4.6 Review

An Overview of Active Electrode Materials for the Efficient High-Performance Supercapacitor Application

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Article Engineering, Electrical & Electronic

Hierarchical-nanofiber structure of biomass-derived carbon framework with direct CO2 activation for symmetrical supercapacitor electrodes

Rakhmawati Farma et al.

Summary: Biomass-based activated carbon materials derived from date seeds have been successfully used as high-performance electrodes for supercapacitor cells. The carbon electrodes, with a hierarchical-nanofiber architecture, showed interconnected pores and exhibited excellent electrochemical performance. The activation temperature of CO2 can adjust the pore size distribution and the hierarchical-nanofiber architecture contributed to increased capacitance and abundant oxygen on the carbon matrix surface.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2023)

Article Energy & Fuels

Role of various redox additive electrolytes on the electrochemical performances of mixed metal oxide loaded multiwalled carbon nanotube based supercapacitors

G. Hariharan et al.

Summary: The electrochemical performances of Zinc oxide/Nickel oxide loaded multi-walled carbon nanotubes were evaluated under different electrolytes. The synthesized nanocomposites were characterized for their structural and morphological properties. The modified working electrodes exhibited superior electrochemical performance and specific capacitance retention, indicating the potential of these materials for energy storage applications.

JOURNAL OF ENERGY STORAGE (2023)

Review Energy & Fuels

Research advance of NiCoP-based materials for high-performance supercapacitors

Changyi Deng et al.

Summary: Transition metal phosphides have high electrical conductivity and electrochemical activity, making them widely used in energy storage and conversion applications such as electrocatalysis, Li-S batteries, and supercapacitors. Bimetallic phosphides show even higher electrochemical activity due to the synergistic effect between different phosphide phases. This review highlights the recent advances in NiCoP-based electrode materials for high-performance supercapacitors, including synthesis methods, heteroatom doping, design principles, and the synergistic effects of different components. In addition, it discusses existing problems, possible solutions, and future research trends, providing practical guidelines for the development of metal phosphide-based electrode materials.

JOURNAL OF ENERGY STORAGE (2023)

Article Chemistry, Multidisciplinary

Layered Double Hydroxide with Interlayer Quantum Dots and Laminate Defects for High-Performance Supercapacitor

Qingjun Yang et al.

Summary: Due to their flexible adjustability, laminates in layered double hydroxides (LDHs) can enhance conductivity and capacitance. However, regulating interlayer activity has been a challenge due to charge repulsion between laminates. In this study, a dual-activity design of LDHs is achieved by introducing laminate defects and interlayer ZnS quantum dots (QDs). The resulting CuCo-LDH-S/ZnS-QDs structure exhibits a 3D self-supporting structure with ultrastability, delivering high capacitance and outstanding cycle life.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Energy & Fuels

Nickel and cobalt oxides supported on activated carbon derived from willow catkin for efficient supercapacitor electrode

Mostafa S. Gouda et al.

Summary: Activated carbons derived from willow catkin were successfully synthesized using a chemical activation technique. Nickel oxide-activated carbon nanocomposites and cobalt oxide-activated carbon nanocomposites were prepared by calcining metal oxide nanoparticles on the activated carbon surface. The 25NiO@Co3O4-AC and 25Co3O4@NiO-AC nanocomposite electrodes exhibited the highest specific capacitances due to the good dispersion of nickel oxide and cobalt oxide.

JOURNAL OF ENERGY STORAGE (2023)

Article Energy & Fuels

Flexible Ti3C2Tx MXene/V2O5 composite films for high-performance all-solid supercapacitors

Wenlong Luo et al.

Summary: A flexible electrode material, Ti3C2Tx MXene/V2O5 film, was prepared by vacuum-assisted filtration of a mixture of MXene nanosheets and V2O5 nanofibers, which effectively suppresses the self-stacking phenomenon of MXene nanosheets and regulates the thickness of the film. The resulting electrode showed good capacitive performance, cycling stability, and flexibility, indicating its potential for application in wearable energy storage devices.

JOURNAL OF ENERGY STORAGE (2023)

Article Materials Science, Multidisciplinary

Fabrication of manganese oxides/carbon composites for high energy density asymmetric supercapacitor

Zhiwei Tian et al.

