Microstructure and properties of AlCrFeNiMoNb high-entropy alloys coating on ZM5 magnesium alloy prepared by high-velocity air fuel (HVAF) spray

AlCrFeNiMoNb high-entropy alloys were successfully coated onto a ZM5 alloy using high -velocity air fuel spray (HVAF). Microcomputed tomography(micro-CT) results revealed that the porosity of the coating was only 0.36%, which demonstrates the coating has a highly dense structure. The average microhardness of high-entropy alloys coating was > 5 times greater than that of the ZM5 alloy substrate. The changes of ZM5 substrate microhardness can be attributed to dynamic recrystallisation. The corrosion potential (E-corr) of the AlCr-FeNiMoNb coating was improved to approximately similar to -0.998 V and the corrosion current (I-corr) of the coating significantly decreased by two orders of magnitude. The wear volume loss of the coating was similar to 15 times lower than that of the ZM5 substrate. This indicates that the coating of the AlCrFeNiMoNb high-entropy alloy on the ZM5 substrate significantly improved the wear resistance of the ZM5 alloy. The ZM5 alloy surface had better corrosion and wear resistance properties owing to the protection offered by the AlCrFeNiMoNb high -entropy alloy. (c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

AlCrFeNiMoNb high-entropy alloys were coated onto a ZM5 alloy using high-velocity air fuel spray, resulting in a highly dense structure and significantly improved wear and corrosion resistance properties of the ZM5 alloy.