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Review
Chemistry, Physical
Ben Hu et al.
Summary: In this article, the application of covalent organic frameworks (COFs) in addressing the issues of sulfur hosts, modified separators, artificial solid electrolyte interphase layers, and solid-state electrolytes in lithium-sulfur batteries is summarized. The focus is on the design and chemistry of COFs for upgrading Li-S batteries. The existing difficulties, prospective remedies, and future research directions for COFs in Li-S batteries are also discussed, laying the foundation for the advancement of this fascinating class of materials.
ADVANCED ENERGY MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Kan Fang et al.
Summary: Flexible zinc-ion batteries (ZIBs) with high safety and low production cost are ideal power sources for portable devices. The low mass-loading and limited areal capacity of the cathode materials are the main challenges for practical ZIBs. This study introduces a binder-free flexible vanadium oxide (MCV@CC) cathode with high mass-loading and large areal capacity, achieved through the bridge effect of MXene. The binder-free cathode reduces the electrochemically inactive weight and enhances the energy density of ZIBs. The MCV@CC cathode demonstrates desirable areal capacity and cycling stability, and the reaction mechanism is found to be based on reversible Zn2+/H+ (de)intercalation in the vanadium oxide interlayer. The use of the bridge effect strategy in constructing high mass-loading flexible electrodes provides insights for ZIBs applications.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Ming Wang et al.
Summary: Reconstructed Zn3V2O7 (OH)2.2 H2O (ZVO) with 8% V-O-V bridging oxygen vacancies was prepared to minimize the diffusion energy barrier of Zn2+ in zinc ion batteries. The cathode with 8% V-O-V bridging oxygen vacancies exhibited ultra-high performance of 135 mAh g-1 at 80 A g-1 and long life of 10,000 cycles with an 88% capacity retention at -30 celcius.
Article
Chemistry, Multidisciplinary
Tingting Lv et al.
Summary: In this study, metal ions were successfully inserted into the interlayer spacing of layered vanadium oxide nanobelts through confined synthesis, significantly improving the electrochemical performance of aqueous zinc-ion batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Environmental
Yuhang Lin et al.
Summary: This work presents the fabrication of LaCO3OH nanocrystals decorated nitrogen-doped carbon nanosheet arrays (MNCS-La) as an advanced sulfur reservoir for Li-S batteries. The hierarchical porous architecture of carbon nanosheet arrays and monodispersed LaCO3OH nanocrystals inhibit the shuttle effect and self-discharge, and enhance the electrochemical conversion kinetics. The sulfur electrodes based on MNCS-La exhibit enhanced electrochemical performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Xiuting Wu et al.
Summary: This study demonstrates a novel cathode material, ZnVO-800, derived from zeolitic imidazolate framework-8 (ZIF-8) by a self-sacrificed route. The ZnVO-800 cathode exhibits outstanding electrochemical performance, with high reversible capacity and excellent cycleability in aqueous zinc ion batteries. The electrochemical mechanism involves the transformation of ZnVO-800 into ZnxV2O5·nH(2)O with high electrochemical activity through in-situ electrochemical activation process, and the heterojunction with hierarchical structure enhances the dynamics and long-term cycleability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Liming Chen et al.
Summary: Acid treatment was used to remove ammonium ions and enhance the performance of ammonium vanadate, improving the efficiency of aqueous zinc ion batteries.
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Chemistry, Multidisciplinary
Jian Peng et al.
Summary: This article reviews the application of electrochemical activation strategy in high-performance aqueous energy storage. The strategy can convert inert or weakly active substances into highly active materials for water-based energy storage through electrochemical treatment, offering advantages of easy operation, variable control, high efficiency, flexibility, and wide applicability.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Xiao Wang et al.
Summary: The study demonstrates an in situ electrochemical activation strategy to enhance the electrochemical activity of a carbon-confined vanadium trioxide (V2O3@C) microsphere cathode, achieving ultra-high capacity and high energy density for zinc-ion batteries.
Article
Chemistry, Physical
Yongzheng Zhang et al.
Summary: In this study, a charge-enriched strategy through MXene-based polypyrrole (MXene-mPPy) layers was explored to achieve dendrite-free zinc metal anodes. The MXene-mPPy layers exhibited excellent charge enrichment ability and could homogenize the dispersion of electric field and ion flux, resulting in a dendrite-free zinc anode with an ultralong cycling lifespan and superior rate capability.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Quan Zong et al.
