期刊
NANO LETTERS
卷 16, 期 11, 页码 6886-6895出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.6b02759
关键词
Silicon nanospheres; magnetic resonances; excitons; resonance coupling; J-aggregates
类别
资金
- National Natural Science Foundation of China [51290271, 11474364]
- National Key Basic Research Program of China [2013CB933601, 2013YQ12034506]
- Guangdong Natural Science Funds for Distinguished Young Scholars Grant [2014A030306017]
- Guangdong Special Support Program
- Fundamental Research Funds for the Central Universities
Due to their optical magnetic and electric resonances associated with the high refractive index, dielectric silicon nanoparticles have been explored as novel nanocavities that are excellent candidates for enhancing various light matter interactions at the nanoscale. Here, from both of theoretical and experimental aspects, we explored resonance coupling between excitons and magnetic/electric resonances in heterostructures composed of the silicon nanoparticle coated with a molecular J-aggregate shell. The resonance coupling was originated from coherent energy transfer between the exciton and magnetic/electric modes, which was manifested by quenching dips on the scattering spectrum due to formation of hybrid modes. The influences of various parameters, including the molecular oscillation strength, molecular absorption line width, molecular shell thickness, refractive index of the surrounding environment, and separation between the core and shell, on the resonance coupling behaviors were scrutinized. In particular, the resonance coupling can approach the strong coupling regime by choosing appropriate molecular parameters, where an anticrossing behavior with a mode splitting of 100 meV was observed on the energy diagram. Most interestingly, the hybrid modes in such dielectric heterostructure can exhibit unidirectional light scattering behaviors, which cannot be achieved by those in plexcitonic nanoparticle composed of a metal nanoparticle core and a molecular shell.
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