期刊
JOURNAL OF WATER PROCESS ENGINEERING
卷 54, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jwpe.2023.103925
关键词
BiOCl; Kaolinite; Co-precipitation; Photocatalysis; Rhodamine B; Sunlight
The study developed a nanocomposite BiOCl@Kaol for the photodegradation of Rhodamine B dye in water. The BiOCl@Kaol nanocomposite exhibited high photocatalytic activity, achieving 100% degradation efficiency within 35 minutes. Additionally, the optimal Clay/BiOCl ratio of 0.4 resulted in 4.37 times better photocatalytic performance compared to bare BiOCl. Monte Carlo calculations revealed the establishment of hydrogen bonds between BiOCl and kaolinite particles, as well as van der Waals attraction between RhB molecules and the BiOCl@Kaol surface.
The development of advanced photocatalytic materials for environmental purposes is among the high research topics. In the present work, a nanocomposite BiOCl@Kaol, made of kaolinite supported Bismuth Oxychloride BiOCl photocatalyst, was designed for Rhodamine B dye photodegradation in aqueous solution. The obtained BiOCl@Kaol nanocomposite exhibited high photocatalytic activity in the removal of Rhodamine B dye (RhB) from water, with a degradation efficiency reaching 100 % within 35 min. Furthermore, it was observed that the nanocomposite photocatalyst, BiOCl@0.4Kaol, at optimal Clay/BiOCl ratio of 0.4, exhibited 4.37 times better photocatalytic performance, compared to bare BiOCl. Finally, to elucidate the photodegradation mechanisms, we determined various interactions occurring between BiOCl and kaolinite particles, as well as between RhB molecules and BiOCl@Kaol nanocomposites, using Monte Carlo calculations. It was concluded from Monte Carlo calculations that hydrogen bonds were established between oxygen atoms of BiOCl and H of kaolinite (001) hydroxyl groups upon the adsorption of BiOCl (003) particles on the kaolinite (001) surface, owing to its high negative interaction energy. Meanwhile, van der Waals attraction was also established between the RhB molecules and the BiOCl@Kaol (001) surface.
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