4.6 Article

Metal-Induced Trap States: The Roles of Interface and Border Traps in HfO2/InGaAs

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MICROMACHINES
卷 14, 期 8, 页码 -

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MDPI
DOI: 10.3390/mi14081606

关键词

defects in HfO2; interface traps; border traps; acceptor-like and donor-like traps; Hf 4f peaks; valence band maximum; electronic band structure

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The impact of the work function of gate metals Ti, Mo, Pd, and Ni on defects in HfO2 and at HfO2/InGaAs interfaces was studied using capacitance-voltage measurements, TCAD simulations, and X-ray photoelectron spectroscopy. The highest density of interface and border traps was found at the Ti/HfO2 interface, while the Mo/HfO2 interface showed the smallest density of traps. The extracted values of D-it for acceptor-like traps and donor-like traps were the lowest reported to date.
By combining capacitance-voltage measurements, TCAD simulations, and X-ray photoelectron spectroscopy, the impact of the work function of the gate metals Ti, Mo, Pd, and Ni on the defects in bulk HfO2 and at the HfO2/InGaAs interfaces are studied. The oxidation at Ti/HfO2 is found to create the highest density of interface and border traps, while a stable interface at the Mo/HfO2 interface leads to the smallest density of traps in our sample. The extracted values of D-it of 1.27 x 10(11) eV(-1)cm(-2) for acceptor-like traps and 3.81 x 10(11) eV(-1)cm(-2) for donor-like traps are the lowest reported to date. The density and lifetimes of border traps in HfO2 are examined using the Heiman function and strongly affect the hysteresis of capacitance-voltage curves. The results help systematically guide the choice of gate metal for InGaAs.

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