Research progress on electrochemical CO2 reduction for Cu-based single-atom catalysts

Article Multidisciplinary Sciences

Selective CO2 electrolysis to CO using isolated antimony alloyed copper

Jiawei Li et al.

Summary: The researchers achieved CO2 reduction at high current density with a Faradaic efficiency over 95% by tuning the CO selectivity of copper through alloying, using an antimony-copper single-atom alloy catalyst.

NATURE COMMUNICATIONS (2023)

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Article Materials Science, Multidisciplinary

Theoretical studies of non-noble metal single-atom catalyst Ni1/MoS2: Electronic structure and electrocatalytic CO2 reduction

Qi Yu

Summary: Single-atom catalysts (SACs), with high catalytic selectivity and tunable activity, have attracted significant attention in recent years. This study computationally screened non-noble metal SACs supported on MoS2, and found that Ni-1/MoS2 catalyst is the most stable among 3d-series SACs. The bonding properties between metal single atoms and MoS2 support, including Ni-S and Ni-Mo bonding, were systematically examined, which are critical for the electronic structure, stability, and catalytic properties of Ni-1/MoS2 catalyst. Furthermore, the high catalytic activity of Ni-1/MoS2 catalyst for CO2 reduction reaction (CO2RR) to methanol was investigated, providing theoretical insights for the design of efficient SACs on MoS2-based functional materials.

SCIENCE CHINA-MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Probing the Roles of Indium Oxides on Copper Catalysts for Enhanced Selectivity during CO2-to-CO Electrochemical Reduction

Yanyan Jia et al.

Summary: By decorating a small amount of In2O3 on the Cu surface, a composite Cu-In2O3 catalyst is developed, which greatly enhances the selectivity and stability for CO2-to-CO reduction. In situ X-ray absorption spectroscopy confirms the redox reaction of In2O3 and the preservation of Cu's metallic state during CO2RR. The strong electronic interaction and coupling at the Cu/In2O3 interface serve as the active site for selective CO2RR.

NANO LETTERS (2023)

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Review Chemistry, Physical

Recent progress of metal single-atom catalysts for energy applications

Qingqing Yang et al.

Summary: Single-atom catalysts (SACs) are highly sought after in heterogeneous catalysis due to their exceptional catalytic performance and stability. Metal SACs have distinct advantages in activity, selectivity, and tunable interactions with supports. This review summarizes the preparation and performance of metal SACs in energy-related applications, including oxygen reduction, hydrogen evolution, N2 reduction, methane conversion, CO2 reduction, CO oxidation, biomass conversion, and environmental pollutant degradation. The challenges and development trends of SACs in industrial applications are discussed.

NANO ENERGY (2023)

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Review Materials Science, Multidisciplinary

The understanding, rational design, and application of high-entropy alloys as excellent electrocatalysts: A review

Yuanbo Zhou et al.

Summary: High-entropy alloys (HEAs) have attracted considerable attention in electrocatalysis due to their excellent activity and selectivity, which can be attributed to the high entropy effect, lattice distortion effect, sluggish diffusion effect, and cocktail effect. However, a systematic summarization of the understanding and rational design of HEA electrocatalysts is lacking. This review provides a systematic summary of HEA electrocatalysts' characteristics and applications, as well as a clarification of their design principles, which has guiding importance for HEA development.

SCIENCE CHINA-MATERIALS (2023)

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Review Materials Science, Multidisciplinary

Recent development in metal halide perovskites synthesis to improve their charge-carrier mobility and photocatalytic efficiency

Marija Knezevic et al.

Summary: In the past decade, all-inorganic metal halide perovskites have been extensively studied as promising materials for optoelectronic devices. They have defect-tolerant properties and can tune their bandgap without affecting their photophysical properties. This review provides an overview of various engineering strategies for metal halide perovskites, which directly influence their charge-carrier mobility, lifetimes, and photocatalytic efficiency. Synthetic approaches such as surface and morphological modifications, anion/cation substitution, metallic doping, coupling, and encapsulation greatly impact the stability, optical properties, and charge-carrier dynamics of perovskites at different time scales.

