期刊
CARBON LETTERS
卷 -, 期 -, 页码 -出版社
SPRINGER JAPAN KK
DOI: 10.1007/s42823-023-00572-6
关键词
Metal organic framework; Silicon; Carbon; Anode; Lithium-ion battery
In this study, carbon frameworks with a 3D porous structure were fabricated using metal-organic frameworks (MOFs) and then subjected to CVD to obtain silicon-carbon complexes. These silicon-carbon complexes with a 3D porous structure exhibited excellent rate capability by providing sufficient paths for Li-ion diffusion and electrolyte contact. The findings demonstrate the applicability of MOF-based carbon frameworks as a material for silicon complex anodes.
The complexation of silicon with carbon materials is considered an effective method for using silicon as an anode material for lithium-ion batteries. In the present study, carbon frameworks with a 3D porous structure were fabricated using metal-organic frameworks (MOFs), which have been drawing significant attention as a promising material in a wide range of applications. Subsequently, the fabricated carbon frameworks were subjected to CVD to obtain silicon-carbon complexes. These silicon-carbon complexes with a 3D porous structure exhibited excellent rate capability because they provided sufficient paths for Li-ion diffusion while facilitating contact with the electrolyte. In addition, unoccupied space within the silicon complex, combined with the stable structure of the carbon framework, allowed the volume expansion of silicon and the resultant stress to be more effectively accommodated, thereby reducing electrode expansion. The major findings of the present study demonstrate the applicability of MOF-based carbon frameworks as a material for silicon complex anodes.
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