Optimization, Kinetics, and Isotherm Studies of Methyl Thioninium Chloride Removal from Simulated Solutions Using Chitosan Derivatives

Methylene blue (MB) dye or methyl thioninium chloride is one of the hazardous cationic dyes that are discharged into the textile effluent causing a highly negative environmental impact. The present work targets the investigation of the adsorption performance of some chitosan-modified products toward the MB dye from simulated solutions. The claimed chitosan derivatives were prepared, characterized, and applied for the removal of lead and copper cations from an aqueous medium in a previous work. These include: N,O-carboxymethyl chitosan (N,O-CM/Cs), chitosan grafted with glutaraldehyde (Cs/GA), chitosan cross-linked with GA/epichlorohydrin (Cs/GA/ECH), and chitosan cross-linked with glutaraldehyde/methylene bis(acrylamide) (Cs/GA/MBA). The modified chitosan derivatives in this study displayed outstanding mechanical qualities, exceptional reusability, and a significant amount of adsorption capacity. The ability of prepared Cs derivatives to eradicate MB was as follows: N,O-CM/Cs (95.1 mg/g) < Cs/GA (120.1 mg/g) < Cs/GA/ECH (220.1 mg/g) < Cs/GA/MBA (270.0 mg/g). The swelling performance of the prepared sorbents was verified under different experimental conditions, and the data revealed that the maximum swelling was attained at pH = 9, temperature 55 degrees C, and after 24 h. The produced Cs derivatives showed exceptional reusability by maintaining higher adsorption effectiveness throughout five cycles. The MB dye was adsorbed onto the modified derivatives according to pseudosecond-order kinetics and the Langmuir model. Moreover, the adsorption process was monitored via atomic force microscopy to verify the differences between the dye-free and dye-loaded adsorbents.

Automated summary

This study investigated the adsorption performance of some chitosan-modified products on the removal of Methylene Blue dye. The modified chitosan derivatives showed outstanding mechanical qualities, reusability, and adsorption capacity. The adsorption abilities of the derivatives were ranked as follows: N,O-carboxymethyl chitosan < chitosan grafted with glutaraldehyde < chitosan cross-linked with glutaraldehyde/epichlorohydrin < chitosan cross-linked with glutaraldehyde/methylene bis(acrylamide). The swelling performance of the sorbents was verified under different conditions and the derivatives showed good reusability throughout multiple cycles.