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Review
Materials Science, Multidisciplinary
Yongteng Qian et al.
Summary: Metal-organic framework-based compounds have unique properties such as a porous structure, ordered porosity, and high specific surface area, making them promising candidates for environmental governance and remediation. This review summarizes the different types of metal-organic framework-based compounds and discusses their various applications in environmental processes including pollutant removal, gas capture, ion detection, gas separation, water harvesting, air purification, and carbon dioxide reduction reactions. The opportunities and challenges for the future development of metal-organic framework-based compounds in environmental applications are also highlighted.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Analytical
Yongteng Qian et al.
Summary: In this study, flower-shaped MoS2/graphene heterostructures were used as electrode materials on flexible substrates to overcome the limitations of low energy density and poor durability of MoS2. The results showed exceptional capacitance of 853 F g(-1) at 1.0 A g(-1) in three-electrode measurements, and 208 F g(-1) at 0.5 A g(-1) with long-term cyclic durability in asymmetric supercapacitor measurements. Nearly 86.5% of the electrochemical capacitance was retained after 10,000 cycles at 0.5 A g(-1). Moreover, a remarkable energy density of 65 Wh kg(-1) at a power density of 0.33 kW kg(-1) was obtained. The MoS2/Gr heterostructure composites have great potential for the development of advanced energy storage devices.
Review
Chemistry, Physical
Yongteng Qian et al.
Summary: Recently, metal-organic framework (MOF)-derived composites have shown promise for energy conversion systems due to their tunable pore size, large surface area, and high catalytic performance. This review summarizes the different synthesis approaches for MOF-derived composites and highlights recent advances in their use for various energy conversion applications. The challenges and future development prospects for MOF-derived composites in the field of energy conversion systems are also discussed.
Article
Chemistry, Physical
Yongteng Qian et al.
Summary: Phase engineering was employed to prepare high-performance phosphorous-doped biphase MoS2 nanoflakes for hydrogen evolution reaction. The doping of MoS2 with P atoms modifies its electronic structure and optimizes its electrocatalytic reaction kinetics, significantly enhancing its electrical conductivity and structural stability. The hierarchically formed flakes of P-BMS provide numerous catalytic surface-active sites, remarkably enhancing its HER activity.
Review
Nanoscience & Nanotechnology
Jian-Xin Wang et al.
Summary: This review focuses on the recent advances in energy transfer luminescent metal-organic framework (ET-LMOF) based sensing materials, with an emphasis on photochemical and photophysical mechanisms. The discussion includes possible energy transfer processes within MOF structures or between MOFs and guest materials. The potential sensing applications of ET-LMOF based sensors are highlighted.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Ji Yong Choi et al.
Summary: By transforming 2D conjugated MOFs into 3D frameworks via postsynthetic pillar-ligand insertion, increased ion accessibility and improved gravimetric capacitance were achieved.
Article
Chemistry, Multidisciplinary
Deren Yang et al.
Summary: This paper reports a simple method for preparing monolayer and bilayer 2D porphyrin-based metal-organic frameworks (MOFs), and finds that the structural transition between monolayer and bilayer leads to different electrocatalytic pathways and affects product selectivity.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Chaonan Zhang et al.
Summary: Energy depletion and environmental pollution are serious challenges for humans. The application of hydrogen energy is a promising strategy to address these issues. However, hydrogen production is a drawback for hydrogen energy. The hydrogen evolution reaction (HER) based on electrocatalysis is an effective way to enhance hydrogen generation with low energy consumption. Many efforts have been made to develop high-performance catalysts for HER processes.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Chemistry, Physical
Muhammad Zubair et al.
Summary: MXenes are a family of 2D transition metal carbides, nitrides, and carbonitrides that exhibit promising electrocatalytic properties for water electrolysis. MXenes can act as efficient electrocatalysts for both HER and OER due to their metallic nature and surface properties.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Analytical
Junping Ma et al.
Summary: Integrating other metal ions into mono-metallic metal-organic frameworks (MOFs) to form bi-metallic MOFs can enhance the performance of MOFs. In this study, Co/Zn-TCPP MOF nanomaterials with different Co/Zn molar ratios were synthesized, and the sensors based on these materials showed catalytic performance to dopamine (DA). The doping of metal ions improves the chemical environment of the pores and increases the types and spatial arrangement of the active sites of the MOF, resulting in improved catalytic activity. The sensor based on Co25Zn75-TCPP exhibited good selectivity and a low detection limit for DA.
Article
Chemistry, Multidisciplinary
Jingting Zhu et al.
Summary: The solar-irradiation strategy is used to prepare hybrid SA-Pt/MoS2 nanosheets with excellent HER activity. Downsizing Pt nanoparticles to single atoms can decrease cost and increase atomic utilization, showing potential for mass production. Theoretical simulations show that Pt improves H atom absorption and charge-transfer kinetics of MoS2, significantly enhancing HER activity.
Article
Chemistry, Multidisciplinary
Haiyan An et al.
Summary: This study successfully constructs a 2D heterostructure named CeO2@NiFe-MOFs, which greatly improves catalytic performance and stability by increasing contact surface and charge transfer. CeO2 plays a significant role in anchoring carboxylic acid groups and enhancing the binding strength of the heterostructures. The heterostructure exhibits good structural stability and significantly enhances the oxygen evolution reaction (OER) efficiencies compared to bare NiFe-MOFs.
Article
Chemistry, Physical
Tongwei Wu et al.
Summary: This study unveils the mechanism, thermodynamics, and kinetics determining the HER/NRR efficiency on the state-of-the-art NRR electrocatalyst, Ru-N-4. The results show that NRR intermediates suppress HER through coadsorption on the catalyst, and the selectivity is determined by the initial step forming *NNH or *H. This provides crucial insights into the complex NRR/HER competition and suggests ways to improve NRR selectivity.
Review
Chemistry, Applied
Feng Zeng et al.
Summary: This review summarizes the recent progress in the stability and deactivation mechanisms of OER catalysts. The correlation between OER activity and stability, methodologies and experimental techniques for studying stability and deactivation, as well as factors influencing stability are discussed. Strategies for stabilizing and regenerating OER catalysts, as well as methods for predicting stability, are also summarized. Furthermore, the review highlights emerging methodologies yet to be explored and future directions for stability studies and the design of highly stable OER catalysts.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Physical
Yongteng Qian et al.
Summary: Interfacial microenvironment modulation has been proven to be an effective strategy to optimize catalytic kinetics, as demonstrated in the synthesis of lattice defect-rich NiS2/MoS2 nanoflakes for water splitting electrocatalysis. The optimized NiS2/MoS2 nanoflakes exhibited remarkable catalytic activity with lower voltage requirements compared to noble-metal-based electrocatalysts, showcasing both high efficiency and long-term stability for overall water splitting.
Review
Chemistry, Physical
Min Kyung Lee et al.
Summary: This review discusses the potential of MOFs and COFs for developing efficient electrocatalysts, focusing on 2D materials with unique properties like large surface area and enhanced electrical conductivity. It also highlights the synthesis methods, advantages, recent advances, and challenges in utilizing 2D materials for various electrocatalytic reactions.