Summary: This study improves the structure and electrochemical properties of ammonium vanadate by introducing potassium ions, resulting in excellent cycling stability and high discharge capacity. The introduction of potassium ions alleviates deammoniation and prevents structural collapse, providing a better ion diffusion pathway.
Article
Chemistry, Multidisciplinary
Yunxiang Zhao et al.
Summary: Layer-structured metal vanadates have been studied as cathode materials due to their redox reactions and cations storage capability. The study introduces large-sized NH4+ ions to enhance the oxygen vacancies and improve the reaction kinetics. This approach significantly improves the capacity and cycling performance of the cathode material. In addition, the study investigates the role of oxygen vacancies in ion diffusion and electronic conductivity. This research provides new insights for the development and practical application of layer-structured cathode materials in energy storage devices.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Chemistry, Physical
Zhengnan Ju et al.
Summary: This review highlights the strategies proposed so far to pursue high energy density aqueous batteries, focusing on various aspects such as electrolytes, electrode chemistry, cathode materials, anode materials, and battery configurations. The emerging electrochemistry and the future development of high-energy aqueous batteries are also discussed.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Xiaodong Liu et al.
Summary: Vanadium sesquioxide (V2O3) embedded in carbon nanofibers (V2O3@C NFs) was developed as a flexible and binder-free cathode material for aqueous zinc-ion batteries (AZIBs), exhibiting high initial capacity, excellent cycling stability, and enhanced rate capability. The unique structure of V2O3@C NFs, including nano-sized V2O3 crystals with a tunnel-like 3D phase structure uniformly distributed in N-doped carbon NFs, contributes to its superior electrochemical performance. The theoretical simulations based on first-principles calculations provide insights into efficient zinc storage mechanism, and the practical application potential of V2O3@C NFs as a cathode material for AZIBs was demonstrated through assembly of a full battery.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Yan Zhang et al.
Summary: In this study, Mn-ions and polyaniline are co-inserted into vanadium pentoxide to develop high-performance layered cathodes for aqueous zinc-ion batteries.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Jiabin Guo et al.
Summary: This study proposes a facile and cost-effective strategy to fabricate polypyrrole-assisted nitrogen-doped vanadium dioxide/nitrogen-doped carbon heterostructures. The resulting electrodes exhibit impressive electrochemical performance and extraordinary mechanical flexibility for all-solid-state fiber-shaped nonpolarity supercapacitors and aqueous zinc-ion batteries. Theoretical calculations also show a significant enhancement in conductivity.
ADVANCED ENERGY MATERIALS
(2022)
Review
Chemistry, Physical
Cong Guo et al.
Summary: Aqueous zinc-ion batteries (ZIBs) have emerged as a competitive and promising option for large-scale energy storage. Vanadium-based compounds have been extensively studied as cathode materials for ZIBs due to their high theoretical capacity and abundant reserves. However, issues such as low conductivity and sluggish kinetics hinder their practical application. Defect engineering is considered an effective approach to addressing these challenges.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Yu Zheng et al.
Summary: A dual-engineering method, involving the partial removal of ammonium cations and the increase of oxygen vacancies, has been proposed to enhance the performance of ammonium vanadate in aqueous zinc ion batteries. Experimental and theoretical results demonstrate that this method can increase the interlayer space for Zn2+ insertion/deinsertion and weaken the interaction between the V-O layer and Zn2+, leading to improved capacity and rate performance.
ENERGY STORAGE MATERIALS
(2022)
Article
Engineering, Environmental
Jiechang Gao et al.
Summary: In this study, Ca-intercalated hydrated vanadium oxide (CaVO) nanobelts were synthesized, which showed enhanced electrochemical performance as cathode materials for practical Zn-ion batteries. The intercalated Ca ions and induced V vacancies synergistically enhanced the Zn-ion storage capability and effectively stabilized the crystal structure, leading to high reversible capacity, superior rate performance, and impressive cycling stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Yuan Li et al.
Summary: Ce0.3V2O5(H2O)·H2O/S (CeVS) material synthesized through hydrothermal reaction exhibits higher capacity and longer lifespan, maintaining the crystallinity and stability of Ce0.25V2O5(H2O)·H2O (CeVO) during the conversion process.
Article
Materials Science, Multidisciplinary
Feng Zhang et al.
Summary: Metal ion pre-intercalation into vanadium oxide is an effective strategy for optimizing the performance of rechargeable zinc-ion battery (ZIB) cathodes. However, improving the battery's long lifespan and high-capacity retention remains a challenge. This study introduces N-doped vanadium oxide as a cathode material for aqueous ZIBs, showing enhanced electronic conductivity and accelerated diffusion kinetics of zinc ions, leading to excellent electrochemical performance and long cycle life.
