期刊
CHEMICAL ENGINEERING SCIENCE
卷 135, 期 -, 页码 421-430出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2015.01.010
关键词
Soot combustion; Hydrotalcite; Cobalt; Pd; Potassium; Catalytic synergism
资金
- National Natural Science Foundation of China [21276184, U1332102, 21476160]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20120032110014]
- Program for Introducing Talents of Discipline to Universities of China [B06006]
The K/Co3-xPdxAl(O) (x=0 or 0.02) and K/Pd/Co3Al(O) catalysts promoted by K and Pd were synthesized by using pH constant co-precipitation and successive impregnation methods through the precursors of hydrotalcites. The physicochemical properties of these catalysts were systematically characterized by XRD, EXAFS, XANES, XPS, HRTEM, H-2-TPR, soot-TPR and in situ FT-IR. It is found that the catalyst K/Pd/Co3Al(O) prepared by successive impregnation displays the lowest characteristic temperatures including the initial and final combustion temperatures (T-i and T-f). The coexistence of K and Pd in K/Pd/Co3Al(O) or K/Co3-xPdxAl(O) can improve both the reducibility and the oxidizabilily of the catalysts, generating a prominent catalytic synergism on soot oxidation. K-Co-O and K-Pd-O have been identified as the main active phases in the catalysts simultaneously promoted by K and Pd. Based on the results of in-situ FT-IR three potential reaction pathways for soot combustion have been revealed, namely the direct soot oxidation, nitrate enhanced soot oxidation and NO2-assisted soot oxidation. As compared with the conventional Pd/Al2O3 catalyst, the as-prepared K/Pd/Co3Al(O) catalyst possesses much higher thermal stability. (C) 2015 Elsevier Ltd. All rights reserved.
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