ADVANCED ENERGY MATERIALS
(2022)
Review
Chemistry, Physical
Yong-Sheng Wei et al.
Summary: Metal-organic frameworks (MOFs) are crystalline porous materials constructed by organic linkers and metal ions/clusters, with high surface area and functional adjustability, leading to versatile applications. This review focuses on the design and synthesis of 1D, 2D, and 3D MOF nanostructures and their derivatives, discussing promising catalytic applications and energy storage, outlining the challenges and future prospects for this emerging field.
ADVANCED ENERGY MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Zhong-Yin Zhao et al.
Summary: This study developed a unique strategy to enhance the OER activity of Ni-based MOFs by the incorporation of Fe3+ ions and BF4- anions. The optimized NiFe-MOF-BF4-0.3 nanosheets exhibit superior OER activity and stability. Experimental and theoretical results demonstrate that the interactions between metal ions and BF4- anions play a crucial role in boosting the OER activity.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Nanoscience & Nanotechnology
Sara Rojas et al.
Summary: Agrochemicals are essential for meeting global food demand, but their widespread use presents challenges like contamination and pest resistance. Developing new materials for their application, detection, and removal is crucial.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Nanoscience & Nanotechnology
Nathan B. Jones et al.
Summary: There is a strong demand for materials that can safely and reversibly store the toxic and highly reactive diborane gas at room temperature. This study investigates the interfacial chemistry of diborane storage in the UiO-66-NH2 metal-organic framework (MOF) and reveals a promising pathway for stable and long-term storage of diborane.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Songsong Li et al.
Summary: This study reports the synthesis of high efficiency electrocatalysts based on S-doped NiFeP and improves the reaction performance by tuning the electronic structure. The research provides a new strategy for designing highly active non-noble metal catalysts.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zongsu Han et al.
Summary: This study develops a general strategy to introduce chirality into metal-organic frameworks and constructs IRMOF-74 analogs with different pore sizes. To enhance detection accuracy, a second luminescent center is introduced for ratiometric sensing. The compounds exhibit pore-size-dependent sensing performance, revealing the importance of pores in MOF-based luminescent sensors.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Zizheng Zhu et al.
Summary: Researchers have reported a Co-VOx-P nanoflower electrocatalyst with excellent catalytic performance for water splitting. Experimental and theoretical studies suggest that the catalyst has enhanced conductivity, facile electron transfer, and favorable surface adsorption strength.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Physical
Song Lu et al.
Summary: This study focuses on investigating the OER/ORR activities of 3d transition metal atoms embedded MoSi2N4, with Ti and Cr showing the best performance as OER and ORR catalysts, while different sites of Cu and Zn also exhibit good electrocatalytic properties in the system.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Environmental
Yihui Wang et al.
Summary: The research on active and efficient electrocatalysts is crucial for the practical application of energy conversion devices. In this study, porous rhodium octahedra were synthesized through a one-pot method called corner-induced-selective-deposition (CISD), and their performances in alkaline media for oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR) were significantly enhanced by interfacial boron modification. The incorporation of boron improved the adsorption properties of the catalyst surface and reduced the overpotentials for the three reactions. This work has the potential to guide the design of other nanoscale functional materials with delicate nanostructures and optimized compositions.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Crystallography
Shengnan Lin et al.
Summary: It is well known that a layered structure is favorable for charge transfer and catalytic materials. In this study, CeO2, Fe3O4, and Fe2O3 nanomaterials with a hierarchical structure were prepared by cationic membrane electrolytic synthesis, and their composition and microstructure were analyzed using XRD, FTIR, XPS, and SEM. Finally, the electrochemical hydrogen evolution performance of the samples was tested.
CRYSTAL RESEARCH AND TECHNOLOGY
(2022)
Article
Thermodynamics
Wenjia Li et al.
Summary: This study presents a photovoltaics and methane-steam-reforming hybrid system that efficiently and carbon-neutrally generates electricity and hydrogen from solar energy and fossil fuels. The system achieves high solar-to-product energy efficiency through comprehensive utilization of different wavelengths of sunlight. The interconversion between hydrogen and electricity enables flexible supply based on demand.
ENERGY CONVERSION AND MANAGEMENT
(2022)
Review
Pharmacology & Pharmacy
Congying Rao et al.
Summary: This review aims to summarize recent advances in the development of MOFs for drug delivery, in particular, focusing on its ability to deliver various drugs and their release mechanism, as well as the in vivo and in vitro biological evaluation. Moreover, the future research directions of MOFs for clinical treatment are also outlined.
EXPERT OPINION ON DRUG DELIVERY
(2022)
Article
Chemistry, Applied
Jun Cheng et al.
Summary: In this study, a novel Ni3S2@2D Co MOF catalyst was synthesized and exhibited excellent hydrogen evolution reaction (HER) activity in alkaline water electrolysis. The catalyst showed better HER performance than commercial Pt/C catalyst and demonstrated good stability. This can be attributed to the honeycomb structure formed by nickel sulfide nanosheets, which facilitated charge transfer and hydrogen evolution.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Chemistry, Physical
Sankar Sekar et al.
Summary: In this study, reduced graphene oxide decorated-cobalt disulfide (rGO-CoS2) nanocomposites were synthesized via a one-step hydrothermal method. The nanocomposites exhibited excellent hydrogen evolution reaction (HER) activities with low overpotential and small Tafel slope, providing a promising scheme for developing efficient rGO-CoS2 electrocatalysts in future green energy technology.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Chemistry, Physical
Hui Xu et al.
Summary: This review comprehensively summarizes the recent advances of noble metal single-atom catalysts (NMSACs) in water splitting applications. By modifying the structure and local coordination environment, NMSACs can significantly enhance the electrochemical performance of water splitting and offer guidance for the development of more advanced NMSACs in the future.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Xin Yang et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Inorganic & Nuclear
Jingfang Tian et al.
Summary: A new 2D structured Ni-MOF (CUST-516) was synthesized and physically post-decorated to obtain Ni/Ni3S2@CN electrocatalyst, which showed excellent HER activity and long-term stability. The synergistic effect of multi-components and the unique pore structure derived from precursor MOF contribute to the enhanced electrocatalytic performance.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Daqi Song et al.
Summary: In this study, two-dimensional NiFe-MOF nanosheets with highly efficient oxygen evolution reaction (OER) performance were successfully synthesized using a simple approach. The use of carboxylated carbon quantum dots (CQDs-COOH) as an inducing agent enlarged the layer spacing of NiFe-MOF and increased the positive charge on the active sites, leading to improved OER performance. The nanosheets also exhibited good stability. The results demonstrate the potential application of this method in energy conversion and storage devices.
Article
Chemistry, Multidisciplinary
Parag Tamuly et al.
Summary: A layered metal-organic framework (MOF), Cd-BPDP, was synthesized using a metal-assisted self-assembly method. The MOF was then exfoliated into porous 2D metal-organic nanosheets (MONs) through ultrasonication and mechanical grinding techniques. The resulting MONs showed significant iodine capture ability, attributed to the increased surface area, charge-transfer complex formation, and reinforced binding of iodine through charge transfer.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Chunxiang Liu et al.
