potential. However, issues such as unstable solid-electrolyte interphase and dendrite growth have led to decline in cycle performance. In recent years, research interest in in situ technologies has surged globally, aiming to understand reaction processes and structure evolution of metallic Li/Na through advanced techniques. Addressing the key issues in metallic Li/Na anodes with a focus on emerging in situ electrode design and advanced electrochemistry mechanism analysis is essential for achieving next-generation reliable and stable metal anodes.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Materials Science, Multidisciplinary

A critical analysis of the X-ray photoelectron spectra of Ti3C2Tz MXenes

Varun Natu et al.

Summary: MXenes, discovered in 2011, have attracted global attention due to their 2D structure and surface chemistry. This review critically evaluates XPS fitting models for Ti3C2Tz MXene, suggesting a new algorithm for quantifying surface terminations based on previously published data. The proposed method assigns various peaks to different Ti atom terminations and identifies a universal reference peak for carbon atoms in the material.

MATTER (2021)

Article Chemistry, Multidisciplinary

Advanced Li metal anode by fluorinated metathesis on conjugated carbon networks

Yong Jun Gong et al.

Summary: The study successfully addressed the challenge of unstable solid electrolyte interphase (SEI) on a Li metal anode by applying graphene-coated aramid to the separator, inducing LiF formation through fluorinated metathesis on a conjugated carbon network. Additional experiments demonstrated the effectiveness of this method with other CCN materials, showing that negative functionalities and lattice structure of the materials played a role in the fluorination process.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Materials Science, Multidisciplinary

Scalable Synthesis of Ti3C2Tx MXene

Christopher E. Shuck et al.

ADVANCED ENGINEERING MATERIALS (2020)

Article Chemistry, Multidisciplinary

Core-Shell C@Sb Nanoparticles as a Nucleation Layer for High-Performance Sodium Metal Anodes

Guanyao Wang et al.

NANO LETTERS (2020)

Article Chemistry, Multidisciplinary

A 3D Hydroxylated MXene/Carbon Nanotubes Composite as a Scaffold for Dendrite-Free Sodium-Metal Electrodes

Xin He et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Nanoscience & Nanotechnology

Large-Area 2D-MXene Nanosheet Assemblies Using Langmuir-Schaefer Technique: Wrinkle formation

Hyeri Kim et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Review Chemistry, Multidisciplinary

Solid Electrolyte Interphases on Sodium Metal Anodes

Changyuan Bao et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Physical

Tortuosity Effects in Lithium-Metal Host Anodes

Hao Chen et al.

Review Chemistry, Multidisciplinary

Sodium Metal Anodes: Emerging Solutions to Dendrite Growth

Byeongyong Lee et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Multidisciplinary

A Sodiophilic Interphase-Mediated, Dendrite-Free Anode with Ultrahigh Specific Capacity for Sodium-Metal Batteries

Lei Ye et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Pillared MXene with Ultralarge Interlayer Spacing as a Stable Matrix for High Performance Sodium Metal Anodes

Jianmin Luo et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Chemistry, Physical

The adhesion energy measured by a stress accumulation-peeling mechanism in the exfoliation of graphite

Minggang Xia et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

Article Chemistry, Physical

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries

Brian D. Adams et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Physical

Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes

Jianming Zheng et al.

ACS ENERGY LETTERS (2018)

Review Energy & Fuels

Batteries and fuel cells for emerging electric vehicle markets

Zachary P. Cano et al.

NATURE ENERGY (2018)

Article Chemistry, Physical

Rethinking sodium-ion anodes as nucleation layers for anode-free batteries

Adam P. Cohn et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

Ultrathin Surface Coating Enables the Stable Sodium Metal Anode

Wei Luo et al.

ADVANCED ENERGY MATERIALS (2017)

Article Chemistry, Multidisciplinary

Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance

Jun Yan et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Article Nanoscience & Nanotechnology

In-Depth Interfacial Chemistry and Reactivity Focused Investigation of Lithium-Imide- and Lithium-Imidazole-Based Electrolytes

Gebrekidan Gebresilassie Eshetu et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Chemistry, Multidisciplinary

Microsized Sn as Advanced Anodes in Glyme-Based Electrolyte for Na-Ion Batteries

Biao Zhang et al.

ADVANCED MATERIALS (2016)

Review Physics, Multidisciplinary

Raman spectroscopy of carbon nanotubes

MS Dresselhaus et al.

PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS (2005)