SCIENCE CHINA-MATERIALS (2023)

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Article Chemistry, Physical

Molecular-level electrocatalytic CO2 reduction reaction mediated by single platinum atoms

Gaoxiang Liu et al.

Summary: This study demonstrates the activation and transformation of H2O and CO2 mediated by electrons and single Pt atoms at the molecular level. The reaction mechanism is revealed by the synergy of mass spectrometry, photoelectron spectroscopy, and quantum chemical calculations. The findings provide insights into the design of novel catalysts for the electrochemical conversion of CO2.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022)

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Article Chemistry, Physical

Photocatalytic degradation of methylene blue (MB) with Cu1-ZnO single atom catalysts on graphene-coated flexible substrates

Ping Rong et al.

Summary: Cu-1-ZnO/GPET composite material with Cu atom dopants shows significantly enhanced photocatalytic activity. The Cu atoms capture photogenerated electrons and help separate them from holes, leading to the activation of O2 and the generation of hydroxyl radicals through reaction with water, resulting in efficient degradation of pollutants.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Multidisciplinary

Recent progress in advanced core-shell metal-based catalysts for electrochemical carbon dioxide reduction

Fengqi Wang et al.

Summary: This review focuses on the recent progress and applications of core-shell metal-based catalysts (CMCs) in electrochemical carbon dioxide reduction (CO2RR). The article covers the mechanisms and evaluation parameters of electrochemical CO2RR, preparation methods and advantages of core-shell metal catalysts, and the advanced CMCs in CO2RR.

CHINESE CHEMICAL LETTERS (2022)

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Article Chemistry, Multidisciplinary

Constructing Cu-C Bonds in a Graphdiyne-Regulated Cu Single-Atom Electrocatalyst for CO2 Reduction to CH4

Guodong Shi et al.

Summary: By anchoring Cu single atoms on graphdiyne, we successfully constructed a Cu-C bond, which promotes the formation of CH4 during CO2 reduction and enhances catalytic performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Review Chemistry, Inorganic & Nuclear

Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

Abebe Reda Woldu et al.

Summary: The article provides a brief overview of CO2RR and discusses recent advances in improving the activity and selectivity of Cu-based nanomaterials for CO2 reduction to multi-carbon products. It reviews different types of Cu nanoparticles, Cu nanocrystals with low- and high-index facets, and other Cu-based nanostructures for CO2RR. The aim of the review is to offer new insights and prospects for future research on CO2RR selectivity using Cu-based catalysts.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Chemistry, Physical

Recent advances in the rational design of single-atom catalysts for electrochemical CO2 reduction

Huoliang Gu et al.

Summary: This review focuses on the structure-function correlation of single-atom catalysts (SACs) in electrochemical CO2 reduction (CO2R). Despite various SACs with attractive CO2R performances have been reported, the relationship between electronic/geometric structure of SACs and their corresponding electrocatalytic performance still needs further research and guidance for rational design.

NANO RESEARCH (2022)

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Article Chemistry, Physical

Rational design of copper-based single-atom alloy catalysts for electrochemical CO2 reduction

Jian-Chao Jiang et al.

Summary: In this study, a series of Cu-based single-atom alloy catalysts (SAAs) were designed and evaluated for CO2RR. The catalysts showed improved activity for CO2 hydrogenation compared to pure Cu catalysts. The bond angle of adsorbed *CO2 and binding energy of *OH were identified as indicators for CO2 activation ability and CO2RR activity, respectively.

NANO RESEARCH (2022)

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Article Multidisciplinary Sciences

In situ dual doping for constructing efficient CO2-to-methanol electrocatalysts

Pengsong Li et al.