Summary: This study reports on a method for preparing high efficiency hydrogen evolution reaction catalyst using a thermal healing process. The Ir single-atom catalyst prepared with this method exhibits higher electrocatalytic activity and stability compared to commercial Pt/C and Ir/C catalysts, showing potential for industrial applications.
Editorial Material
Chemistry, Multidisciplinary
Omar M. Yaghi
Summary: Understanding the mechanism of MOF crystal growth is crucial for their design. In this study, Deng and colleagues employ an optical method to visualize and track the crystal interface during MOF growth. They also derive a reaction kinetic equation for individual crystals of MOFs, which offers valuable guidance for MOF synthesis.
Article
Chemistry, Physical
Md Ahasan Habib et al.
Summary: A boron-based ternary W3CoB3 electrode is designed for water splitting electrocatalysis, demonstrating low overpotentials and excellent performance. The incorporation of boron atoms promotes electron supply and enhances electrocatalytic performance.
MATERIALS TODAY ENERGY
(2022)
Article
Green & Sustainable Science & Technology
Jordan Martinez et al.
Summary: This study presents the synthesis of supported Fe-doped Pd nanoparticles for electrocatalytic water splitting. The bimetallic PdFe-NPs show superior activity and stability, attributed to the synergetic effect of Fe-Pd interactions and the protecting role of the MOF organic linker.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Chemistry, Multidisciplinary
G. Yasin et al.
Summary: A facile tempted-defects assisted fractionation strategy was presented to synthesize N, S, and O tri-doped metal-free catalyst (DETDAP), which exhibits excellent bifunctional catalytic activity with low overpotential towards both the OER and HER. The tailored defects in tri-doped interlinking were found to enhance the bifunctional catalytic performance, providing a perceptive understanding of the synergetic principles of heteroatom-interlinking-tailoring nanostructures in water splitting.
MATERIALS TODAY CHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
K. Chhetri et al.
Summary: An efficient and stable electrocatalyst for overall water splitting in alkaline media was successfully prepared using a rational design of two-dimensional metal-organic framework (MOF)-derived mesoporous structures. The catalyst exhibited enhanced electrocatalytic activity towards the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) due to abundant heterointerfaces, mesoporous nanostructures, and multimetallic active centers. This work opens up new possibilities for exploring MOF-based catalysts for overall water splitting applications.
MATERIALS TODAY NANO
(2022)
Article
Chemistry, Physical
Lunhong Ai et al.
Summary: This study presents the construction of phosphate-incorporated iron oxide nanosheet arrays as multifunctional photothermal-electrocatalytic electrodes, which exhibit excellent performance in hydrogen evolution reaction and oxygen evolution reaction under near-infrared light irradiation. The in-situ surface self-heating induced by photothermal conversion significantly improves the electrocatalytic performances with relatively low overpotentials, demonstrating the potential of integrating photothermal effects in electrode materials for high-performance electrocatalysis.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Pharmacology & Pharmacy
Xiaolie He et al.
Summary: 2D nanomaterials have shown promising potential in the field of neural repair and regeneration. They possess unique physicochemical properties and biological activities, which make them suitable for synaptic modulation, neuroinflammatory reduction, stem cell fate regulation, and injured neural cell/tissue repair. Functional 2D nanomaterials offer a promising strategy for repairing and regenerating the injured nervous system.
ADVANCED DRUG DELIVERY REVIEWS
(2022)
Article
Chemistry, Physical
Ju-E Cun et al.
Summary: This article reviews the applications of copper-based metal-organic frameworks (Cu-MOFs) in the field of biomedicine and discusses their future development prospects. The article introduces the synthesis methods and strategies of Cu-MOFs and summarizes their recent advances in cancer treatment, bacterial inhibition, biosensing, biocatalysis, and wound healing.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2022)
Article
Engineering, Environmental
Hao Zhang et al.
Summary: This study reports a bottom-up method for preparing PtNPs-decorated 2D MOF nanosheets, which activates edge-doping engineering in MNPs. Due to the high surface area of ultrathin MOF nanosheets, PtNPs can be uniformly anchored, resulting in a high photocatalytic hydrogen production rate.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Keemin Park et al.
Summary: In this study, a 2D morphological NiFe MOF electrocatalyst co-doped with metalloid and non-metal elements was reported for enhanced OER performances. The synergistic effect of metalloid (Te) and halogen (Cl) doping improved OER kinetics, reducing overpotential and increasing long-term stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Hongwei Chang et al.
Summary: Large, single-layer two-dimensional metal-organic framework (MOF) nanosheets can be efficiently fabricated using supercritical CO2 in a pure aqueous system. The incorporation of SC CO2 not only facilitates the exfoliation of bulk MOF into nanosheets, but also enhances its stability in aqueous solution.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Physical
Mengmeng Liu et al.
Summary: This review discusses the important fabrication approaches of MoS2 ultrathin nanosheet to improve its intrinsic catalytic activity. Several modification strategies involve either morphology modulation or electron structural modulation to enhance charge transfer kinetics. The key challenges and future directions of developing high-performance MoS2-based electrocatalysts for overall water splitting are also discussed.
Review
Chemistry, Multidisciplinary
Linjuan Wang et al.
Summary: The development of advanced electronic devices is driving various aspects of modern technology and industry. This paper provides a detailed overview of the synthesis strategies of 2D metal organic frameworks (MOFs) that are gaining increasing attention, serving as a basis for expanding the use of novel key materials in electrical devices and integrated circuits. The synthesis methods of 2D MOFs are summarized and discussed in depth, along with the illustrations of promising applications in various electrical devices and integrated circuits.
Article
Chemistry, Multidisciplinary
Wen-Da Zhang et al.
Summary: In this study, open hollow 2D MOFs were successfully prepared and scaled up using a self-template method. The evolution from solid to hollow structures was tracked, and a series of open hollow MOFs with different sizes were synthesized. Furthermore, open hollow structured cobalt/N-doped porous carbon composites were realized through a conformal transformation process, showing potential applications in sustainable energy conversion technologies.
Article
Chemistry, Multidisciplinary
Yizhe Liu et al.
Summary: A novel LDHs-assisted approach is developed to synthesize freestanding bimetallic 2D metal-organic framework nanosheets (2D MOF NSs) with outstanding activities and proton transfer ability in the oxygen evolution reaction (OER).
Article
Chemistry, Physical
Mariya Pimpilova et al.
Summary: Hydroperoxides generated on lipid peroxidation are highly reactive compounds that indicate the deterioration of lipid samples. In this study, Co-doped graphitic carbon nitride 2D nanomaterials were examined as catalysts for the electrochemical reduction of water-soluble hydroperoxides. The composition of the electrode modifying phase, operating potential range, and linear dynamic range have been optimized, and the catalytic effect of the electrode has been proven to be higher than that of a polymer-covered electrode.
Article
Chemistry, Multidisciplinary
Graciela Villalpando et al.
