期刊
CHEMICAL ENGINEERING SCIENCE
卷 123, 期 -, 页码 474-486出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2014.11.039
关键词
Methane dehydroaromatization; Gas to liquid; Zeolite catalyst; Mo/H-ZSM5; Benzene production; Non-oxidative coupling
资金
- Air Force Office of Scientific Research via a Basic Research initiative grant
This paper develops a detailed chemical kinetics reaction mechanism to represent methane dehyclroaromatization (MDA) chemistry on bi-functional Mo/zeolite catalysts. The model is validated using a range of previously published results from packed-bed experiments. The reaction mechanism consists of four methane activation reactions on Mo2C sites. The resulting gas-phase hydrogen and ethylene continue to react on Bronsted acid sites within the zeolite structure using 46 reaction steps. In addition to the desired benzene formation, the model also predicts the formation of toluene, naphthalene, and other side products. In addition to reaction kinetics on the catalyst surfaces, the packed bed model incorporates a Dusty Gas model that accommodates ordinary and Knudsen diffusion as well as pressure driven advection. Because the model represents essentially all published reports of MDA performance, it is reasonably expected that the model can be applied as a predictive tool to support reactor and process development. (C) 2014 Elsevier Ltd. All rights reserved.
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