Summary: A dual doping strategy was used in this study to construct efficient CO2-to-methanol electrocatalysts. The results showed that this approach significantly enhanced the selectivity and current density of methanol formation, providing a new direction for the design of efficient catalysts for CO2 electroreduction to methanol.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Identifying Key Descriptors for the Single-Atom Catalyzed CO Oxidation

Max J. Hulsey et al.

Summary: Understanding the structure-activity correlations for heterogeneous single-atom catalysts (SACs) is crucial for catalytic design. In this study, we found that linear scaling relations were not applicable for SACs and established multiple scaling relations between activity and calculated descriptors. The thermodynamic driving force for oxygen vacancy formation was identified as an important factor in addition to substrate adsorption energies, particularly for CO. This work presents a successful approach for re-establishing scaling relations for SACs and has broad implications for catalytic processes involving this type of catalyst.

CCS CHEMISTRY (2022)

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Review Chemistry, Applied

Rational design strategies of Cu-based electrocatalysts for CO2 electroreduction to C2 products

Shuo Liu et al.

Summary: This review summarizes the recent progress in the mechanistic studies of Cu-based catalysts for the reduction of CO2 to C-2 products. The key strategies for enhancing the electrocatalytic performance of Cu-based catalysts, including tuning electronic structure, surface structure, and coordination environment, are focused on. The correlation between the structural characteristics of Cu-based catalysts and their activity and selectivity to C-2 products is discussed.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Dynamic Stability of Copper Single-Atom Catalysts under Working Conditions

Xiaowan Bai et al.

Summary: This study evaluates the dynamic stability of single copper atom catalysts under realistic reaction conditions using a constant-potential hybrid-solvation dynamic model. The adsorption of H is found to be the key driving force for the leaching of copper single atoms from the catalyst surface. The study provides a fundamental understanding of the dynamic stability of Cu single-atom catalysts and calls for a reassessment of the stability of currently reported single-atom catalysts considering realistic reaction conditions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Review Chemistry, Physical

Electrochemical Reduction of Carbon Dioxide: Recent Advances on Au-Based Nanocatalysts

Qisi Chen et al.

Summary: This review introduces the electrochemical reduction of CO2 and focuses on recent accomplishments with respect to Au-based nanocatalysts. Manipulating various factors allows for the identification of clues for excellent Au-based nanocatalysts.

CATALYSTS (2022)

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Review Chemistry, Multidisciplinary

Current state of copper-based bimetallic materials for electrochemical CO2 reduction: a review

Otmane Zoubir et al.

Summary: This review article provides insight into important parameters and synthesis methods for electrocatalytic CO2 reduction over bimetallic copper-based materials. Challenges and perspectives for further advancement of this rapidly growing technology are also discussed.

RSC ADVANCES (2022)

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Article Chemistry, Physical

Crystal facet effects of platinum single-atom catalysts in hydrolytic dehydrogenation of ammonia borane

Qingdi Sun et al.

Summary: Pt1/Co3O4-c catalysts exhibit great catalytic activities in hydrolytic dehydrogenation, with electron depletion of single-atomic Pt species tailored by supports.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Review Nanoscience & Nanotechnology

Defect Engineering on Carbon-Based Catalysts for Electrocatalytic CO2 Reduction

Dongping Xue et al.

Summary: This paper systematically introduces the main construction methods of carbon-based nanomaterials with different defects, and reviews the structure-activity relationship of defective carbon-based catalysts in electrocatalytic carbon dioxide reduction (ECR) reaction. The challenges and opportunities of high-performance defective CBN in ECR are discussed, along with possible future solutions.

NANO-MICRO LETTERS (2021)

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Article Multidisciplinary Sciences

Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane

Yanming Cai et al.

Summary: Single-atom catalysts are promising for catalyzing CO2 reduction to produce high value hydrocarbons, but most reactions yield CO. In this study, a low-temperature calcining process was used to fabricate a carbon-dots-based SAC which efficiently converts CO2 to methane.

NATURE COMMUNICATIONS (2021)

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Review Electrochemistry

Electrospun nanofibers for electrochemical reduction of CO2: A mini review

Xin Zong et al.