Summary: The low conductivity of metal oxide electrode and the low specific capacitance of carbon electrode are the major limitations for the commercial application of supercapacitors. In this study, manganese oxides/carbon composites were prepared using homemade porous carbon and KMnO4, which showed both high capacitance of metal oxides and high conductivity of carbon due to Mn-O-C interaction. The optimized composite electrode exhibited an incredible ultra-high specific capacitance and the assembled asymmetric supercapacitor device achieved an astonishing energy density and maintained high capacitance after 10,000 cycles. This material is expected to be a promising candidate for large-scale commercial applications due to its simple preparation methods and excellent performance.

DIAMOND AND RELATED MATERIALS (2023)

Article Electrochemistry

Direct growth of TiO2-MoO2/MnO2-MoO2 on plasma-treated carbon-cloth surface for high-performance supercapacitor and oxygen evolution reaction

Ramkumar Vanaraj et al.

Summary: This study focuses on the modification of carbon cloth surface and the functionalization of TiO2-MoO2/MnO2-MoO2 for high-performance symmetric supercapacitors and the oxygen evolution reaction (OER). Oxygen plasma treatment was used to activate the carbon cloth, and TiO2-MoO2/MnO2-MoO2 materials were directly functionalized onto the carbon cloth surface to obtain the target materials (CC-TiO2-MoO2 and CC-MnO2-MoO2). The functionalization of TiO2-MoO2/MnO2-MoO2 on carbon cloth was confirmed by various spectroscopy techniques, and the surface morphologies of the materials were studied using microscopy. The bimetallic oxide materials were strongly attached to the surface of the activated carbon cloth and exhibited stable charge-transfer properties.

ELECTROCHIMICA ACTA (2023)

Article Electrochemistry

Delaminated N-Ti3C2@Ni3S4 nanocomposites based high-performing supercapacitor device fabrication

Iffat Ashraf et al.

Summary: In this study, a supercapacitor based on N-Ti3C2@Ni3S4 nanocomposites was prepared, which showed high specific capacitance and cyclic stability. The phase development and surface morphology of the materials were systematically investigated using a range of characterization techniques. The electrochemical results demonstrated that the N-Ti3C2@Ni3S4 nanocomposite exhibited high specific capacitance and cyclic stability. Moreover, the symmetric supercapacitor device of N-Ti3C2@Ni3S4 nanocomposite showed excellent energy density and power density.

ELECTROCHIMICA ACTA (2023)

Article Chemistry, Physical

Composite cathode with low-defect NiFe Prussian blue analogue on reduced graphene oxide for aqueous sodium-ion hybrid supercapacitors

Tianyu Miao et al.

Summary: Researchers have developed a novel binder-free composite cathode material consisting of highly crystallized NiFe Prussian blue analogue nanocubes grown on reduced graphene oxide. The composite electrode exhibits high specific capacitance, remarkable rate performance, and satisfactory cycling stability in aqueous Na2SO4 electrolyte. This work provides a new approach for the scalable fabrication of binder-free PBA cathode materials.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Review Energy & Fuels

Advancements in MXene-polymer composites for high-performance supercapacitor applications

Muhammad Amirul Aizat Mohd Abdah et al.

Summary: State-of-the-art supercapacitors based on MXene and polymer composites offer an innovative approach to enhance electrochemical performance. MXene, a 2D material, exhibits exceptional electrochemical attributes and metallic conductivity. However, the restacking nature of MXene layers limits electrolyte penetration and ion adsorption/desorption. This review discusses the harnessing techniques and properties of MXene and polymer-based composites, as well as their applications in supercapacitors.

JOURNAL OF ENERGY STORAGE (2023)

Article Energy & Fuels

Highly flexible, foldable carbon cloth/MXene/polyaniline/CoNi layered double hydroxide electrode for high-performance all solid-state supercapacitors

Zhongtai Lin et al.

Summary: Layered double hydroxide (LDH) is a promising electrode material due to its high specific area, good cycle stability, and high power density. However, its application in energy storage is limited by large internal resistance. To solve this problem, carbon cloth/MXene/PANI/CoNi-LDH (CC/MXPACN) composites are fabricated by electrodeposition, and their electrochemical performances are investigated. The assembled asymmetric supercapacitor exhibits high specific capacitance, long-term stability, and good power density and energy density, showing great potential in energy storage applications.

JOURNAL OF ENERGY STORAGE (2023)

Review Energy & Fuels

MXene-Based Electrodes for Supercapacitor Energy Storage

Yucheng Chen et al.

