Facile Synthesis of Citric Acid Functionalized Fe3O4@Activated Carbon Magnetic Nanocomposite for Efficient Adsorption of Brilliant Green Dye from Wastewater

Owing to the impact of brilliant green dye on potable water contamination, citric acid functionalized magnetic nanocomposite in presence of activated carbon was prepared for easy, quick, and efficient removal of the dye from water. Batch adsorption studies were conducted to maximize the adsorption efficiency by optimizing contact time, initial dye concentration, pH, dosage, and salt concentration. The maximum efficiency of the citric acid functionalized Fe3O4@activated carbon was found to be 773 mg g(-1). The efficiency of the monolayer adsorption process as depicted from the Langmuir model is explained based on the hydrogen bonding, electrostatic interaction, and porosity of the adsorbent. The adsorption process follows a pseudo-second order kinetics model which can also be correlated to the relatively quick adsorption process. The saturation magnetization of the nanocomposites prepared in presence of activated carbon was found to be 35.2 emu/g, which makes it effective for quick magnetic separation. Built on the findings, we report an economical, efficient, and satisfactory alternative adsorbent for the abatement of brilliant green dye from coloured wastewater and contaminated water sources.

Automated summary

This study prepared a novel adsorbent using citric acid functionalized magnetic nanocomposite and activated carbon for efficient removal of brilliant green dye from water. The maximum efficiency reached 773 mg g(-1) by optimizing contact time, initial dye concentration, pH, dosage, and salt concentration. The adsorption process followed a pseudo-second order kinetics model and was explained by the hydrogen bonding, electrostatic interaction, and porosity of the adsorbent. The prepared nanocomposite exhibited high saturation magnetization, making it effective for quick magnetic separation.