Summary: This review discusses the electrochemical reduction of CO2 and the application of electrospun nanofibers as CO2RR catalysts. The paper analyzes the advantages of electrospinning technology in preparing CO2RR catalysts, reviews the recent progress in this field, and outlines the future prospects and challenges of electrospun materials for CO2RR.

ELECTROCHEMISTRY COMMUNICATIONS (2021)

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Review Chemistry, Physical

Advances in green synthesis and applications of graphene

Qi Yu et al.

Summary: Green synthesis of graphene has gained significant attention for its potential in sustainable developments, with various environmentally friendly synthesis methods being explored. The exceptional properties of graphene make it ideal for applications in energy storage, catalysis, electrochemistry, and other fields.

NANO RESEARCH (2021)

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Review Chemistry, Multidisciplinary

Architectural Design for Enhanced C2 Product Selectivity in Electrochemical CO2 Reduction Using Cu-Based Catalysts: A Review

Changlong Xiao et al.

Summary: Electrochemical conversion of CO2 to value-added chemicals and fuels using Cu catalysts has shown promising potential, but poor product selectivity remains a major technical challenge for global applications. Tailoring the electrocatalyst architecture through nanotechnology principles can significantly impact the adsorption energetics of key intermediates and reaction pathways.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

High-Rate CO2 Electroreduction to C2+ Products over a Copper-Copper Iodide Catalyst

Hefei Li et al.

Summary: The study successfully designed a Cu-CuI composite catalyst that achieves high-efficiency production of C2+ products.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Energy & Fuels

Tailored catalyst microenvironments for CO2 electroreduction to multicarbon products on copper using bilayer ionomer coatings

Chanyeon Kim et al.

Summary: The authors investigated and optimized the microenvironment near the copper catalyst surface using bilayer ionomer coatings to improve the efficiency of CO2 reduction. By tailoring the microenvironment and coupling it with pulsed electrolysis, higher local CO2/H2O ratio and pH values are achieved, leading to selective C2+ production.

NATURE ENERGY (2021)

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Article Chemistry, Physical

High-purity and high-concentration liquid fuels through CO2 electroreduction

Peng Zhu et al.

Summary: Liquid fuels generated from the electrochemical CO2 reduction reaction have high energy densities and storage advantages, but are often produced in low concentrations and mixed with impurities due to limitations in current traditional CO2 electrolyzers and CO2RR catalysts. Strategies in reactor engineering and catalyst improvement are proposed to overcome these challenges and make electrochemical production of liquid fuels more competitive in the future.

NATURE CATALYSIS (2021)

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Review Chemistry, Physical

Tandem catalysis in electrochemical CO2 reduction reaction

Yating Zhu et al.

Summary: Electrochemical CO2 reduction through tandem catalysis has shown promise in enhancing efficiency, with limitations primarily due to high overpotential and poor selectivity in producing highly reduced carbon compounds. Recent advances in tandem catalysis for CO2RR have provided effective methods to improve performance, indicating potential for further research and development.

NANO RESEARCH (2021)

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Review Materials Science, Multidisciplinary

A review of non-noble metal-based electrocatalysts for CO2 electroreduction

Jia-Jun Wang et al.

Summary: Excessive CO2 emissions have caused severe environmental issues, leading to the exploration of non-noble metal-based CO2RR catalysts as a critical solution. Researchers summarized the recent advances and classification of such catalysts, discussing their preparation strategies and CO2RR mechanisms in detail.

RARE METALS (2021)

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Article Chemistry, Applied

Influence of Pore Structure of Silica Coated on Copper-Zinc Oxide-Based Catalyst for Carbon Dioxide into Methanol

Tetsuo Umegaki et al.

Summary: By controlling the amount of surfactant and swelling agent, the pore structure of the silica-coated catalyst was successfully adjusted, resulting in increased specific surface area and mesopore ratio, which led to a catalyst with high activity and stability for hydrogenation of carbon dioxide into methanol.

