4.6 Article

An efficient bifunctional electrocatalyst for water splitting based on cobalt phosphide

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NANOTECHNOLOGY
卷 27, 期 23, 页码 -

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IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/27/23/23LT01

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cobalt phosphide; nanowire array; hydrogen evolution reaction; oxygen evolution reaction; bifunctional catalysts; water splitting

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The development of highly efficient electrocatalysts for water splitting is critical for various renewable-energy technologies. In this letter, we demonstrate a cobalt phosphide nanowire array grown on a Ti mesh (CoP/TM) behaving as a bifunctional electrocatalyst for water splitting. The CoP/TM electrode delivers 10 mA cm(-2) at an overpotential of 72 mV for the hydrogen evolution reaction (HER) and 310 mV for the oxygen evolution reaction (OER) in 1.0M KOH. Furthermore, its corresponding two-electrode alkaline electrolyzer displays 10 mA cm(-2) at 1.64 V.

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