Article
Electrochemistry
Ziqing Wang et al.
Summary: In this study, high-capacity and high-stability aqueous zinc-vanadium batteries were achieved by simultaneously regulating the ions in the electrolyte. Na+ cations suppressed cathode dissolution and restrained Zn dendrite growth, while ClO4- anions formed a protective layer to decrease Zn dendrites and H2 evolution. The battery exhibited durable performance during long-term cycling.
Review
Materials Science, Multidisciplinary
Jing Zhang et al.
Summary: Lithium-sulfur batteries have advantages in theoretical energy density, but face challenges in reaction kinetics and lithium behavior. Active catalysts can improve the reaction kinetics and lithium behavior to enhance performance.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Tyler S. Mathis et al.
Summary: By including excess aluminum during the synthesis of the Ti3AlC2 MAX phase precursor, improved Al-Ti3C2 nanosheets with enhanced crystallinity and carbon stoichiometry are produced, leading to higher resistance to oxidation and increased electronic conductivity. The shelf life of aqueous suspensions of stoichiometric single-to few-layer Al-Ti3C2 flakes made from the modified precursor is extended to over ten months, compared to 1 to 2 weeks for previously published Ti3C2. Additionally, the improved Al-Ti3C2 exhibits oxidation initiation at temperatures 100-150 degrees C higher than conventional Ti3C2, demonstrating potential for widespread use of this material.
Review
Chemistry, Multidisciplinary
Haobo Dong et al.
Summary: The latest progress in polymer electrolytes for flexible ZIBs, particularly hydrogel electrolytes, is summarized in the article, along with discussions on relevant challenges, device configurations, and life cycle analysis. It is noted that most current polymer electrolytes emphasize electrochemical performance, with little consideration for mechanical behavior and interactions with electrode materials. Strategies to combine softness and strength, as well as the introduction of a ranking index to evaluate both electrochemical and mechanical properties, are discussed.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Sourav Mallick et al.
Summary: The growing demand for efficient energy storage devices has led to the emergence of rechargeable aqueous zinc-based battery technologies as a compelling alternative to lithium-based batteries. However, challenges such as cathode dissolution and dendrite formation still need to be addressed in zinc-ion batteries.
Article
Chemistry, Multidisciplinary
Xiao Wang et al.
Summary: A novel vanadium-based oxide cathode based on MgV2O6 center dot 1.7H(2)O nanobelts has been developed, demonstrating high capacity, strong rate capability, stable cycling performance, and suitable energy density for high-performance zinc-ion storage devices.
Review
Chemistry, Applied
Ying Liu et al.
Summary: Vanadium-based compounds are considered suitable cathode candidates for ZIBs with various structures and large layer spacings. This review emphasizes on the electrode design strategy, electrochemical performances, and energy storage mechanisms while pointing out the limitations and future prospects of vanadium-based materials.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Review
Chemistry, Multidisciplinary
Xiao Wang et al.
Summary: This review discusses the key challenges of rechargeable aqueous zinc-ion batteries, analyzing the structural features and electrochemical properties of different cathode materials, and proposing various electrode design strategies to guide future research activities. The focus is mainly on achieving high energy density and durable cathode materials.
Article
Engineering, Environmental
Bobae Ju et al.
Summary: This study prepared a VOH cathode material through a hydrothermal process, verified its applicability in aqueous zinc-ion batteries, and found that it possesses highly stable amorphous phase and reversible redox reactions, leading to superior and stable long-term cycling performance.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Xuefang Xie et al.
Summary: Electrochemical in situ defect induction can enhance the performance of vanadium nitride oxide materials in zinc-ion batteries, enabling efficient zinc ion storage through activation and in situ defect induction.
Article
Chemistry, Physical
Ying Liu et al.
Summary: In this study, a unique tunnel structured Na+ doped VO2 nanobelts were prepared with durable cycle stability, which were assembled into Zn/NVO batteries delivering large specific capacity and rate performance due to co-intercalation of crystal water and Na+. This pre-intercalation strategy enhances the electrochemical performance of vanadium oxide electrode materials and provides new ideas for developing other cathode materials for AZIBs.
Article
Chemistry, Multidisciplinary
Hangda Chen et al.
Summary: By inserting Mn2+, the structure stability of hydrated vanadium oxide is improved, the electronic structure is adjusted, and the conductivity is enhanced. Moreover, Mn2+ alters the migration pathway of Zn2+, reduces the migration barrier, and enhances the rate performance.