Summary: MXenes, a new class of two-dimensional advanced functional nanomaterials, show promising potential as high-performance electrodes for electrochemical capacitors. This paper critically reviews the recent advancements in utilizing MXenes in supercapacitor electrodes, including their unique structural features, fabrication strategies, performance improvement, and the challenges and opportunities in this rapidly emerging area.

ENERGY & FUELS (2022)

Article Materials Science, Multidisciplinary

Scalable fabrication of NiCo2O4/reduced graphene oxide composites by ultrasonic spray as binder-free electrodes for supercapacitors with ultralong lifetime

Zhongting Shi et al.

Summary: Large area NiCo2O4/rGO composites with hierarchical structure were fabricated and used as binder-free electrodes for supercapacitors, showing high specific capacitance, good rate performance, and remarkable cycling stability. The assembled ASC achieved high energy density at high power density and ultralong cycling life, indicating great potential for advanced supercapacitors.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

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Self-Supporting, Binder-Free, and Flexible Ti3C2TX MXene-Based Supercapacitor Electrode with Improved Electrochemical Performance

Rui Ma et al.

Summary: By optimizing the integration approach and modifying the surface chemistry of MXene, high-performance supercapacitor electrodes with enhanced capacitance, rate capability, cyclic stability, and mechanical flexibility are achieved.

ACS NANO (2022)

Review Physics, Applied

Renewable waste biomass-derived carbon materials for energy storage

Yuancheng Huang et al.

Summary: Developing high-performance electrode materials is crucial for energy storage systems. Biomass-derived carbons demonstrate great potential due to their rich structure, low cost, abundance in reserves, and excellent electrochemical performance. This review provides a systematic classification of waste biomass and discusses the microstructures of their derived carbons. It analyzes the effects of biomass-derived carbons' structure, porosity, interlayer spacing, and heteroatomic doping on different energy storage devices as electrode materials. Furthermore, it summarizes the challenges, solutions, and developing trends in biomass-derived carbons.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2022)

Article Chemistry, Multidisciplinary

Self-Assembly of Hausmannite Mn3O4 Triangular Structures on Cocosin Protein Scaffolds for High Energy Density Symmetric Supercapacitor Application

Johnbosco Yesuraj et al.

Summary: Recent advances have shown that using biological scaffolds for nanoparticle synthesis is useful in preparing nanostructures with uniform shape and size. The cocosin protein, derived from coconut fruit, has been studied as a scaffold for synthesizing Mn3O4 materials. The protein has been found to interact with manganese ions, resulting in a hexamer structure for the Mn3O4 material. Additionally, the cocosin-Mn3O4 material exhibits high specific capacitance and cyclic stability in electrochemical supercapacitors, making it a promising electrode for energy storage applications.

LANGMUIR (2022)

Article Materials Science, Multidisciplinary

Three-dimensional hierarchically porous nitrogen-doped carbon from water hyacinth as selenium host for high-performance lithium-selenium batteries

Wei-Na Deng et al.

Summary: In this study, a hierarchically porous nitrogen-doped carbon material was developed as a scaffold for selenium in lithium-selenium batteries, leading to significant improvement in performance.

RARE METALS (2022)

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Vertical Arrangement of Ti2CTX MXene Nanosheets on Carbon Fibers for High-Performance and Flexible Zn-Ion Supercapacitors

Bao Shi et al.

Summary: In this study, Ti2CTx MXene nanosheets were vertically grown on carbon fiber substrates by a molten salt method assisted by a selective etching process. This approach overcomes the limitations of MXene electrodes at high charge-discharge rates and achieves high areal capacitance and excellent stability.

ACS APPLIED NANO MATERIALS (2022)

Article Chemistry, Multidisciplinary

Organic Crosslinked Polymer-Derived N/O-Doped Porous Carbons for High-Performance Supercapacitor

Jianhao Lao et al.

Summary: Supercapacitors, as a new type of electrical energy storage device, can provide a potential solution to environmental problems caused by economic development and excessive use of fossil energy resources. In this study, nitrogen/oxygen-doped porous carbon materials were fabricated through the calcination and activation of an organic crosslinked polymer, resulting in a high-performance electrode material with excellent electrochemical performance and energy storage potential.

NANOMATERIALS (2022)

Article Energy & Fuels

NiZnCoO4/CoWO4 hybrid composite with improved electrochemical performance for supercapacitor application

Rana R. Neiber et al.