Summary: In this study, a chemical exfoliation method was used to delaminate the layered antiferromagnet vanadium oxychloride, demonstrating the potential of chemical exfoliation and the effects of low dimensionality on magnetic properties.
Article
Chemistry, Physical
Zhixiao Gao et al.
Summary: The study found that metal-hexahydroxybenzene nanosheets M-3(C6O6) showed excellent performance in terms of structural stability, electronic properties, and ORR catalytic activity, especially for Cu-3(C6O6) and Rh-3(C6O6) which demonstrated promising catalytic effects in the oxygen reduction reaction.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Xuanbing Wang et al.
Summary: Surface-engineered porous and superhydrophilic heterostructure demonstrated superior electrocatalytic performance and stability for water splitting.
APPLIED SURFACE SCIENCE
(2022)
Review
Chemistry, Inorganic & Nuclear
Ling-Na Shi et al.
Summary: Water splitting is an important technique for green hydrogen production, but its efficiency is limited by the slow kinetics and high overpotentials of the hydrogen and oxygen evolution reactions. MXenes-based nanomaterials show promise as efficient electrocatalysts due to their unique properties, but their catalytic mechanism is not well understood. This review summarizes recent progress in the synthesis, physical properties, and performance improvement strategies of MXenes for electrocatalytic water splitting, and provides insights into the challenges and future research directions of MXenes in this application.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Physical
Jaya Verma et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Nannan Ma et al.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Shuke Li et al.
Summary: A trifunctional electrode material based on a two-dimensional cerium-based metal organic framework decorated with platinum nanoparticles has been developed, which effectively enhances electron transport efficiency and increases the number of electrochemically reactive sites. The material exhibits excellent performance in the hydrogen evolution reaction, oxygen evolution reaction, and supercapacitor reactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Yujie Song et al.
Summary: Two-dimensional (2D) layered metal-organic framework (MOF) nanoparticle (NP) superstructures were synthesized using an ice-templating strategy. The resulting carbon nanoparticle superstructures showed improved oxygen reduction activity compared to isolated carbon particles in alkaline media.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Energy & Fuels
Xiaomin Xu et al.
Summary: This article presents the application of high-entropy materials in water electrolysis, focusing on their role in catalyzing water-splitting reactions. The article summarizes various design strategies for high-entropy materials, including controlling size and shape, constructing porous structures, engineering defects, etc., to enhance catalytic performance. Additionally, it points out the challenges faced in the field and suggests future perspectives for development.
Article
Chemistry, Physical
Jiayi Tang et al.
Summary: This study demonstrates that versatile perovskite-based oxides can be developed into low-cost, highly active, and durable electrocatalysts for high current density water splitting, which is of great importance for large-scale hydrogen production.
Article
Chemistry, Physical
Tingting Liang et al.
Summary: This study investigated the effects of atom doping on the structural characteristics and hydrogen evolution reaction (HER) performance of black phosphorene (BP), a potential electrocatalyst material. The results showed that the doping of metal atoms, especially Fe, improved the electronic properties and significantly enhanced the HER performance. This research provides theoretical significance for the design of high-efficiency HER electrocatalysts.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Xiaofei Wei et al.
Summary: In this study, a series of 2D metal-organic frameworks were designed and investigated for their catalytic performance in oxygen reduction and evolution reactions. The CoN2O2 structure showed superior electrocatalytic activity, possibly due to its moderate adsorption interaction with key intermediates.
ACS MATERIALS LETTERS
(2022)
Review
Chemistry, Inorganic & Nuclear
Jinyi Chen et al.
Summary: Metal-organic frameworks (MOFs), including titanium-based MOFs (Ti-MOFs), have gained significant attention for their wide range of applications. However, the development of MOF materials for biological applications is still an emerging field. This study reviews the recent research progress on Ti-MOFs in therapeutic areas such as antibacterial, oncology, anti-inflammation, and bone injury, providing new directions for further research in the biomedical field.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Jie Song et al.
Summary: A facile approach to synthesize a Pt-doped metal-organic framework-derived layered double hydroxide with highly dispersed 2D nanosheets and excellent catalytic properties has been developed. This material shows low overpotentials and small Tafel slopes, making it a promising HER electrocatalyst in alkaline and neutral electrolytes.
CHEMICAL COMMUNICATIONS
(2022)
Review
Chemistry, Multidisciplinary
Abtin Ebadi Amooghin et al.
Summary: This article focuses on the application of fluorinated metal-organic frameworks (F-MOFs) in gas separation. By precisely designing and synthesizing new F-MOFs structures, specific gas separation purposes can be achieved. The basic principles, structure-performance relationships, and applications in adsorption and membrane gas separation are discussed. The importance of F-MOFs in gas separation and future challenges are highlighted.
CHEMICAL SOCIETY REVIEWS
(2022)
Article
Chemistry, Multidisciplinary
Tobias Binninger et al.
Summary: A computational study revealed that the classical oxygen evolution reaction (OER) mechanism on iridium dioxide (IrO2) surface should be reconsidered, as it follows a bi-nuclear mechanism rather than the commonly considered mono-nuclear mechanism. This new pathway allows the Ir-O bonds to remain stable, explaining the outstanding stability of IrO2 under OER conditions.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Licheng Huang et al.
Summary: This article reports a low-cost phosphated Zn-doped bimetallic skeleton that exhibits highly efficient electrocatalytic activity for water splitting. The catalyst achieves low overpotentials and good stability through heterogeneous atom doping and a self-supported electrode design.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Physical
Meiling Huo et al.
Summary: In this study, a heteroepitaxially grown 2D zeolitic imidazolate framework with a leaf-like morphology (ZIF-L) was successfully synthesized. It exhibited high surface area, abundant active sites, and improved conductivity. The derived material from the heteroepitaxially grown MOF, ultra-small Co nanoparticle immobilized nitrogen doped carbon (HM-Co@NC), showed superior oxygen reduction reaction (ORR) activity and stability, making it a promising candidate for rechargeable Zn-air batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Joshua Nicks et al.
Summary: Liquid exfoliation of layered MOFs to form MONs, followed by click reactions for post-exfoliation functionalization, allows for tuning of surface properties and enables various applications.
Article
Chemistry, Multidisciplinary
Ying-Xia Du et al.
Summary: In this study, a 2D bimetal Co-TCPP(Fe) metal-organic framework (MOF) was synthesized and transformed into a Fe-CoP/C composite with favorable oxygen evolution reaction (OER) performance. The Fe-CoP/C composite exhibited a low overpotential and improved OER performance, which can be attributed to Fe-doping in Co (oxy)hydroxide and the high electrochemical surface area induced by the 2D nanoplate morphology and conductive carbon network.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Guangtong Hai et al.
Summary: In this study, a factor was proposed for fast screening of 2D metal-organic frameworks (MOFs) as catalysts for the oxygen evolution reaction (OER). By using high-throughput density functional theory (DFT) calculations, it was found that when the Gibbs free energy change of the O-O bond formation is close to a specific value, the OER performance of the MOFs would reach its peak. Guided by this factor, the researchers successfully predicted and obtained high-performance Ni-based 2D MOFs.
