期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 9, 页码 2125-2131出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500252
关键词
benzyl esters; catalysis; C-H activation; iron
资金
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Key Laboratory of Organic Synthesis of Jiangsu Province
- American Chemical Society Petroleum Research Fund [54247-UNI3]
- PSC-CUNY award from the City University of New York [67312-0045]
An atom-economic and efficient non-precious metal-catalyzed esterification of benzyl C-H bonds has been developed. A variety of a-keto benzyl esters have been accessed in good yields through the reactions between benzyl derivatives and benzoylformic acids using iron trifluoride as a catalyst in the presence of di-tert-butyl peroxide under an inert atmosphere. This strategy provides a straightforward access to linearly expanded alpha-keto benzyl esters. A plausible reaction mechanism is proposed.
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