Summary: In this study, we propose an in-situ approach to couple Ni-Zn-Co trimetallic oxides with CoWO4 to construct an efficient hybrid composite electrode. Compared to its pristine counterparts, this hybrid electrode exhibits superior electrochemical characteristics, thanks to the synergy of multi-atom conductivity, surface area, and redox-active sites.

JOURNAL OF ENERGY STORAGE (2022)

Article Energy & Fuels

A reign of bio-mass derived carbon with the synergy of energy storage and biomedical applications

Rajkumar Palanisamy et al.

Summary: The use of carbon based electrodes with high specific surface area and suitable pore size distribution greatly enhances the energy and power density of energy storage devices. This study focuses on the development of ecofriendly and low-cost carbon material containing fluorine (F) atoms from Ipomoea carnea flower biomass for applications in lithium-sulfur batteries, supercapacitors, and biomedical fields. The carbon material shows promising results as an electrode material for lithium-sulfur batteries, effectively tackling the capacity fading issue due to the insulating nature of sulfur electrodes. It also demonstrates excellent electrochemical performance and high coulombic efficiency. Additionally, the carbon material exhibits outstanding specific capacitance when used as electrode material for supercapacitors. The cytotoxicity of the carbon material is also analyzed and shows potential for biomedical applications.

JOURNAL OF ENERGY STORAGE (2022)

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Na+ pre-intercalated Na0.11MnO2 on three-dimensional graphene as cathode for aqueous zinc ion hybrid supercapacitor with high energy density

Hao Ren et al.

Summary: This study presents the growth of sodium pre-intercalated delta-MnO2 nanoflakes on three-dimensional graphene using a simple electrodeposition method. The electrode exhibits excellent specific capacitance and cycling stability, thanks to the high-crystallinity graphene and sodium pre-intercalation. The assembled zinc ion hybrid supercapacitor device demonstrates superb energy density, power density, and cycling lifespan.

CARBON (2022)

Article Chemistry, Multidisciplinary

Preparation of N,P Co-doped Porous Carbon Derived from Daylily for Supercapacitor Applications

Tianxiang Jin et al.

Summary: A daylily-derived porous carbon material with high specific surface area and heteroatom content has been successfully prepared by a simple carbonization method. It shows remarkable specific capacitance and excellent cycling stability, making it suitable for high-performance supercapacitors.

ACS OMEGA (2022)

Article Engineering, Electrical & Electronic

CoFe2O4 Nanoparticle Decorated Hierarchical Biomass Derived Porous Carbon Based Nanocomposites for High-Performance All-Solid-State Flexible Asymmetric Supercapacitor Devices

Debika Gogoi et al.

Summary: In this study, a high-performance all-solid-state flexible supercapacitor device was constructed using coconut fiber-derived porous carbon as the anode and a nanocomposite composed of CoFe2O4 nanoparticles immobilized within the pores of porous carbon as the cathode. The device exhibited high energy density, good cycle life, and retained its performance even after physical deformation, demonstrating its potential for green energy-based electrochemical energy storage applications.

ACS APPLIED ELECTRONIC MATERIALS (2022)

Article Materials Science, Paper & Wood

Sandwich-like chitosan porous carbon Spheres/MXene composite with high specific capacitance and rate performance for supercapacitors

Lansheng Wei et al.

Summary: This study combines Ti3C2Tx MXene nanosheets with porous carbon microspheres to construct a sandwich-like structure, which exhibits high specific capacitance and good cycling stability in supercapacitors.

JOURNAL OF BIORESOURCES AND BIOPRODUCTS (2022)

Article Chemistry, Physical

V2O5/vertically-aligned carbon nanotubes as negative electrode for asymmetric supercapacitor in neutral aqueous electrolyte

Gan Sun et al.

Summary: A composite electrode with a unique three-dimensional hierarchical nanostructure of V2O5/VACNTs was successfully prepared and applied in aqueous ASCs, showing ideal specific capacitance and outstanding cycling stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Review Chemistry, Multidisciplinary

Recent Advances of Asymmetric Supercapacitors

Nannan Wu et al.

Summary: This article introduces the structure and material compositions of asymmetric supercapacitors, which are classified into two types: electric double-layer capacitor//pseudocapacitive-type and electric double-layer capacitor//battery-type hybrid, using carbon materials and different metal oxides/hydroxides as anodes and cathodes. Recent advances show that Li-ion-based ASCs have great potential, and the challenges and prospects for the development of ASCs are pointed out.