TOPICS IN CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Recent Progresses in Electrochemical Carbon Dioxide Reduction on Copper-Based Catalysts toward Multicarbon Products

Jinli Yu et al.

Summary: Electrochemical carbon dioxide reduction reaction offers a promising way of converting CO2 to value-added chemicals, but the conversion to more valuable multicarbon products remains challenging. Recent progress in using copper-based catalysts for electrochemical CO2 reduction to multicarbon products is reviewed, with a focus on catalyst engineering and cell engineering approaches.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

A Tandem Strategy for Enhancing Electrochemical CO2 Reduction Activity of Single-Atom Cu-S1N3 Catalysts via Integration with Cu Nanoclusters

Datong Chen et al.

Summary: In this study, a tandem electrocatalyst for CO2-to-CO conversion was developed, achieving high Faradaic efficiency and stability. The asymmetric Cu-S1N3 atomic interface, along with the adjacent Cu-x, promotes proton-coupled electron transfer over atomic-level catalytic sites.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Highly Selective Tandem Electroreduction of CO2 to Ethylene over Atomically Isolated Nickel-Nitrogen Site/Copper Nanoparticle Catalysts

Dong-Li Meng et al.

Summary: An effective tandem catalysis strategy was developed to improve the selectivity of CO2RR towards C2H4, using multiple distinct catalytic sites in local vicinity. A tandem electrocatalyst PTF(Ni)/Cu was constructed, which significantly enhanced the Faradaic efficiency of C2H4 to 57.3% at -1.1 V versus RHE. Experimental and theoretical results showed that the local high concentration of CO generated by PTF(Ni) sites facilitated the C-C coupling on nearby Cu NP sites to form C2H4.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Engineering, Environmental

A review on electrochemical synthesized copper-based catalysts for electrochemical reduction of CO2 to C2+ products

Wangxiang Ye et al.

Summary: In recent years, copper-based catalysts for electrocatalytic CO2 reduction have attracted significant attention, despite facing challenges in low selectivity, hydrogen evolution, and stability. The synthesis of Cu-based catalysts via electrochemical methods offers advantages in terms of simple process, controllable conditions, durability, and eco-friendliness, providing a direction for the development of low-cost, high-performance Cu-based catalysts in the future.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

Research progress of electrochemical CO2 reduction for copper-based catalysts to multicarbon products

Zhiyuan Ni et al.

Summary: This review summarizes the design strategies of copper-based catalysts to improve the performance of ECO2RR, including structure, defect, compounds-derived catalysts, bimetallic construction, and heterogeneous engineering. The correlation between the formation mechanism of the C-C bond and the structural characteristics of the catalyst is discussed, along with the main challenges of reducing CO2 to C2+ products such as low selectivity, low activity, and low stability. This review also provides distinctive insights and potential strategies for the design and performance optimization of copper-based catalysts.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Nanoscience & Nanotechnology

Copper-catalysed exclusive CO2 to pure formic acid conversion via single-atom alloying

Tingting Zheng et al.

Summary: The single-atom Pb-alloyed Cu catalyst (Pb1Cu) efficiently converts CO2 into formic acid with high selectivity and activity, offering the potential to increase productivity.

NATURE NANOTECHNOLOGY (2021)

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Article Multidisciplinary Sciences

First-principles design of a single-atom-alloy propane dehydrogenation catalyst

Ryan T. Hannagan et al.

Summary: The well-defined nature of single-atom-alloy catalysts allows for unambiguous theoretical modeling and precise surface science experiments, leading to the design of highly active, selective, and coke-resistant catalysts for low-temperature nonoxidative propane dehydrogenation.

SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Single-Atom Electrocatalysts for Multi-Electron Reduction of CO2

Bingxing Zhang et al.