Article
Chemistry, Physical
Peng Liu et al.
Summary: Defect-rich Fe-doped NiS/MoS2 ultrathin nanosheets were synthesized by manipulating lattice defects, which exhibited optimized adsorption energy and favorable electrochemical reaction kinetics, leading to enhanced activities for both hydrogen and oxygen evolution reactions. This material has the potential for practical applications.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Review
Chemistry, Inorganic & Nuclear
Yue Li et al.
Summary: This article reviews the development and applications of flexible metal-organic frameworks (MOFs) in gas storage and separation. It points out that flexible MOFs have controllable structural changes and breathing phenomena, which give them unique advantages in performance tuning.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Applied
Rui Huang et al.
Summary: This study presents a RuPbOx electrocatalyst for efficient and stable water oxidation in acid. The incorporation of Pb leads to the formation of superoxide precursors, which improves the kinetics of the oxygen evolution reaction.
CHINESE JOURNAL OF CATALYSIS
(2022)
Review
Chemistry, Applied
Jiaheng Peng et al.
Summary: The commercialization of proton exchange membrane fuel cells (PEMFCs) is significant for achieving a cleaner energy society. However, the sluggish reaction kinetics and harsh conditions of the oxygen reduction reaction affect the durability and cost of PEMFCs. Researchers have focused on studying the structural evolution of Pt-based electrocatalysts throughout their lifecycle to optimize their activity and durability.
CHINESE JOURNAL OF CATALYSIS
(2022)
Article
Engineering, Environmental
Huijie Wei et al.
Summary: In this study, a new strategy was proposed to synthesize lamellar redox-active iron-quinoid MOFs with excellent conductivity and magnetic properties for optimal microwave absorption performance. By modulating the morphology and crystallinity of MOF, adequate impedance matching was achieved through the simultaneous implementation of magnetic and electrical loss, opening up new opportunities to develop high-efficiency, lightweight, and tunable microwave absorbers.
CHEMICAL ENGINEERING JOURNAL
(2021)
Review
Chemistry, Multidisciplinary
Jingjuan Liu et al.
Summary: Two-dimensional conductive metal-organic frameworks (2D c-MOFs) have attracted extensive attention for their predictable structures, high electrical conductivity, and inherent permanent porosity, making them a promising platform for electrical devices. Recent research highlights the design strategies, unique electrical properties, and potential applications of 2D c-MOFs in electrochemical energy storage. Elucidating the structure-function correlations may guide the development of next-generation energy storage devices based on 2D c-MOFs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Qingcui Liu et al.
Summary: By optimizing the molar ratio of Ni to Co, a bimetal 2-methylimidazole based 2D-MOF with 5% Ni/Co molar ratio was synthesized, showing excellent activity and good stability in OER.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Editorial Material
Biochemical Research Methods
Sabine Szunerits
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Physical
Yu Lin et al.
Summary: This study successfully developed a Ru-doped NiFeP/NF electrocatalyst with excellent hydrogen evolution performance in acid, neutral, and alkaline media. The OER in alkaline media only requires an overpotential of 179 mV to achieve 10 mA.cm(-2).
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Hongbao Liu et al.
Summary: The study introduced a bifunctional CoNiP/NF catalyst with a hollow well-integrated nanostructure, which combines the advantages of 2D nanosheets and 3D microspheres to provide rich reaction active sites. This nanostructure demonstrated remarkable electrochemical performance and lower cell voltage for water electrolysis, suggesting potential for designing porous nano-catalysts for hydrogen economy.
APPLIED SURFACE SCIENCE
(2021)
Article
Engineering, Environmental
Hao Liu et al.
Summary: The study introduces a flexible and free-standing nano porous NiMnFeMo alloy with ultrahigh catalytic activity for both anode and cathode in electrochemical water splitting. The alloy exhibits excellent performance even at high current density and shows superior stability when used in a water electrolyzer. DFT calculations suggest that the catalyst's activity is attributed to the synergetic effect of solid solution elements.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Mengyi Han et al.
Summary: In this study, a new strategy was developed to grow ultrathin BMOFNs on NiCo-LDH, creating non-noble metal electrocatalysts that are both active and stable. The optimized NiCo-LDH@MOFs heterostructure exhibited superior electrocatalytic activity and enhanced durability, showcasing advanced AFM-IR technology to investigate the formation of 2D-2D heterogeneous structures in NiCo-LDH@MOFs. This work demonstrates an in-situ growth strategy for high-performance ultrathin MOF-based electrocatalysts and provides insights into the morphology-structure-composition evolution of the nanoscale electrocatalyst.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Cheng Chen et al.
Summary: 2D NiFe-MOF-74 nanosheets on nickel foam exhibit increased surface area, efficient utilization of active metal sites, and enhanced electrocatalytic activity through the collaboration of Ni and Fe metals, making them promising for water-splitting applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Acoustics
Noemi Contreras-Pereda et al.
Summary: The research on ultrasound-assisted delamination of 2D layered coordination polymer crystals led to stable nanosheet colloidal water suspensions, showing higher catalytic activities compared to their bulk counterparts. This highlights the potential of liquid phase exfoliation combined with suitable synthetic design of 2D coordination polymers to enhance functional properties and catalytic active sites.
ULTRASONICS SONOCHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Cong Zhang et al.
Summary: This study proposes a new strategy to enhance the alkaline hydrogen evolution reaction activity of bimetallic PtxNiy nanoalloys by inducing Pt surface segregation with the small gas molecule of H-2. The PtNi5-0.3 sample shows superior electrocatalytic performance with significantly low overpotential and steep Tafel slope compared to previously reported PtxNiy catalysts.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Leily Majidi et al.
Summary: A 2D copper-based conductive MOF, Cu-THQ, exhibits excellent catalytic activity for aqueous CO2 reduction reaction (CO2RR) with low overpotentials. The material shows high CO production rate and current density at low overpotentials, making it a promising candidate for practical applications in CO2RR.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Mengjun Wang et al.
Summary: A new liquid-liquid interfacial synthesis method was developed for the efficient fabrication of two-dimensional Ni metal-organic framework nanosheets, allowing for the modulation of active sites and achieving optimal electrocatalytic performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Kai Ge et al.
Summary: A facile synthesis method was reported for the preparation of two-dimensional bimetallic metal-organic frameworks with excellent electrocatalytic activity for the oxygen evolution reaction. Experimental and theoretical studies revealed that the morphology and co-doping of Fe/Co played crucial roles in enhancing the electrocatalytic performance of the material. The simple and efficient synthetic approach is promising for the mass production and future commercialization of functional two-dimensional MOFs with low cost and high yield.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Zhijie Chen et al.
Summary: The development of adsorbents with molecular precision is a promising strategy for enhancing the storage of hydrogen and methane, both considered key clean energy gases. In this study, a postsynthetic modification strategy on the robust metal-organic framework MFU-4l significantly improved its storage capacity for these gases, placing MFU-4l-Li among the best materials for this application.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Review
Chemistry, Inorganic & Nuclear
Sherif A. Younis et al.
