期刊
NANO RESEARCH
卷 9, 期 10, 页码 2862-2874出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-016-1172-0
关键词
FeS nanosheets; high-energy facets; counter electrode; first-principles calculation; catalytic reduction
类别
资金
- National Natural Science Foundation of China [21473051, 21371053]
- Application Technology Research and Development Projects in Harbin [2013AE4BW051]
- International Science & Technology Cooperation Program of China [2014DFR41110]
The catalytic activity of materials is highly dependent on their composition and surface structure, especially the density of low-coordinated surface atoms. In this work, we have prepared two-dimensional hexagonal FeS with high-energy (001) facets (FeS-HE-001) via a solution-phase chemical method. Nanosheets (NSs) with exposed high-energy planes usually possess better reaction activity, so FeS-HE-001 was used as a counter electrode (CE) material for dye-sensitized solar cells (DSSCs). FeS-HE-001 achieved an average power conversion efficiency (PCE) of 8.88% (with the PCE of champion cells being 9.10%), which was almost 1.15 times higher than that of the Pt-based DSSCs (7.73%) measured in parallel. Cyclic voltammetry and Tafel polarization measurements revealed the excellent electrocatalytic activities of FeS-HE-001 towards the I (3) (-) /I- redox reaction. This can be attributed to the promotion of photoelectron transfer, which was measured by electrochemical impedance spectroscopy and scanning Kelvin probe, and the strong I (3) (-) adsorption and reduction activities, which were investigated using first-principles calculations. The presence of high-energy (001) facets in the NSs was an important factor for improving the catalytic reduction of I (3) (-) . We believe that our method is a promising way for the design and synthesis of advanced CE materials for energy harvesting.
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