Summary: The rational design of single-atom electrocatalysts is crucial forachieving efficient multi-electron reduction of CO2 to hydrocarbons or alcohols. Various strategies in regulating the interactions between active sites and key reaction intermediates are summarized, aiming to optimize the catalytic performance and explore the activity origin at atomic level.

SMALL (2021)

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Article Chemistry, Physical

Highly Selective Two-Electron Electrocatalytic CO2 Reduction on Single-Atom Cu Catalysts

Chaochen Xu et al.

Summary: Cu-based electrocatalysts with high catalytic selectivity for the CO2 reduction reaction are a significant technological challenge. A Cu single atom catalyst, Cu-N-4-NG, has been developed for the selective electrocatalytic reduction of CO2 to CO, achieving an 80.6% Faradaic efficiency under moderate applied potential. The single-atom structure and coordination environment, along with moiety-anchoring graphene, contribute to the high selectivity and efficiency of CO production on Cu-N-4-NG compared to bulk Cu catalysts.

SMALL STRUCTURES (2021)

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Review Chemistry, Multidisciplinary

Recent advances in innovative strategies for the CO2 electroreduction reaction

Xinyi Tan et al.

Summary: The CO2RR system faces limitations in practical applications due to low current density, poor CO2 utilization, and energy efficiency. To improve its performance, systematic consideration and optimization of each component are necessary. This review focuses on innovative design strategies for tandem catalysts, electrolytes, electrodes, and devices, as well as discussions on opportunities and challenges for future advancements in the CO2RR system.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Electrocatalytic reduction of CO2 and CO to multi-carbon compounds over Cu-based catalysts

Wenchao Ma et al.

Summary: This tutorial review explores the electrocatalytic reduction of CO2 with H2O to multi-carbon (C2+) compounds, focusing on the similarities and differences in the electrocatalytic CO2 and CO reduction reactions (CO2RR and CORR) into C2+ compounds over Cu-based catalysts. It discusses fundamental aspects, reaction mechanisms, efficient catalysts, and key factors determining selectivity, activity, and stability. Opportunities, challenges, and future trends in the electrocatalytic CO2RR and CORR are also highlighted for the synthesis of C2+ olefins and oxygenates.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Multidisciplinary

Electrocatalysis for CO2 conversion: from fundamentals to value-added products

Genxiang Wang et al.

Summary: This article provides a comprehensive review of recent research progress on the selective electrocatalytic conversion of CO2 into value-added products. It covers the history and fundamental science of electrocatalytic CO2RR, the design, preparation, and performance evaluation of electrocatalysts, factors influencing the CO2RR, and associated theoretical calculations. Emphasis is placed on emerging trends in selective electrocatalytic conversion of CO2 and discussions on structure-performance relationships and mechanisms.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Multidisciplinary

Copper-based single-atom alloys for heterogeneous catalysis

Fengjuan Qin et al.

Summary: Single-atom alloy (SAA) catalysts play an important role in heterogeneous catalysis, with wide applications and outstanding performance in improving atom utilization and catalytic selectivity. Research progress on copper-based single-atom alloys is promising and shows potential applications in various catalytic reactions.

CHEMICAL COMMUNICATIONS (2021)

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Review Engineering, Environmental

CO2 towards fuels: A review of catalytic conversion of carbon dioxide to hydrocarbons

Mustapha D. Garba et al.

Summary: Meeting the ever-increasing global energy demands is a serious challenge of the 21st century, with one solution being the conversion of CO2 into hydrocarbon fuels. Utilizing heterogeneous catalysis with zeolite and non-zeolite based catalysts, as well as noble and transition metals, can lead to the production of high value-added HC fuels from CO2. This review article emphasizes the importance of research and technological advancements in this area for both industries and academia.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Review Chemistry, Physical

Recent Advances in Electrochemical CO2 Reduction Using Copper-Based Catalysts

Yichen Meng et al.