Summary: Rare earth metal-organic frameworks (RE-MOFs) have attracted significant research interest for their unique properties in various biomedical applications. They show promise for drug delivery, imaging, and sensing fields, but still face challenges in design and utilization.
COORDINATION CHEMISTRY REVIEWS
(2021)
Editorial Material
Chemistry, Physical
Renhao Dong et al.
Summary: By linking pi-conjugated, electron-deficient ligands into atomically precise large single crystals of conducting 2D metal-organic frameworks, it is possible to determine the intrinsic electrical conductivity and charge transport mechanism.
Review
Nanoscience & Nanotechnology
Md Al Mahadi Hasan et al.
Summary: The development of a nation is closely linked to its energy consumption, and 2D nanomaterials are becoming a key focus for energy harvesting applications. Scientists are utilizing the unique properties of these materials to create compact energy scavenging devices and overcome challenges in material selection and fabrication technologies. Harvesting energy from sustainable sources using 2D nanomaterials shows promise for solving energy problems in various fields and applications.
NANO-MICRO LETTERS
(2021)
Article
Chemistry, Physical
Ruijin Meng et al.
Summary: The study reveals that using catalysts synthesized with 2D MOF nanosheets with different metal centers can optimize the performance of Li-S batteries, where Ni-MOF effectively catalyzes the reduction of long-chain polysulfides, and Co-MOF benefits the deposition kinetics of Li2S. Furthermore, the bimetal CoNi-MOF exhibits synergistic sulfur electrocatalytic activity, reducing reaction activation energies, enhancing reaction rates, and effectively inhibiting the shuttle effect.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Guojun Zheng et al.
Summary: Cu-BDC MOF nanosheets were successfully synthesized and carbonized at different pyrolysis temperatures to obtain C-500 and C-700 derivatives, both with abundant mesoporous structures, showing superior performance as anode materials for lithium-ion and potassium-ion batteries.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Lvhan Liang et al.
Summary: By utilizing the isolating effect of cobalt single atoms on platinum, strong interaction between cobalt single atoms and platinum, and the confinement of the metal organic framework-derived porous carbon matrix, platinum nanoparticles were successfully evenly immobilized on a nitrogen-doped carbon matrix with rich cobalt single atoms as multiple active sites. This not only increased the active centers, but also promoted catalysis kinetics, significantly improving catalytic activity for oxygen reduction and hydrogen evolution reactions.
Article
Chemistry, Applied
Guozheng Zhao et al.
Summary: Two host-guest two-dimensional (2D) MOFs based on N,N'-bis(n-hexyl)-4,4'-bipyridinium dibromide were prepared and showed photochromic properties. The electronic structures and matching rules between donors and receptors were explored using density functional theory.
Article
Energy & Fuels
Zhanlei Wang et al.
Summary: The excessive consumption of fossil fuels has depleted reserves and caused environmental crises, prompting a shift towards clean energy sources. However, the intermittent nature of these sources presents challenges in meeting long-term energy demand. Researchers propose the use of hybrid energy systems, with a novel energy cycle incorporating wind turbines, solar PV fields, alkaline fuel cells, Stirling engines, and electrolyzers. The introduced cycle aims to generate electricity and hydrogen fuel, demonstrating an output of 10.5 kW of electricity and an electrical efficiency of 56.9%.
Article
Chemistry, Physical
Min Wang et al.
Summary: A newly developed self-supported electrocatalyst with Fe-doped Ni3S2 nanoparticles exhibits high activity and durability in alkaline media, providing an effective solution for water electrolysis.
Article
Chemistry, Multidisciplinary
Y. -H. Luo et al.
Summary: By controlling the ultrasonic duration and solvent polarity, iron(II)-based 2D MOF was tailored into 2D nanosheets and 1D nanoribbons, exhibiting different properties and applications in different solutions. These results provide a novel strategy for the controlled preparation of layered nanomaterials.
MATERIALS TODAY CHEMISTRY
(2021)
Review
Chemistry, Physical
Zhenglong Li et al.
Summary: The exploration of highly active and low-cost electrocatalysts using 2D metal-free nanomaterials is crucial for sustainable and efficient energy conversion technologies. Surface engineering and interface engineering are key strategies for constructing advanced electrocatalysts based on these materials. Challenges and future directions of utilizing 2D metal-free nanomaterials in electrocatalysis are also discussed.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Ming-Feng Qin et al.
Summary: This paper presents the first example of a semiconducting porphyrinylphosphonate metal-organic framework and its chemical exfoliation into ultrathin metal-organic layers with high conductivity and efficient photocatalytic properties in reducing CO2 to CO. Spectroscopic studies suggest that the remarkable photocatalytic performance is a result of proper band alignment and great charge extraction capability of the cocatalyst, providing insights into catalyst design for coherent energy flow in hybrid photocatalytic systems.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Daili Tang et al.
Summary: A one-step electrosynthesis strategy for fabrication of 2D Hemin-bridged MOF sheets or 2D/3D Zn(II)-MOF hybrid nanocomposites on an electrode is reported. By controlling electrodeposition times and adding organic ligands, materials with varied morphologies can be obtained, providing a new avenue for preparing high surface area and biomimetic catalysts in the form of 2D/3D MOF hybrid nanocomposites.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Xueqing Yu et al.
Summary: This study successfully synthesized Pt/NixFe LDHs catalysts, demonstrating superior trifunctional electrocatalytic activity and durability for applications in sustainable energy conversion and storage systems such as water-alkali electrolyzers and hybrid sodium-air batteries.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Fuqin Zheng et al.
Summary: A facile strategy was proposed to fabricate 2D FeNi layered double hydroxide nanosheets packed with 1D sword-like FeNi-MOFs using FeNi-LDH as a semi-sacrificial template. The composite exhibited enhanced OER electrocatalytic performance due to its unique 2D/1D combined structure, with low overpotential, small Tafel slope, and high long-term durability, providing a new way to fabricate advanced catalysts for electrochemical energy conversion.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Joshua Nicks et al.
Summary: Metal-organic framework nanosheets (MONs) have programmable structures and high surface areas, making them useful in catalysis, sensing, optoelectronics, and gas separation applications. Their unique combination of properties presents common opportunities and challenges in various fields.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Ye Zeng et al.
Summary: NiFe oxyhydroxide has promising OER activity, which can be further enhanced by constructing pn junction. The MnCo-CH@NiFe-OH pn junction shows significantly improved OER performance and HER activity, outperforming Pt/C||RuO2 catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Engineering, Environmental
Lingya Yi et al.
Summary: In this study, graphene sheets doped with abundant N atoms were used as a unique support to load ultrasmall iridium nanoparticles, resulting in excellent electrocatalytic activity for overall water splitting. The enhanced activity was attributed to the strong coordination between Ir atoms and N dopants, enriching the electron density of Ir atoms for optimal electronic configuration during HER and OER processes.
CHEMICAL ENGINEERING JOURNAL
(2021)
Review
Chemistry, Inorganic & Nuclear
Weidong Fan et al.
