Alginate microcapsules produced by external gelation in milk with application in dairy products

This study aims to explore possibility of production of alginate microcapsules by extrusion-dripping onto bovine milk directly. As a source of calcium necessary for capsules formation, three different types of milk were used (skimmed, whole and enriched milk). In that respect, impact of milk type and properties (e.g. density, viscosity, surface tension and soluble calcium content) on capsules formation was studied. In addition, influence of alginate type and concentration on capsules formation was assessed. The properties of the milk, viscosity in particular, contributed to the greater extent of microcapsules deformation in comparison to ones produced using CaCl2 solution. More concentrated alginate solutions (up to 1.5%), yielded in more spherical capsules; the same was noticed with G-rich alginate. Upon microcapsules production, significant decrease in soluble calcium (23-27% reduction) and total protein content (1-4% reduction) of milk was observed; this can be assigned to the interactions with alginate network, which was further confirmed via confocal laser scanning microscopy. Encapsulation efficiency study showed that developed capsules were able to entrap blue dextrans at satisfactory extent (from 43 & PLUSMN; 2% to 56 & PLUSMN; 1%), where higher efficiency of encapsulation was achieved for the blue dextrans of higher molecular weight.

Automated summary

This study investigates the feasibility of producing alginate microcapsules by directly extruding and dripping them onto bovine milk. Three types of milk (skimmed, whole, and enriched milk) were used as a calcium source for capsule formation. The study analyzed the impact of milk type and properties, as well as alginate type and concentration, on the formation of capsules. The results showed that milk properties, particularly viscosity, influenced the deformation of microcapsules more than when using a CaCl2 solution. More concentrated alginate solutions and G-rich alginate resulted in more spherical capsules. The study also observed a decrease in soluble calcium and total protein content in milk after microcapsule production, indicating interactions with the alginate network