Article
Chemistry, Physical
Rui Li et al.
Summary: This study reports a PANI-intercalated V2O5 hybrid bronze with ultra-high interlayer spacing for use as an AZIB cathode, which shows improved stability and electronic conductivity. The PAVO cathode exhibits excellent cycling stability and rechargeable performance, indicating potential for designing optimized molecular-scale hybrid bronzes in the future.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Tao He et al.
Summary: A novel cation-deficient nonstoichiometric Zn-0.3(NH4)(0.3)V4O10·0.91H2O (ZNV) cathode material for aqueous zinc batteries (AZBs) was reported in this research, exhibiting high discharge capacity and superior cycle stability. Both experiments and theoretical simulations demonstrated that the presence of cation vacancies facilitates Zn2+ diffusion during cycles.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Kaiyue Zhu et al.
Summary: Search for high-capacity and stable cathodes is vital for the commercial development of high-energy-density, low-cost, and safe aqueous Zn-ion batteries. An activated VO2 cathode with high capacity and stability was developed by in situ electrochemical oxidation, demonstrating high discharge capacity, superior high-rate performance, and excellent cycling stability, making it a promising cathode for practical ZIBs.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Shenglong Li et al.
Summary: The development of high-performance cathode materials is crucial for the commercial applications of zinc-ion batteries. Vanadium-based V10O24·nH2O shows excellent electrochemical performance as a ZIB cathode, with high reversible capacity, ultrahigh rate performance, and long-term cycling stability. The synergistic effects of ultrathin nanoribbon structures, oxygen vacancy, and water molecules contribute to enhancing the electron/ion transfer kinetics and maintaining structural stability during cycling.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Lishang Zhang et al.
Summary: Rechargeable aqueous zinc ion batteries with vanadium-based cathodes face the challenge of vanadium dissolution in aqueous electrolytes, which can be effectively suppressed using guest engineering strategy.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Materials Science, Multidisciplinary
Huanyan Liu et al.
Summary: Rechargeable aqueous zinc-ion batteries (ZIBs) are considered a promising energy storage solution for grid-scale applications due to their safety, eco-friendliness, and cost-effectiveness. Despite significant progress in developing efficient cathodes, anodes, and electrolytes, the understanding of ZIBs and their energy storage mechanisms is still in its early stages and requires further investigation for practical implementation. This review provides a comprehensive summary of the development of ZIBs, design strategies, challenges, and opportunities for practical viability.
Article
Materials Science, Multidisciplinary
Feng Zhang et al.
Summary: The cathode of rechargeable aqueous zinc-ion batteries with organic cations and Zn2+ ions pre-inserted vanadium oxide shows high discharge capacity and ultra-long cycle life, indicating significant potential for practical applications in energy storage.
ENERGY & ENVIRONMENTAL MATERIALS
(2021)
Article
Chemistry, Physical
Junjie Shi et al.
JOURNAL OF POWER SOURCES
(2020)
Article
Chemistry, Multidisciplinary
Hao Luo et al.
Article
Chemistry, Physical
Muhammad Sufyan Javed et al.
Article
Chemistry, Multidisciplinary
Xiao Wang et al.
Article
Chemistry, Multidisciplinary
Hainan Zhao et al.
Article
Chemistry, Physical
Na Wang et al.
ADVANCED ENERGY MATERIALS
(2020)
Review
Chemistry, Physical
Fang Wan et al.
ACS ENERGY LETTERS
(2020)
Review
Chemistry, Physical
Biwei Xiao
Review
Chemistry, Multidisciplinary
Ning Zhang et al.
CHEMICAL SOCIETY REVIEWS
(2020)
Article
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Jaeho Shin et al.
ADVANCED ENERGY MATERIALS
(2019)
Article
Multidisciplinary Sciences
Ying-Qi Li et al.
NATURE COMMUNICATIONS
(2019)
Article
Materials Science, Multidisciplinary
Lingling Zhang et al.
ADVANCED MATERIALS TECHNOLOGIES
(2019)
Article
Chemistry, Physical
Tianpeng Jiao et al.
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Article
Chemistry, Physical
Yifu Zhang et al.
ACS APPLIED ENERGY MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Hongfei Li et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2018)
Article
Chemistry, Physical
Qiu Jiang et al.
ADVANCED ENERGY MATERIALS
(2018)
Article
Chemistry, Multidisciplinary
Kan Zhan et al.