Changes in Physicochemical Properties of Coal and Their Mechanism Due to Supercritical CO2-H2O Treatment

The dissolution of supercritical carbon dioxide (ScCO2) in water forms a ScCO2-H2O system, which exerts a transformative influence on the physicochemical characteristics of coal and significantly impacts the CO2-driven enhanced coalbed methane (CO2-ECBM) recovery process. Herein, the effect of ScCO2-H2O treatment on the physicochemical properties of coal was simulated in a high-pressure reactor. The migration of major elements, change in the pore structure, and change in the CH4 adsorption capacity of coal after the ScCO2-H2O treatment were detected using plasma emission spectroscopy, the low-temperature liquid nitrogen adsorption method, and the CH4 adsorption method, respectively. The results show that (1) the ScCO2-H2O treatment led to mineral reactions causing a significant migration of constant elements in the coal. The migration of Ca ions was the most significant, with an increase in their concentration in treated water from 0 to 16-970 mg center dot L-1, followed by Na, Mg, and K. Al migrated the least, from 0 to 0.004-2.555 mg center dot L-1. (2) The ScCO2-H2O treatment increased the pore volume and pore-specific surface area (SSA) of the coal via the dissolution and precipitation of minerals in the coal pores. The total pore volume increased from 0.000795-0.011543 to 0.001274-0.014644 cm(3)center dot g(-1), and the total pore SSA increased from 0.084-3.332 to 0.400-6.061 m(2)center dot g(-1). (3) Changes in the CH4 adsorption capacity were affected by the combined effects of a mineral reaction and pore structure change. The dissolved precipitates of the minerals in the coal pores after the ScCO2-H2O treatment caused elemental migration, which not only decreased the mineral content in the coal pores but also increased the total pore volume and total pore SSA, thus improving the CH4 adsorption capacity of the coal. This study provides theoretical support for CO2 sequestration and ECBM recovery.

Automated summary

The study investigates the impact of supercritical carbon dioxide and water solution on coal, revealing that this treatment can induce migration of elements, changes in pore structure, and an increase in methane adsorption capacity. This research provides significant theoretical support for CO2 sequestration and coalbed methane recovery.