Summary: The burning of fossil fuels leads to an increase in CO2 concentration in the atmosphere, causing various climate-related issues. Utilizing renewable energy and capturing CO2 can help address these concerns. Copper-based catalysts show promise in electrochemical CO2 reduction, but improving the selectivity of valuable products remains a challenge. Further research is needed in this area to explore reaction mechanisms and enhance product selectivities.

ACTA PHYSICO-CHIMICA SINICA (2021)

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Review Chemistry, Multidisciplinary

Single-atom alloy catalysts: structural analysis, electronic properties and catalytic activities

Tianjun Zhang et al.

Summary: This review discusses the development and application of single-atom alloy catalysts, highlighting structural analysis at the atomic scale using microscopy and spectroscopy tools, electronic properties research through X-ray spectroscopy techniques and quantum calculations, and catalytic activity in representative reactions. It also proposes future perspectives for single-atom alloy catalysts from structural, electronic, and reactivity aspects.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Selenium-Doped Hierarchically Porous Carbon Nanosheets as an Efficient Metal-Free Electrocatalyst for CO2 Reduction

Bingxing Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Recent Advances in Atomic-Level Engineering of Nanostructured Catalysts for Electrochemical CO2 Reduction

Huiling Liu et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Accelerating CO2 Electroreduction to CO Over Pd Single-Atom Catalyst

Qun He et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Rational Design of Ag-Based Catalysts for the Electrochemical CO2 Reduction to CO: A Review

Dalei Sun et al.

CHEMSUSCHEM (2020)

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Article Chemistry, Analytical

Highly dispersed, single-site copper catalysts for the electroreduction of CO2 to methane

Teng Zhang et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Physical

Graphdiyne-Supported Single Iron Atom: A Promising Electrocatalyst for Carbon Dioxide Electroreduction into Methane and Ethanol

Xin Liu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Chemistry, Multidisciplinary

Competition between CO2 Reduction and Hydrogen Evolution on a Gold Electrode under Well-Defined Mass Transport Conditions

Akansha Goyal et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

Atomic-level tuning of Co-N-C catalyst for high-performance electrochemical H2O2 production

Euiyeon Jung et al.

NATURE MATERIALS (2020)

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Review Chemistry, Physical

Promises of Main Group Metal-Based Nanostructured Materials for Electrochemical CO2 Reduction to Formate

Na Han et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

Boosting CO2 Electroreduction to CH4 via Tuning Neighboring Single-Copper Sites

Anxiang Guan et al.

ACS ENERGY LETTERS (2020)

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Article Energy & Fuels

Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts

Linan Zhou et al.

NATURE ENERGY (2020)

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Review Chemistry, Multidisciplinary

Recent Progress on Bismuth-based Nanomaterials for Electrocatalytic Carbon Dioxide Reduction

Chan Yang et al.

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES (2020)

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Article Multidisciplinary Sciences

Synergy effects on Sn-Cu alloy catalyst for efficient CO2 electroreduction to formate with high mass activity

Ke Ye et al.

SCIENCE BULLETIN (2020)

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Article Chemistry, Physical

Heterogeneous Catalysts with Well-Defined Active Metal Sites toward CO2 Electrocatalytic Reduction

Deren Yang et al.

ADVANCED ENERGY MATERIALS (2020)

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Review Materials Science, Multidisciplinary

Graphene-supported metal single-atom catalysts: a concise review

Shuai Ren et al.

SCIENCE CHINA-MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation

Yu Xiong et al.

NATURE NANOTECHNOLOGY (2020)

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Article Chemistry, Physical

Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C-C coupling over fluorine-modified copper

Wenchao Ma et al.

NATURE CATALYSIS (2020)

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Review Chemistry, Multidisciplinary

Single-Atom Alloy Catalysis

Ryan T. Hannagan et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Non-Metal Single-Phosphorus-Atom Catalysis of Hydrogen Evolution

Weiwei Fu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Inside Cover: Electrochemical Reduction of CO 2 to Ethane through Stabilization of an Ethoxy Intermediate (Angew. Chem. Int. Ed. 44/2020)

Anthony Vasileff et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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