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Yeasts-derived nitrogen-doped porous carbon microcapsule prepared by silica-confined activation for supercapacitor

Juan Du et al.

Summary: A nitrogen-doped porous carbon microcapsule was successfully prepared using a silica-confined activation strategy with yeasts as a renewable biomass carbon precursor. This material exhibited a high specific surface area and abundant pores due to the limited space provided by the silica shell, leading to improved electrochemical performance in supercapacitor applications compared to direct pyrolysis products from yeasts.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Sustainable Carbon Materials toward Emerging Applications

Guojun Lan et al.

Summary: The production and utilization of renewable materials should aim to be carbon neutral for a sustainable society. Sustainable carbon materials, which have applications in CO2 utilization, renewable energy storage, and biomedicine, are gaining attention, but face challenges in energy consumption and environmental pollution during preparation. Developing low-cost, scalable, and environmentally friendly methods for producing sustainable carbon materials, particularly using biomass as a precursor, is crucial for advancement in this field.

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Skirmante Tutliene et al.

Summary: Aqueous Na-ion batteries show promise for stationary energy storage, with research focusing on novel electrode materials. The NASICON-structured NaTi2(PO4)(3) phosphate framework is a widely studied negative electrode material. The preparation of active material and carbon composite properties are crucial in determining the performance of the electrochemical system.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

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Unlocking the Potential of Oxygen-Deficient Copper-Doped Co3O4 Nanocrystals Confined in Carbon as an Advanced Electrode for Flexible Solid-State Supercapacitors

Shude Liu et al.

Summary: Incorporating Cu dopants and O vacancies into Co3O4 nanocrystals confined in a carbon matrix, termed as O-v-Cu-Co3O4@C, helps improve the specific capacity and rate performance of the material. The heterostructured architecture with multifunctional nanogeometries enables high intercomponent synergy, leading to enhanced electrical conductivity and enriched redox chemistry, ultimately resulting in a significantly improved energy density of 64.1 W h kg(-1) at 800 W kg(-1) for asymmetric supercapacitors.

ACS ENERGY LETTERS (2021)

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A facile approach of micro-mesopores structure binder-free coin/monolith solid design activated carbon for electrode supercapacitor

Apriwandi Apriwandi et al.

Summary: This research successfully converted banana leaves biomass into porous carbon without using complicated techniques, such as hard/salt-templates or heteroatoms-doping. The obtained activated carbon exhibited a 3D porous structure with enhanced specific surface area and mesoporosity, leading to the production of high-capacity symmetric supercapacitors. This study provided a feasible approach to obtain hierarchical activated porous carbon as an electrode material for energy storage devices.

JOURNAL OF ENERGY STORAGE (2021)

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Boron-Doped Trimetallic Cu-Ni-Co Oxide Nanoneedles for Supercapacitor Application

Iftikhar Hussain et al.

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MATERIALS ADVANCES (2020)

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JOURNAL OF MATERIALS CHEMISTRY A (2020)

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APL MATERIALS (2019)

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ACCOUNTS OF CHEMICAL RESEARCH (2019)

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JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

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INORGANIC CHEMISTRY FRONTIERS (2017)

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Shuanghao Zheng et al.

ENERGY STORAGE MATERIALS (2017)

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Timur Islamoglu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

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ACCOUNTS OF CHEMICAL RESEARCH (2016)

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Akshay Jain et al.

CHEMICAL ENGINEERING JOURNAL (2016)

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Jing Tang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Hojin Choi et al.

NANOMATERIALS (2015)

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Carbons and Electrolytes for Advanced Supercapacitors

Francois Beguin et al.

ADVANCED MATERIALS (2014)

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Insertion-Type Electrodes for Nonaqueous Li-Ion Capacitors

Vanchiappan Aravindan et al.

CHEMICAL REVIEWS (2014)

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Debasis Ghosh et al.

DALTON TRANSACTIONS (2014)

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Xiao-Yan Zhao et al.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2014)

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Recent advances in porous graphene materials for supercapacitor applications

Xiong Zhang et al.

RSC ADVANCES (2014)

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JOURNAL OF MATERIALS CHEMISTRY A (2014)

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MATERIALS TODAY (2013)

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ELECTROCHIMICA ACTA (2011)

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CHEMISTRY OF MATERIALS (2010)

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ENERGY & ENVIRONMENTAL SCIENCE (2010)

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Michio Inagaki et al.

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JOURNAL OF POWER SOURCES (2007)

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