Summary: Precise control of pore size and environment in metal-organic framework (MOF) is essential for achieving high performance gas adsorption and separation. The introduction of isoreticular chemistry in MOFs provides opportunities to improve their gas adsorption and separation performance, enhancing their advantages in gas separation applications.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Chemistry, Inorganic & Nuclear
Jingwen Jia et al.
Summary: This study focused on the application of NiFe MOF/NF synthesized by solvothermal method in oxygen electrocatalysis, revealing that the polar solvent mixture of acetone and water could control the formation of two-dimensional MOFs and exhibit excellent electrocatalytic performance in the oxygen evolution reaction.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Review
Chemistry, Physical
Torbjorn Egeland-Eriksen et al.
Summary: Hydrogen energy storage systems are technically feasible but require cost reductions for commercial attractiveness; low energy efficiency of some components affects costs; with the expected increase of intermittent renewable energy in power systems, hydrogen technology may see further development; hybrid systems offer the best solution but need to be tailored to specific situations for optimal efficiency.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Analytical
Qiling Li et al.
Summary: This study proposed a facile method to fabricate a self-supported electrode with excellent hydrogen evolution reaction (HER) activities. The optimized 2D CoP/Co-MOF exhibits outstanding HER performance over a wide pH range, with fast charge-transfer rate and abundant exposed active sites. This work provides an effective strategy to design pH-universal HER activity of MOF-based electrocatalysts.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Analytical
Daniel Ohm et al.
Summary: The study found that the size and dispersion of Pd and Ir monoatomic islands can be controlled by the deposition potential and duration of Cu. The hydrogen evolution reaction on 2D Pd or Ir islands on Au(111) can be tuned by selectively adjusting island size and inter-island distance on the nanoscale, with the charge density of the islands showing a maximum for intermediate deposition times.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Yao Pang et al.
Summary: In this study, a self-supporting amorphous NiFeCoP catalyst with nanoporous structure was prepared via a facile electrochemical dealloying method. The catalyst exhibited good electrocatalytic activity for both oxygen evolution reaction and hydrogen evolution reaction in 1.0 M KOH. The bifunctional electrocatalyst achieved outstanding and durable electrocatalytic activity in water splitting, providing a feasible strategy for efficient and low-cost bifunctional electrocatalysts.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Kuthuru Suresh et al.
Summary: By improving packing efficiency and crystal size distributions, the hydrogen storage density of metal-organic frameworks (MOFs) can be significantly enhanced, maximizing storage capacity. System model projections show that engineering crystal morphology/size or using bimodal distributions of cubic crystal sizes can surpass the current volumetric capacity of compressed storage systems.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
Aparna Murali et al.
Summary: Two-dimensional nanomaterials show unique physical, chemical, and biological properties, allowing for enhanced interactions with biomolecules and cells, and have broad potential in biomedical applications.
Review
Chemistry, Multidisciplinary
Kexin Zhang et al.
Summary: Oxygen evolution reaction (OER) is crucial in electrochemical applications like water splitting and rechargeable metal-air batteries, but its slow kinetics presents a performance bottleneck. Therefore, rational design of OER electrocatalysts based on understanding mechanisms and structure-activity relationship is essential. Study of reaction pathways, intermediates, and descriptors can lead to more efficient design of transition metal-based OER electrocatalysts.
Review
Chemistry, Multidisciplinary
Xu Liu et al.
Summary: This review discusses the crucial oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) mechanisms in zinc-air batteries (ZABs) and the importance of developing efficient and stable bifunctional ORR/OER catalysts to enhance ZAB performance. Additionally, it summarizes the improvements in energy efficiency, stability, and environmental adaptability of ZAB by introducing additional reactions and altering the OER pathway.
Article
Chemistry, Multidisciplinary
Xiaomin Xu et al.
Summary: This study presents a strategy of cation deficiency-promoted phase separation to design perovskite-based composites with significantly enhanced water oxidation kinetics compared to single-phase counterparts. The composite catalyst outperforms known perovskite oxide systems and state-of-the-art catalysts by 1-3 orders of magnitude, demonstrating a simple and viable approach to developing high-performance, perovskite-based composite catalysts for electrochemical energy conversion.
Article
Chemistry, Multidisciplinary
Rory Ma et al.
Summary: This study presents a theoretical investigation on the hydrogen evolution reaction (HER) system on Ni(abt)(2) catalyst using DFT and CCSD(T) calculations. The results show that a hydrogen atom from each of two amino groups is transferred to the central Ni atom one by one to form the hydrogen molecule.
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Hector Prats et al.
Summary: Hydrogen oxidation and evolution processes are important from both fundamental and applied perspectives. Few studies have explicitly accounted for the impact of H* coverage and mass transport in interpreting experimental kinetic data, leading to discrepancies in kinetic parameters and reaction mechanisms. Understanding H* coverage or activation energies is generally required to assign a reaction mechanism in HOR/HER processes. This study applies these concepts to activity data of various electrocatalysts, such as Au, Pt, MoS2, and CoP.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Review
Chemistry, Multidisciplinary
Xiaomin Xu et al.
Summary: Proton exchange membrane (PEM) water electrolysis is a promising technology for green hydrogen production, but the slow reaction kinetics of the anodic oxygen evolution reaction (OER) in an acidic environment hinders its practical viability. Noble metal-based catalysts like iridium and ruthenium are effective for the acidic OER, but their low abundance and high cost pose challenges for their use in PEM electrolyzers. Metal-organic frameworks (MOFs) have emerged as a platform for designing efficient and cost-effective acidic OER catalysts, with promising future research directions towards better catalysts for operation in acidic environments and PEM devices.
Article
Chemistry, Physical
Hui-Ya Wang et al.
Summary: The synthesis of MOF derivatives/MXene crosslinking networks has led to the development of materials with remarkable microwave absorption performance, demonstrating the potential for lightweight and highly efficient microwave absorbents.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Shanhe Zhou et al.
Summary: The misuse of antibiotics has led to global issues, and the synthesis of four new metal-organic frameworks with various topologies has allowed for the detection of 11 types of antibiotics through fluorescence quenching effect, with sample 2 showing sensitive and selective detection for nitrofurantoin (NZF). This highly selective probe behavior towards NZF ions can be maintained even in the presence of other interfering antibiotics.
Review
Chemistry, Multidisciplinary
Yingping Pang et al.
Summary: This article focuses on the electrochemical nitrogen reduction reaction (NRR) using two-dimensional (2D) nanomaterials as electrocatalysts, aiming to promote the sustainable production of NH3. The key metrics pursued in NRR, including the superior selectivity, activity, and stability of electrocatalysts, are highlighted in the study.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Physical
Yanru Wang et al.
Summary: This study demonstrates the in situ growth of 2D Co-MOF nanosheet arrays on conductive substrates and their subsequent conversion into Ni@CoO@Co-MOF composites for electrocatalysis. The composites show excellent performance for HER and OER, surpassing most Co/CoO-based electrocatalysts. The two-electrode electrolyzer fabricated from the composites displays a low overpotential for overall water splitting.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Ziqiang Wang et al.
