期刊
POLYMERS
卷 15, 期 18, 页码 -出版社
MDPI
DOI: 10.3390/polym15183696
关键词
PP; SEBS; SEBS-g-(GMA-co-St) graft copolymer; compatibility; mechanical properties
Graft copolymers of SEBS-g-(GMA-co-St) were prepared via melt grafting and used as a compatibilizer for PP and SEBS blends. The amount of GMA significantly affected the properties of the blends, with GMA reacting with PP and SEBS to enhance their compatibility. The introduction of SEBS-g-(GMA-co-St) led to decreased crystallinity and increased crystal size, while maintaining high transmittance. Notched impact strength and elongation at break of the blends showed an increasing and then decreasing trend with increased GMA content, with the optimal toughness observed at 3 wt% GMA content.
Styrene (St) was used as comonomer and glycidyl methacrylate (GMA) as grafting monomer to prepare SEBS-g-(GMA-co-St) graft copolymers via melt grafting. Then, the graft copolymers were employed as a compatibilizer for melt blending polypropylene (PP) and hydrogenated styrene-butadiene-styrene (SEBS) triblock copolymers. The effects of the amount of GMA in the graft copolymers on thermal properties, rheology, crystallization, optical and mechanical properties, and microstructure of the blends were investigated. The results show that GMA and St were successfully grafted onto SEBS. The GMA amount in the graft copolymer significantly influenced the comprehensive properties of PP/SEBS/SEBS-g-(GMA-co-St) blends. The epoxy groups of GMA reacted with PP and SEBS, forming interfacial chemical bonds, thereby enhancing the compatibility between PP and SEBS to varying extents. After introducing SEBS-g-(GMA-co-St) into PP/SEBS blends, crystallinity decreased, crystal size increased while transmittance remained above 91% with rising GMA amount in the graft copolymers, indicating excellent optical properties. Notched impact strength and elongation at break of the blends showed a trend of first increasing and then decreasing with increased amounts of GMA in the graft copolymers. When the amount of GMA in the graft copolymers was 3 wt%, the blends exhibited optimal toughness with notched impact strength and elongation at break of 30,165.82 J/m2 and 1445.40%, respectively. This was attributed to the tightest dispersion interface adhesion and maximum matrix plastic deformation, consistent with the mechanical performance results.
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