Summary: Hierarchical IrTe nanotubes (NTs) with assembled nanosheets were prepared through a replacement reaction between Te nanowires and metal precursors in the presence of formic acid, serving as a bifunctional electrocatalyst for effective oxygen and hydrogen evolution reactions in acidic media. The IrTe NTs exhibited high-efficiency performance towards electrocatalytic overall water splitting in 0.5 M H2SO4 solution, reaching 10 mA cm(-2) at a cell voltage of only 1.53 V, showcasing a powerful approach to fabricate active bifunctional electrocatalysts for overall water splitting.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Review
Chemistry, Applied
Chengying Guo et al.
Summary: This review summarizes the recent progress in amorphous electrocatalysts for water splitting, including synthesis strategies, characterization tools, the origin of enhanced activity and stability, as well as current challenges and opportunities in this research area.
CHINESE JOURNAL OF CATALYSIS
(2021)
Article
Chemistry, Multidisciplinary
Zhenguo Wang et al.
Summary: In this study, a unique morphology of TS-Co3O4@VS2 hydrogen evolution catalyst was prepared using the MOF template method, showing excellent performance in hydrogen production efficiency and stability.
Review
Chemistry, Multidisciplinary
Joseph F. Olorunyomi et al.
Summary: Metal-organic frameworks (MOFs) are large surface area materials with organized porous cages that show promise in various applications like chemical sensing due to their design flexibility and predisposition towards functionalization. Recent studies have focused on the applications of MOF films and devices in chemical sensing since 2015, indicating their potential for integration in optical and electronic analytical devices. Demonstrations of future sensors are seen in MOF-based wearables and smartphone sensors, hinting at accelerated development of MOF-based analytical devices through collaborative efforts between scientists and engineers.
MATERIALS HORIZONS
(2021)
Article
Chemistry, Multidisciplinary
Can Sun et al.
Summary: This study presents a highly active bifunctional electrocatalyst derived from ZIF-8 with Rh nanoparticles enriched in a carbon matrix, showing excellent performance in both ORR and HER. The catalyst is comparable to commercial Pt/C catalyst in terms of ORR in alkaline media, suggesting new possibilities for fuel cells and water splitting.
Article
Materials Science, Biomaterials
Rui Zeng et al.
Summary: The study successfully synthesized a pH-responsive drug delivery system with a two-dimensional structure from bottom to top, demonstrating high anti-tumor activity and excellent biocompatibility in cancer treatment.
JOURNAL OF MATERIALS CHEMISTRY B
(2021)
Article
Chemistry, Analytical
Qiutong Li et al.
Summary: 2D Ni/Fe MOF nanosheets were successfully synthesized with excellent catalytic properties using a simple two-step ultrasound strategy. The nanozyme showed high sensitivity and linear response range in detecting multiple targets including H2O2, glutathione, and Hg2+.
ANALYTICAL METHODS
(2021)
Review
Chemistry, Multidisciplinary
Du San Baek et al.
Summary: This review discusses the current debate on identifying activity descriptors of the alkaline HER, hindering the design of high-performance catalysts. Strategies guided by activity descriptors for designing nanocatalytic materials for the alkaline HER are summarized, along with activity parameters of representative catalysts. Future perspectives for this field are suggested based on the findings of this study.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Review
Chemistry, Multidisciplinary
Yuan Cheng et al.
Summary: This article reviews the research on the thermal and mechanical properties of 2D materials, providing insights from both theoretical and experimental perspectives. It discusses the mechanical properties of 2D nanomaterials, the effects of thermal fluctuation on these properties, experimental methods to introduce strain, and fundamental phonon and thermal properties of 2D materials. The review gives an advanced understanding of these properties and their potential applications in nanoscale electronic, optoelectronic, and thermal functional devices.
Article
Chemistry, Multidisciplinary
Yue Zhou et al.
Summary: The study presents a general strategy for the rational design and synthesis of multifunctional 2D porous electrocatalysts, demonstrating excellent electrochemical activity and long-term stability in overall water splitting applications. The porous NiCoSe nanosheet arrays show low overpotential for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), making them promising candidates for future renewable energy systems.
Review
Chemistry, Multidisciplinary
Tingting Huang et al.
Review
Chemistry, Physical
Furat Dawood et al.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Review
Biochemistry & Molecular Biology
Dimitrios Giliopoulos et al.
Review
Chemistry, Multidisciplinary
Sengeni Anantharaj et al.
Article
Chemistry, Multidisciplinary
Yuanwen Zhang et al.
ADVANCED MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Katam Srinivas et al.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2020)
Review
Materials Science, Multidisciplinary
Yuan Pan et al.
SCIENCE CHINA-MATERIALS
(2020)
Article
Chemistry, Physical
Qiu Jin et al.
ADVANCED ENERGY MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Yifan Lin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Multidisciplinary
Mingchao Wang et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Chemistry, Physical
Dan Li et al.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2020)
Article
Chemistry, Applied
Fei-Fei Wang et al.
APPLIED ORGANOMETALLIC CHEMISTRY
(2020)
Article
Electrochemistry
Qingtao Wang et al.
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Aliki Moysiadou et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Multidisciplinary
Xia Liu et al.
Article
Chemistry, Physical
Weijie Zhu et al.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2020)
Article
Chemistry, Applied
Kai Huang et al.
CHINESE JOURNAL OF CATALYSIS
(2020)
Article
Chemistry, Multidisciplinary
Jia-Tong Ren et al.
Article
Chemistry, Physical
Kannimuthu Karthick et al.
CATALYSIS SCIENCE & TECHNOLOGY
(2020)
Review
Chemistry, Multidisciplinary
Yanshu Shi et al.
TRENDS IN CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Wei Pang et al.
Article
Nanoscience & Nanotechnology
Taewoo Kim et al.
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Multidisciplinary
Thibault Sohier et al.
Article
Chemistry, Multidisciplinary
Yifan Lin et al.
Article
Chemistry, Physical
Meng Ye et al.
NPJ COMPUTATIONAL MATERIALS
(2019)
Article
Nanoscience & Nanotechnology
Hani Nasser Abdelhamid
Article
Engineering, Chemical
Tahmineh Tamiji et al.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2019)
Article
Nanoscience & Nanotechnology
Pengchen He et al.
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Multidisciplinary
Xi Zhao et al.
Article
Chemistry, Applied
Yongteng Qian et al.
MICROPOROUS AND MESOPOROUS MATERIALS
(2019)
Article
Acoustics
Xuemin Wang et al.
ULTRASONICS SONOCHEMISTRY
(2019)
Review
Chemistry, Multidisciplinary
Bo You et al.
ADVANCED MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Xiudong Zhang et al.
Article
Chemistry, Multidisciplinary
Pei Nian et al.
Article
Chemistry, Physical
Hui Li et al.
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Article
Chemistry, Multidisciplinary
Jin Huang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2018)
Review
Chemistry, Physical
Vinod K. Sangwan et al.
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 69
(2018)
Article
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CHEMICAL COMMUNICATIONS
(2010)
